The Hellmann-Feynman theorem valid for the parameter dependence of bound states is generalised to the case of Gamow states using an appropriate definition of scalar products and expectation values with such states. The one-dimensional square well potential is considered as an illustrative example.
We present a simple derivation of the Hellmann–Feynman theorem at finite temperature. We illustrate its validity by considering three relevant examples, which can be used in quantum mechanics lectures: the one-dimensional harmonic oscillator, the one-dimensional Ising model, and the Lipkin model. We show that the Hellmann–Feynman theorem allows one to calculate expectation values of operators that appear in the Hamiltonian. This is particularly useful when the total free energy is available, but there is no direct access to the thermal average of the operators themselves.
Theorems giving exact expressions for the derivative of the energy with respect to a parameter in the Hamiltonian for cyclic classical mechanical problems in both the relativistic and nonrelativistic cases are derived. Comparison is made with similar well-known theorems in the quantum mechanical case. Applications of both classical and quantum derivative relations are made to deduction of parametric dependence of the energy in simple cases, deduction of a meaning to the expectation value of the Dirac operator β, and construction of a test of consistency for a well posed problem in the theory of a Dirac particle in a bound state.
Various versions of the Hellmann-Feynman theorem that were studied in a previous paper are applied to the actual computation of certain contributions to the expectation value of the kinetic and potential energies of nuclear matter. The numerical importance of the contributions which violate the Bethe-Brandow-Petscheck theorem in some versions is examined. We also provide a discussion of the so-called conserving approximation which directly derives the expectation value of the kinetic energy from that of the potential energy.