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Physical Review Letters

Tricritical Exponents and Scaling Fields

Eberhard K. Riedel, Franz Wegner

Published Aug 7, 1972• 311 citations
Publisher

Abstract

The tricritical behavior of a classical three-well-potential model for two-component systems (such as ${\mathrm{He}}^{3}$-${\mathrm{He}}^{4}$ mixtures) is discussed by using renormalization-group techniques. The tricritical exponents and scaling fields are calculated for three dimensions.

DOI
10.1103/physrevlett.29.349

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Eberhard K. Riedel

A theory for tricritical phenomena proposed by Wegner and the author is described on an elementary level. The emphasis of the discussion is on (i) the differences between critical and tricritical phase transitions, (ii) the crossover phenomena that occur near tricritical points, and (iii) the determination of tricritical exponents, scaling fields and scaling functions. The results have been obtained by renormalization‐group techniques and a scaling field approach to crossover phenomena. The elements of these techniques are briefly explained.

Annual Conference on Magnetism and Magnetic Materials (MMM)•Jan 1, 1974•1 citation
The tricritical behavior of a classical three-well-potential model for two-component systems (such as He3{\mathrm{He}}^{3}He3-He4{\mathrm{He}}^{4}He4 mixtures) is discussed by using renormalization-group techniques. The tricritical exponents and scaling fields are calculated for three dimensions.
In Part I the global phase diagram of the general spin-1, nearest-neighbor, ferromagnetic Ising model was studied for d=2d=2d=2 dimensions using an approximate renormalization-group approach of the Migdal-Kadanoff type. Here general ddd is considered with emphasis on $\ensuremath{\epsilon}=d\ensuremath{-}1$ expansions and on the variation of the tricritical exponents with d< 4d<~4d< 4. A dilution field is introduced which can be chosen to yield tricritical exponents for d=2d=2d=2, in better agreement with more reliable estimates and conjectured exact results. The three-phase monohedra, which describe the densities of coexisting phases near a tricritical point, are calculated quantitatively for d=2d=2d=2, and their shape contrasted with that predicted by classical theory: they are found, in particular, to be significantly flattened.
Thermodynamic behavior of a mixture of weakly interacting fermions and bosons is investigated in 4-\ensuremath{\epsilon} dimensions by the renormalization-group method with the purpose of studying scaling and crossover properties of the system in the tricritical region. Conventional tricritical scaling, first found to break down for a classical infinite-component model, is seen to do so more spectacularly in the case of the mixture. Whereas in the infinite-component model, conventional scaling holds in the ordered and disordered phases separately (i.e., with different tricritical exponents), it is impossible in either of the phases of the mixture. The breakdown of scaling in the mixture is associated with the dimensionless strength v6{v}_{6}v6​ of the six-point interaction in the effective Hamiltonian that causes the parameters of the renormalized Hamiltonian to depend on two combinations of scaling fields rather than one. The strength v6{v}_{6}v6​ is a quantum-mechanical parameter, being proportional in three dimensions to b3{b}^{3}b3/${\ensuremath{\lambda}}_{T}^{4}$KF{K}_{F}KF​, where ${\ensuremath{\lambda}}_{T}$, KF{K}_{F}KF​, and b denote, respectively, the boson thermal wavelength, the Fermi momentum of the fermion component, and the scattering length associated with the fermion-boson interaction. The square root of this quantity agrees with the nonuniversality parameter, which was found to characterize tricritical amplitude ratios in three dimensions in an earlier work.
A semi-microscopic scaling-field theory is developed for crossover phenomena near critical and tricritical points. The theory is based on a renormalization-group description of a model with two competing fixed points (such as a critical and a tricritical fixed point) in terms of scaling fields. The coupled nonlinear differential equations for scaling fields are truncated such as to preserve the physics essential for crossover phenomena. The approach allows the explicit calculation of thermodynamic functions for (i) tricritical systems and (ii) critical systems with an irrelevant scaling field. We obtain, for example, an explicit expression for the scaling function of the susceptibility, which describes the crossover from the tricritical to the critical region. The idea of "flow diagrams" in the scaling-field space is used to characterize crossover phenomena globally in the whole critical region. The concept of asymptotic critical exponents is generalized and effective critical exponents are introduced as logarithmic derivatives of thermodynamic quantities with respect to experimental fields and scaling fields, respectively. By using the method of effective exponents the size of the crossover region between regions of different asymptotic critical behavior is estimated. For the susceptibility, the width of the crossover region in decades of the effective temperature variable is roughly equal to the inverse of the crossover exponent. In the case of a critical system with a slow transient the asymptotic critical exponent is only reached extremely close to the critical point (unless the amplitude of the transient vanishes). It might then be impossible to determine the asymptotic exponent experimentally or by conventional series-expansion techniques, and an analysis of the data in terms of effective exponents is the alternative. The scaling-field approach is applied to three systems with crossover phenomena: (i) the model for tricritical systems with molecular-field tricritical exponents, (ii) the Ashkin-Teller model in three dimensions, and (iii) a model for phase transitions with Fisher exponent renormalization due to a constraint.
We analyze exactly in the limit $n\ensuremath{\rightarrow}\ensuremath{\infty}$, the nnn-component continuous-spin model with a cubic field term ${\stackrel{\ensuremath{\rightarrow}}{\mathrm{H}}}_{3}\ifmmode\cdot\else\textperiodcentered\fi{}\stackrel{\ensuremath{\rightarrow}}{\mathrm{s}}{|\stackrel{\ensuremath{\rightarrow}}{\mathrm{s}}|}^{2}$. Full "four-field" tricritical behavior is exhibited for dimensionalities $d\ensuremath{\ge}3$. However, orthodox tricritical scaling is shown to be impossible for 3<d<43<d<43<d<4: to obtain the correct nonclassical spherical-model exponents on the $\ensuremath{\lambda}$ line (H=H3=0,T>TtH={H}_{3}=0, T>{T}_{t}H=H3​=0,T>Tt​) it is essential to allow for a dangerous irrelevant scaling variable $p\ensuremath{\propto}\frac{1}{{R}_{0}^{d}}$, where R0{R}_{0}R0​ is the range of the pair interactions. The appropriate crossover exponent is ${\ensuremath{\varphi}}_{p}=3\ensuremath{-}d$ so that ppp is marginal for d=3d=3d=3: orthodox scaling is then possible but the scaling functions are nonuniversal. On the disordered symmetry plane (H=H3=0H={H}_{3}=0H=H3​=0) only the corrections to scaling survive and describe crossover to Gaussian tricritical behavior. For T>TtT>{T}_{t}T>Tt​ bicritical crossover from spherical to classical critical behavior occurs when H3{H}_{3}H3​ varies but scaling is fully obeyed. Some inferences for systems with finite nnn are drawn.
A theory for tricritical phenomena proposed by Wegner and the author is described on an elementary level. The emphasis of the discussion is on (i) the differences between critical and tricritical phase transitions, (ii) the crossover phenomena that occur near tricritical points, and (iii) the determination of tricritical exponents, scaling fields and scaling functions. The results have been obtained by renormalization‐group techniques and a scaling field approach to crossover phenomena. The elements of these techniques are briefly explained.