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Physical Review A

Critical Phenomena in Systems of Finite Thickness. III. Specific Heat of an Ideal Boson Film

Michael N. Barber, Michael Ellis Fisher

Published Aug 1, 1973• 49 citations
Publisher

Abstract

The specific heat at constant density of an ideal-Bose-fluid film of thickness $L=l{\ensuremath{\rho}}^{\ensuremath{-}\frac{1}{3}}$, but infinite lateral extent, is calculated analytically to order ${l}^{\ensuremath{-}2}$. Both hard-wall and periodic boundary conditions are considered. Good agreement with the numerical calculations of Goble and Trainor for the total specific heat under hard-wall conditions is obtained down to $l\ensuremath{\simeq}10$. In the critical region, the large-$l$ behavior accords with the scaling theory of finite-size effects. The appropriate scaling functions and the surface specific heat are explicitly calculated.

DOI
10.1103/physreva.8.1124

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The specific heat at constant density of an ideal-Bose-fluid film of thickness L=l\ensuremathρ\ensuremath−13L=l{\ensuremath{\rho}}^{\ensuremath{-}\frac{1}{3}}L=l\ensuremathρ\ensuremath−31​, but infinite lateral extent, is calculated analytically to order l\ensuremath−2{l}^{\ensuremath{-}2}l\ensuremath−2. Both hard-wall and periodic boundary conditions are considered. Good agreement with the numerical calculations of Goble and Trainor for the total specific heat under hard-wall conditions is obtained down to l\ensuremath≃10l\ensuremath{\simeq}10l\ensuremath≃10. In the critical region, the large-lll behavior accords with the scaling theory of finite-size effects. The appropriate scaling functions and the surface specific heat are explicitly calculated.
The grand potential pressure of an ideal boson film which is infinite in d-1 dimensions (d > 2) but of finite thickness L in the dth dimension is analysed in the limit L -+ CX), to order L -d. Across the film (i) periodic, (ii) antiperiodic, and (iii) hard wall boundary conditions are applied. The corresponding shifts in the critical temperature Te.iL) are found to vary, for large L, as (i) L -d+2 for all d ;;:. 3, (ii) L-1, L -2lnL, and L -2 for d = 3,4, and ;;:. 5 respectively, and (iii) L -1lnL and L -1 for d = 3 and ;;:. 4. With hard wall boundary conditions, the critical temperature of a sufficiently thick film exceeds that of the bulk, while the other boundary conditions depress Te. The bulk critical region is asymptotically "rounded" on a scale set by the bulk correlation length matching the thickness L in accord with the scaling theory of finite-size effects.
Our previous evaluation of the specific heat of an ideal Bose gas confined to a thin-film geometry is extended to second order in (l‾D\frac{\overline{l}}{D}Dl​), where l‾\overline{l}l is the mean interparticle distance. Explicit expressions, involving a dimensionless parameter yyy, are obtained both for the specific heat of the system and for the temperature at which the specific heat is maximum. Occurrence of the parameter yyy, which is a measure of the chemical potential of the system in terms of the spacing of the single-particle energy levels, enables us to cast our expression for the specific heat of the system into a form consistent with the scaling theory of Fisher and Barber. Our results for the specific-heat maximum, as a function of (Dl‾\frac{D}{\overline{l}}lD​), are a considerable improvement over the first-order ones reported earlier, and have come remarkably close to the ones obtained numerically by Goble and Trainor.
The specific heat of an ideal semi-infinite ($\ensuremath{\infty}\ifmmode\times\else\texttimes\fi{}\ensuremath{\infty}\ifmmode\times\else\texttimes\fi{}D$) Bose gas is calculated numerically using a number of boundary conditions. The results provide a suitable comparison with the analytical calculations of Fisher and Barber and of Pathria. The agreement is very good except for the Neumann boundary condition where the numerical result shows deviation from that of Pathria. However, the earlier assumption of the existence of a "correlation length" appears to have little physical basis. For the hard-wall case, the anomaly in the specific heat is probably due to constraint on particle density. The distinctive effect of such a boundary condition (${\ensuremath{\Psi}}_{s}=0$) is explored more thoroughly in maximal assemblies ($L\ifmmode\times\else\texttimes\fi{}L\ifmmode\times\else\texttimes\fi{}D$) where its effect on specific heat shows up prominently.
An asymptotic evaluation of the specific heat of an ideal Bose gas confined to a thin-film geometry ($\ensuremath{\infty}\ifmmode\times\else\texttimes\fi{}\ensuremath{\infty}\ifmmode\times\else\texttimes\fi{}D$) is carried out, under a variety of boundary conditions, without converting summations into integrations. The theoretical results for the Dirichlet boundary conditions (${\ensuremath{\psi}}_{S}=0$) contain all the significant features of the numerical results obtained earlier by Goble and Trainor; in particular, we reproduce the characteristic length D∗{D}^{*}D∗ at which the specific heat of the system is at an absolute maximum. It turns out that D∗{D}^{*}D∗ is directly proportional to the mean interparticle distance l‾\overline{l}l, with a constant of proportionality $c(\ensuremath{\approx}20\ensuremath{-}30)$. No such characteristic length appears if boundary conditions other than Dirichlet's are employed. The shift, and the rounding off, of the specific-heat maximum are also studied, and the distinguishing influence of the boundary conditions examined.
Critical phenomena in films of finite thickness are considered. A detailed scaling theory, with allowance for distinct exponents $\ensuremath{\lambda}$ and $\ensuremath{\theta}=\frac{1}{\ensuremath{\nu}}$ for the critical-point shift and rounding, respectively, is confirmed by exact calculations on ddd-dimensional ferromagnetic spherical models and ideal Bose fluids with various boundary conditions. Isingmodel results and existing data on real helium films are consistent with the theory.
The recent observation by Hasan and Goble of a discrepancy between their numerical results on the specific heat of an ideal Bose gas confined to a thin-film geometry and the earlier analytic calculations of Pathria employing Neumann boundary conditions is shown to be unjustified. In those cases where a true comparison is possible, e.g., under Dirichlet or periodic boundary conditions, the observed deviations turn out to be insignificant if one uses the more recent second-order calculations of Greenspoon and Pathria rather than the original first-order ones of Pathria. For comparison under Neumann boundary conditions, fresh numerical calculations are required. We also present here second-order analytic calculations of the specific heat of this system (i) under mixed boundary conditions (Dirichlet on one wall, Neumann on the other) and (ii) under antiperiodic boundary conditions, and compare them with the relevant numerical calculations of Hasan and Goble.