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Journal of Statistical Physics

Condensation in the imperfect boson gas

M. van den Berg, John T. Lewis, Ph. De Smedt

Published Dec 1, 1984• 63 citations
Publisher
DOI
10.1007/bf01010502

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Journal of Physics A Mathematical and General•Nov 27, 1998•26 citations
The nature of the Einstein-Bose condensation in an imperfect boson gas is discussed. It is argued that no matter how low the temperature, provided it is not zero, macroscopic second-sound waves should be weakly excited as thermal fluctuations about equilibrium. This implies that the single-particle momentum distribution must be smeared so that the state of zero momentum cannot contain a finite fraction of the particles. A microscopic mechanism which independently leads to a momentum spread is discussed. It is suggested that the actual Einstein-Bose condensation of an imperfect gas takes place in energy rather than momentum but that even in terms of this variable it becomes perfectly sharp only at zero temperature. This hypothesis is formulated analytically in terms of correlation functions of the second-quantized boson field.
We show that the pressure of the Bogoliubov weakly imperfect Bose gas (WIBG) can be calculated exactly in the thermodynamic limit. We point out the sufficient and necessary conditions for it not to equate with the pressure of the ideal Bose gas (IBG). We prove that they differ only in that part of the phase diagram where the WIBG has a Bose condensate. We show that in contast to the conventional Bose condensate (e.g. in the IBG) the condensate in the WIBG is due to an effective attraction between bosons in the zero-mode.