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IEEE Journal of Quantum Electronics

Sharp line excitation of resonance fluorescence in pink ruby

F. Barocchi, M. Mancini, Riccardo Pratesi, G. Toraldo di Francia

Published May 1, 1968• 1 citation
Publisher
DOI
10.1109/jqe.1968.1075122

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Journal of the Physical Society of Japan•Jul 15, 1981•3 citations
The unique optical properties of the ruby crystal that make it effective as a lasing medium were measured using a simple optical setup.Ruby's absorption of visible light was shown to be strongest at 420 and 550 nm, corresponding to its physical appearance as transparent pink.While the ruby crystal was illuminated with a 532 nm green laser, the R-line fluorescence peaked at 693.5 ± 1.1 nm.Finally, the fluorescence lifetime of ruby was measured by pulsing the laser with a signal generator and capturing the decaying fluorescence on a digital oscilloscope using a photodiode.An exponential decay time-constant of 3.6 ± 0.1 ms was obtained, corresponding to the fluorescence lifetime.
A large number of small but sharp changes (increases and decreases) of the R 1 fluorescence in ruby are observed as a function of applied magnetic field between 2 K and 77 K. At liquid helium temperatures, these signals have linewidths much narrower than the inhomogeneous linewidth (∼0.1 cm -1 ) of the R 1 line. All of these signals appear at the fields where the Zeeman splittings in the excited state \bar E ( 2 E ) and the ground state 4 A 2 satisfy an energy-matching condition for simultaneous transitions of two or more ions. Two distinct mechanisms are found to be responsible for the signals: spin-spin cross-relaxation between \bar E ( 2 E ) and 4 A 2 , and resonant self-trapping of the R 1 line. From the temperature dependence of the linewidths of the signals, thermal broadening of \bar E ( 2 E ) is measured below 77 K. Similar signals are observed in the N lines due to energy transfer from isolated ions to pairs.