Wigner representations of the rotational motion of a rotator or spherical top, as well as symmetrical and arbitrary tops are presented. The unique form of the transformations to these representations is derived using a set of natural requirements. As a particular case of these representations, a Wigner representation of angular momentum orientation is found. Relations between this representation and those of irreducible tensor operators and coherent states are established. For large angular momentum l >>1, rough equations for the Wigner functions are derived, and it is shown that they are similar to the well known equation for the Wigner function for translational motion.
Wigner representations of the rotational motion of a rotator or spherical top, as well as symmetrical and arbitrary tops are presented. The unique form of the transformations to these representations is derived using a set of natural requirements. As a particular case of these representations, a Wigner representation of angular momentum orientation is found. Relations between this representation and those of irreducible tensor operators and coherent states are established. For large angular momentum l >>1, rough equations for the Wigner functions are derived, and it is shown that they are similar to the well known equation for the Wigner function for translational motion.
A comprehensive study is presented on the Weyl-Wigner formalism for rotation-angle and angular-momentum variables: the elements of kinematics are extended, the elements of dynamics are established, and the implications of rotational perodicity and angular-momentum quantization are investigated. Particular attention is paid to discreteness, and two of its consequences are emphasized: the importance of evenness and oddness, and the need to use two difference operators in a discrete domain, whereas one differential operator suffices in a continuous domain. These consequences are shown to strongly distinguish the Weyl-Wigner formalism for rotation-angle and angular-momentum variables from the well-known Weyl-Wigner formalism for Cartesian-position and linear-momentum variables. The point is made clear that the first of these formalisms cannot be regarded as a trivial and straightforward extension of the second. The rotational Wigner function is derived as the only bilinear form of the state vector that is real, has the natural invariances for rotational motion, and yields the correct distributions for the rotation-angle and angular-momentum variables as well as the appropriate expression for the transition probability between states. The conditions for its uniqueness are thus established. Its properties are described in detail and, in particular, its uniform boundedness is demonstrated. The rotational Wigner function and the associated correspondence between quantum operators and classical-like functions, as well as the relations they obey, are explored and are written so as to clearly exhibit the distinct contributions of evenness and oddness in the discrete domain of the angular-momentum eigenvalues, thus providing a most natural way to account for periodicity.Using the derivative, which acts on the continuous rotation-angle variable, and the forward and backward differences, which act on the discrete angular-momentum variable, the equation of motion for the rotational Wigner function is established. This equation is detailed for the following Hamiltonian forms: those that depend only on the angular-momentum variable, including, in particular, the free rotator, and those that are in the cosine of the rotation-angle variable. It is verified that the Weyl-Wigner formalism for rotation-angle and angular-momentum variables has the correct nonperiodic limit and that it properly reduces to the Weyl-Wigner formalism for Cartesian-position and linear-momentum variables. In order to illustrate the formalism, a careful analysis is carried out for the rotational Wigner function representing the energy eigenstates of a hindered rotator whose Hamiltonian is the sum of a term in the absolute value of the angular-momentum variable with a term in the cosine of the rotation-angle variable. For this hindered rotator, and within the approximation of a large absolute value of the angular-momentum variable, the equation of motion for the rotational Wigner function is solved for its stationary solutions, and the time-independent Schr\"odinger equation is also solved.
Abstract This chapter presents orbital angular momentum as the generator or rotations in space. The operators which carry out rotations in space form a group, which is a symmetry group of the Hamiltonian when the interaction is spherically symmetric. In such a case, there are certain useful statements which we can make about the role of invariant and irreducible subspaces of the Hilbert space under the group operations and how to calculate matrix elements of tensor operators within such spaces, that is, the Wigner-Eckart theorem.
We propose a Wigner transformation of the density matrix and operators of a system with bounded coordinates and discrete momentum spectra (typically, a particle in a box) and prove that all requirements for such a transformation are satisfied. The phase-space mapping adopted here is employed to compute the quasiprobability distributions associated with the pure states of a quantum rotator and the image of the angular momentum operator. The mapping of the dynamics of these objects, both in the reversible and irreversible frame, is constructed as well, and the conditions for the existence of a classical limit in the form of a Fokker-Planck equation of motion are investigated.
Angular momentum theory provides a mathematical foundation for the rotation of the eigenvectors of the angular momentum operator, the spherical harmonics functions. A useful property of spherical harmonics is that their rotation in 3D space corresponds to rotation in the virtual space of their azimuthal degrees of freedom. In addition to that, spherical harmonics functions that have different orbital indices do not mix. Given that spherical harmonics functions have known rotation properties, and that any arbitrary function can be expanded in a series of spherical harmonics, this property allows the rotation of an electrostatic potential when it is expanded in the series of spherical harmonics. In this chapter, the exponential form of the rotation operator, the rotation matrix for a 3D rotation of the coordinate system, and the principles of rotation of vectors and functions are described. The chapter provides a detailed self-contained introduction to the theory of angular momentum, derives the commutative properties of the angular momentum operator, and explains shift operators, while minimizing references to quantum mechanics and entirely avoiding group theory.
It has been the purpose of the monograph Angular Momentum in Quantum Physics (AMQP) to develop comprehensively those aspects of angular momentum theory that are required in carrying out research in modern physics and chemistry. The emphasis there was principally on physical concepts and the symmetry principles that underlie the general applicability of angular momentum theory to a broad area of physical phenomena. Mathematical techniques were introduced within the context of the physical concepts themselves. Physical applications of angular momentum theory are to a large extent applications of specific properties of Wigner or Racah functions (more generally of 3 n-j coefficients) or of the representation functions themselves. Such applications tend to emphasize the “numerical” aspects of these functions and thus obscure the relationships to other areas of mathematics. The purpose of the present monograph is to show by specific examples the many interrelations that exist between concepts originating in angular momentum theory and various areas of mathematics. It turns out that this is a substantial task—the diversity of the interrelations is far greater than might be thought. Even a brief acquaintance with the contents of AMQP will show that the concept that recurs again and again in physical applications is that of an irreducible tensor operator with respect to a group [in our case, SU (2), the quantal rotation group]. Indeed, it is this concept that carries the mathematical apparatus of the physical theory beyond the related but much simpler results of the Lie algebraic theory of the angular momentum itself and the implied representation theory of the group SU (2).
The general theory of quantum angular momentum is used to derive the unique Wigner distribution function for arbitrary angular-momentum states. We give the explicit distribution for atomic angular-momentum Dicke states, coherent states, and squeezed states that correspond to a collection of N two-level atoms. These Wigner functions W(\ensuremath{\theta},cphi) are represented as a pseudoprobability distribution in spherical phase space with spherical coordinates \ensuremath{\theta} and cphi on the surface of a sphere of radius \ensuremath{\Elzxh} \ensuremath{\surd}j(j+1) where j is the total angular-momentum eigenvalue.