Hamiltonian Dynamics and the Schrodinger Equation

Jan J., Vasyl Kovalchuk

Schrödinger Equation as a Hamiltonian System, Essential Nonlinearity, Dynamical Scalar Product and some Ideas of Decoherence

Abraham Nitzan

This chapter focuses on the time-dependent Schrödinger equation and its solutions for several prototype systems. It provides the basis for discussing and understanding quantum dynamics in condensed phases, however, a full picture can be obtained only by including also dynamical processes that destroy the quantum mechanical phase. Such a full description of quantum dynamics cannot be handled by the Schrödinger equation alone; a more general approach based on the quantum Liouville equation is needed. This important part of the theory of quantum dynamics is discussed in Chapter 10. Given a system characterized by a Hamiltonian Ĥ , the time-dependent Schrödinger equation is For a closed, isolated system Ĥ is time independent; time dependence in the Hamiltonian enters via effect of time-dependent external forces. Here we focus on the earlier case. Equation (1) is a first-order linear differential equation that can be solved as an initial value problem.

Benjamin Liebowitz

Swagat Kumar, Colin Wilmott

The Schrödinger equation describes how quantum states evolve according to the Hamiltonian of the system. For physical systems, we have it that the Hamiltonian must be a Hermitian operator to ensure unitary dynamics. For anti-Hermitian Hamiltonians, the Schrödinger equation instead models the evolution of quantum states in imaginary time. This process of imaginary time evolution has been used successfully to calculate the ground state of a quantum system. Although imaginary time evolution is non-unitary, the normalised dynamics of this evolution can be simulated on a quantum computer using the quantum imaginary time evolution (QITE) algorithm. In this paper, we broaden the scope of QITE by removing its restriction to anti-Hermitian Hamiltonians, which allows us to solve any partial differential equation (PDE) that is equivalent to the Schrödinger equation with an arbitrary, non-Hermitian Hamiltonian. An example of such a PDE is the famous Black-Scholes equation that models the price of financial derivatives. We will demonstrate how our generalised QITE methodology offers a feasible approach for real-world applications by using it to price various European option contracts modelled according to the Black-Scholes equation.