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Communications in Mathematical Physics

Markovian master equations

E. B. Davies

Published Jun 1, 1974• 934 citations
Publisher
DOI
10.1007/bf01608389

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arXiv:2411.16878•Nov 25, 2024•0 citations
We derive a Markovian master equation for driven open quantum systems based on the Lewis-Riesenfeld-invariants theory, which is available for arbitrary driving protocols. The role of the Lewis-Riesenfeld invariants is to help us bypass the time-ordering obstacle in expanding the propagator of the free dynamics, such that the Lindblad operators in our driven Markovian master equation can be determined easily. We also illustrate that, for the driven open quantum systems, the spontaneous emission and the thermal excitation induce the transitions between eigenstates of the Lewis-Riesenfeld invariant, but not the system Hamiltonian's. As an example, we present the driven Markovian master equation for a driven two-level system coupled to a heat reservoir. By comparing to the exactly solvable models, the availability of the driven Markovian master equation is verified. Meanwhile, the adiabatic limit and inertial limit of the driven Markovian master equation are also discussed, which result in the same Markovian master equations as those presented before in the corresponding limits.
We derive a completely positive post-Markovian master equation (PMME) from a microscopic Markovian collisional model framework, incorporating bath memory effects via a probabilistic single-shot measurement approach. This phenomenological master equation is both analytically solvable and numerically tractable. Depending on the choice of the memory kernel function, the PMME can be reduced to the exact Nakajima-Zwanzig equation or the Markovian master equation, enabling a broad spectrum of dynamical behaviors. We also investigate thermalization using the derived equation, revealing that the post-Markovian dynamics accelerates the thermalization process, exceeding rates observed within the Markovian framework. Our approach solidifies the assertion that "collisional models can simulate any open quantum dynamics", underscoring the versatility of the models in realizing open quantum systems.