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Physical Review A

Dissipation and fluctuation due to foreign-atom collisions: A Langevin-type equation approach

Li You, J. Cooper

Published Oct 1, 1992• 0 citations
Publisher

Abstract

We present a formal quantum-mechanical treatment of the damping and fluctuations of a generic radiator atom due to collisions with foreign gas atoms. By working in the Heisenberg picture, the fluctuating noise sources are identified with the damping. Under the same approximations as the conventional line-shape broadening theory in the impact (Markov) approximation, the fluctuation-dissipation theorem is satisfied in the form of the conservation of an equal-time commutator for the atomic operators. The implications of this type of approach for the quantum theory of light propagation in an active medium is addressed. Simple cases for two-level and three-level \ensuremath{\Lambda}-type systems are given explicitly.

DOI
10.1103/physreva.46.4335

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We present a formal quantum-mechanical treatment of the damping and fluctuations of a generic radiator atom due to collisions with foreign gas atoms. By working in the Heisenberg picture, the fluctuating noise sources are identified with the damping. Under the same approximations as the conventional line-shape broadening theory in the impact (Markov) approximation, the fluctuation-dissipation theorem is satisfied in the form of the conservation of an equal-time commutator for the atomic operators. The implications of this type of approach for the quantum theory of light propagation in an active medium is addressed. Simple cases for two-level and three-level \ensuremath{\Lambda}-type systems are given explicitly.
In the previous chapter, we developed the equation of motion for a system as it evolved under the influence of an unobserved (reservoir) system. We used the density matrix approach and worked in the interaction picture. In this chapter, we consider the same problem of the system-reservoir interaction using a quantum operator approach. We again eliminate the reservoir variables. The resulting equations for the system operators include, in addition to the damping terms, the noise operators which produce fluctuations. These equations have the form of classical Langevin equations, which describe, for example, the Brownian motion of a particle suspended in a liquid. The Heisenberg–Langevin approach discussed in this chapter is particularly suitable for the calculation of two-time correlation functions of the system operator as is, for example, required for the determination of the natural linewidth of a laser. We first consider the damping of the harmonic oscillator by an interaction with a reservoir consisting of many other simple harmonic oscillators. This system describes, for example, the damping of a single-mode field inside a cavity with lossy mirrors. The reservoir, in this case, consists of a large number of phonon-like modes in the mirrors. We also consider the decay of the field due to its interaction with an atomic reservoir. An interesting application of the theory of the system–reservoir interaction is the evolution of an atom inside a damped cavity. It is shown that the spontaneous transition rate of the atom can be substantially enhanced if it is placed in a resonant cavity.
A model independent generalization of quantum mechanics, including the usual as well as the dissipative quantum systems, is proposed. The theory is developed deductively from the basic principles of the standard quantum theory, the only new qualitative assumption being that we allow the wave operator at time t of a quantum system to be non-differentiable (in t) in the usual sense, but only in an appropriately defined (Sec. 5) stochastic sense. The resulting theory is shown to lead to a natural generalization of the usual quantum equations of motion, both in the form of the Schrödinger equation in interaction representation (Sec. 6) and of the Heisenberg equation (Sec. 8). The former equation leads in particular to a quantum fluctuation-dissipation relation of Einstein’s type. The latter equation is a generalized Langevin equation, from which the known form of the generalized master equation can be deduced via the quantum Feynmann-Kac technique (Secs. 9 and 10). For quantum noises with increments commuting with the past the quantum Langevin equation defines a closed system of (usually nonlinear) stochastic differential equations for the observables defining the coefficients of the noises. Such systems are parametrized by certain Lie algebras of observables of the system (Sec. 10). With appropriate choices of these Lie algebras one can deduce generalizations and corrections of several phenomenological equations previously introduced at different times to explain different phenomena. Two examples are considered: the Lie algebra [q, p]=i (Sec. 12), which is shown to lead to the equations of the damped harmonic oscillator; and the Lie algebra of SO(3) (Sec. 13) which is shown to lead to the Bloch equations. In both cases the equations obtained are independent of the model of noise. Moreover, in the former case, it is proved that the only possible noises which preserve the commutation relations of p, q are the quantum Brownian motions, commonly used in laser theory and solid state physics.
The need for a quantum-mechanical formalism for systems with dissipation which is applicable to the radiation field of a cavity is discussed. Two methods that have been used in this connection are described. The first, which starts with the classical Newtonian equation of motion for a damped oscillator and applies the conventional formal quantization techniques, leads to an exact solution; but subsequent discussion shows that this method is invalid, the results being unacceptable from a quantum-mechanical viewpoint. The second method, which considers the interaction of two systems, the lossless oscillator and the loss mechanism, is adopted in the present article. No special model is used for the loss mechanism, but this mechanism is assumed to have a large number of densely-spaced energy states.The approximations with respect to the loss mechanism that underlie the concept of dissipation are discussed. These approximations are then applied to the analysis, and a differential equation for a coordinate operator of the harmonic oscillator is obtained which has the formal appearance of the Newtonian equation of motion for a driven damped harmonic oscillator, the driving term being an operator referring to the loss mechanism. The presence of the driving term is responsible for the difference between the present theory and that of the first method mentioned above. A solution of the differential equation for the coordinate operator is given explicitly. An examination of the physical significance of the solution shows that the driving term is responsible not only for the thermal fluctuations which are due to the loss mechanism, but also for the proper commutation relationship of the conjugate coordinates of the oscillator and for its zero-point fluctuations.A generalization of the solution to provide for a classical driving force and coupled atomic systems is given. The results are then restated in a form that refers to the loss mechanism only through the two parameters by which it is usually described---the dissipation constant and the temperature.
A previously developed novel theory for the formal canonical quantization of classically dissipating systems will be the starting point for a detailed discussion of the quantum statistical aspects of the simple linearly damped harmonic oscillator. The formalism essentially involves complex classical canonical coordinates and momenta, and thus quite naturally leads to the possibility of creation and annihilation operators. Furthermore, the occurrence of quantal noise operators appears to be of principal importance for the conservation of the fundamental commutator in the course of time, as will be expressed in a simple fluctuation-dissipation relation. Making a canonical transformation back to the real, Cartesian Hermitian position and momentum an "effective" Hermitian Hamiltonian will be derived, with which a transformation is made from the Heisenberg frame to the Schr\"odinger frame where the density operator equation will be computed. This will make it obvious that no proper Schr\"odinger equation exists for the dissipative subsystem on its own, thus reflecting an incomplete knowledge. The master equation will then be translated into its Wigner representation. The intimate connection between the diffusion coefficients in the resulting Fokker-Planck equation and the uncertainty relation will be demonstrated in a clear fashion.
An operational method is presented that can avoid some of the difficulties associated with numerically simulating the Langevin operator equations for a dissipative quantum optical system. The approach is based on a set of quantum-classical correspondence rules that relate atomic operators in the Heisenberg picture to their corresponding double-dimensioned classical atomic variables. With this approach, the Langevin operator equations can be transformed into a doubled set of classical stochastic differential equations (SDE's). The relationship to the quantum regression theory up to the two-time correlation function and similarities to the positive P representation are discussed. As an illustrative example, we show that both the resonance fluorescence spectrum (Mollow spectrum) as well as the absorption spectrum for a two-level atom interacting with a near-resonance field can be simulated from the doubled set of classical SDE's without explicit reference to the quantum regression theorem.
A quantum treatment of a coherently driven cavity with a medium of two-level atoms is given. The system displays both absorptive and dispersive bistability. Quantum fluctuations are included via a Fokker-Planck equation in a generalized PPP representation, after adiabatic elimination of the atomic variables. The transmitted spectrum and correlation function is calculated in a linearized (Gaussian) approximation. In the limit of large detuning and radiative damping, the quantum fluctuations are identical to those of a simple nonlinear polarizability theory. An analysis is given of the nonclassical statistical properties of the intensity-correlation spectrum.