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Journal de Physique Lettres

Study of Hg* (63 p1)-noble gas collisions in a 200 kG field range

J. C. Gay, A. Omont

Published Jan 1, 1976• 8 citations
Publisher

Abstract

The study of Hg* (6 3P1)-rare gas collisions in a 200 kG range of magnetic field is reported. The results show that the collisional transfer rates between the m = 0 and the m = ± 1 Zeeman sublevels of an even isotope of mercury exhibit a strikingly different dependence on the field strength according to the noble gas species. A very qualitative attempt at interpretation is given using the results of a previous theoretical model which predicts a strong anisotropy of the relaxation process when the vapour is submitted to such magnetic fields.

DOI
10.1051/jphyslet:0197600370406900

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The study of Hg* (6 3P1)-rare gas collisions in a 200 kG range of magnetic field is reported. The results show that the collisional transfer rates between the m = 0 and the m = ± 1 Zeeman sublevels of an even isotope of mercury exhibit a strikingly different dependence on the field strength according to the noble gas species. A very qualitative attempt at interpretation is given using the results of a previous theoretical model which predicts a strong anisotropy of the relaxation process when the vapour is submitted to such magnetic fields.
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An experimental study of excitation transfer between certain Zeeman sublevels of the 32PJ3^{2}P_{J}32PJ​ states in strong magnetic fields is reported for $\mathrm{Na}(3^{2}S_{\frac{1}{2}})\ensuremath{-}{\mathrm{Na}}^{*}(3^{2}P_{J})$ resonant collisions. A major decrease in the $M=\ensuremath{-}\frac{3}{2}\ensuremath{\rightarrow}M=\frac{3}{2}$ transfer rate is observed between 4 and 80 kG. Approximate calculations in the correlation-function framework are performed, and the experimental results and theoretical predictions for the field dependence are in good agreement. Some insights into the mechanisms of the collision process are deduced and the particularly important role of the electronic spin is emphasized. The importance of the symmetry properties of the interaction potential is also directly demonstrated.
The authors report an application of the pulsed magnetic field technique to the study of resonant inter-atomic collisions on the decay of alignment ( gamma 2 ) of the 6 3 P 1 state of mercury. Resonance fluorescence scattered at right angles from atoms near the front face of a cell is observed; the depolarizing effect of multiple scattering is thereby reduced, allowing studies of same-isotope collisions to proceed to higher density. For this geometry the effect of wall collisions on gamma 2 is not large. Magnetic scanning of the lamp is employed, firstly, to determine the isotopic abundance in the cell, and, secondly to enable study of both 'same-isotope' and 'different-isotope' collisions using the same lamp and cell. The results for different-isotope collisions confirm those obtained by others. For Hg 198 -Hg 198 collisions, the contribution to gamma 2 is found to be (4.7+or-0.5)*10 -9 N cm 2 s -1 , in satisfactory agreement with the theoretical value.
Magnetic field dependence of cross sections for collisional disorientation of 6 sup2sup 2sup2Psub1sub 1sub1/sub2sub 2sub2 cesium atoms
The magnetic field dependence of the cross sections for the disorientation of 6 sup2sup 2sup2Psub1sub 1sub1/sub2sub 2sub2 cesium atoms, induced in Cs-He collisions, has been studied using Zeeman scanning techniques. A Cs-He mixture, contained in a fluorescence cell which was located in a magnetic field variable from 0 to 10 kG, was irradiated with the circularly polarized 8943-A component of cesium resonance radiation in a direction parallel to the field, and the polarization of the resonance fluorescence was monitored in the backward direction in relation to the helium pressure and to the magnetic field strength. The cross sections, which are in good agreement with the results obtained previously at high and low magnetic fields, exhibit a variation with the magnetic field, which is in accordance with theoretical predictions. (AIP)