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The Journal of Chemical Physics

Wigner phase-space description of a Morse oscillator

Hai-Woong Lee, Marlan O. Scully

Published Nov 1, 1982• 72 citations
Publisher

Abstract

Quantum and classical dynamics of a Morse oscillator are investigated in a phase space using the Wigner distribution function. The phase-space description offers a pictorial representation of quantum dynamics in terms of trajectories. Based on the comparison of these trajectories with classical trajectories, a systematic scheme accurately describing quantum dynamics is presented.

DOI
10.1063/1.444412

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Phase space is the unity of position and momentum configuration space. It allows for an effective description of dynamical systems and is particularly useful when it comes to studying chaos theory and statistical mechanics. After the advent of quantum physics early in the 20th century, E. Wigner [91], J. E. Moyal [62] and H. J. Groenewold [31] introduce a quantum theory in phase space. Despite the apparent added complexity of the mathematics involved in this new framework, the underlying classical and quantum equations show many similarities. The probability distribution in classical physics becomes the Wigner distribution, a probability distribution usually featuring negative values. In 2013, O. Steuernagel and D. Kakofengitis, inspired by the work of H. Bauke [7] and E. Wigner [91], identified the quantum analogue of the classical phase space flow: the Wigner current J [83]. This Wigner current allows the visualisation of quantum dynamics through a quantum fluid dynamics perspective in phase space. This thesis is written by collection of five articles. They are prefaced by an introduction into the basics of quantum phase space theory and its link with both classical phase space dynamics and the standard Schrödinger approach, followed by the articles published during this PhD. Article 1 shows the importance of the integral form of the Wigner current. We use it to derive the Ehrenfest’s theorem, as well as to refute some propositions made within the community. Article 2 shows that, using the Wigner current, an Eulerian and Lagrangian point of view do not always give the same results for the quantum case. We demonstrate that the negativities of the Wigner distribution, sign of quantumness of the system, are created by the Wigner velocity field singularities. The Wigner velocity field is the quantum analogue of the classical phase space velocity field. In Article 3, we see that even though Wigner distributions of quantum systems feature spotty structures which saturate on scales ɑZ [97], the construction of a superoscillating Wigner distribution allows one to generate much smaller structures, of the order of ɑZ /α with α a positive constant potentially very large. In Article 4, we introduce the concept of quantum shear suppression in phase space. The Wigner current features an effective quantum “viscosity”, suppressing classical dynamics fine details. This viscosity is the mechanism by which the Zurek scale is enforced dynamically onto the state in phase space. In Article 5, we apply the previous ideas to Kerr-type oscillators. Its Wigner current is derived, and using it we show that its values are conserved on a ring during the time evolution of the Kerr oscillator. The shear suppression is also studied.

•May 30, 2019•1 citation
Quantum and classical dynamics of a Morse oscillator are investigated in a phase space using the Wigner distribution function. The phase-space description offers a pictorial representation of quantum dynamics in terms of trajectories. Based on the comparison of these trajectories with classical trajectories, a systematic scheme accurately describing quantum dynamics is presented.
Abstract In this article, the rotating Kratzer oscillator in quantum phase space is studied. The Langer transformation is used to map the Kratzer oscillator with centrifugal term onto a one‐dimensional Morse oscillator. As a result, the Wigner distribution functions for the Morse oscillator are obtained. The quantum states of the system are visualized in the phase space for a few vibrational and rotational quantum numbers. The results obtained in the phase space correspond to those derived in the standard quantum theory. © 2009 Wiley Periodicals, Inc. Int J Quantum Chem, 2010
In this lecture, a limited introduction of gauge invariance in phase-space is provided, predicated on canonical transformations in quantum phase-space. Exact characteristic trajectories are also specified for the time-propagating Wigner phase-space distribution function: they are especially simple – indeed, classical – for the quantized simple harmonic oscillator. This serves as the underpinning of the field theoretic Wigner functional formulation introduced. Scalar field theory is thus reformulated in terms of distributions in field phase-space. This is a pedagogical selection from work published in Refs. 1) and 2).
Phase space is the unity of position and momentum configuration space. It allows for an effective description of dynamical systems and is particularly useful when it comes to studying chaos theory and statistical mechanics. After the advent of quantum physics early in the 20th century, E. Wigner [91], J. E. Moyal [62] and H. J. Groenewold [31] introduce a quantum theory in phase space. Despite the apparent added complexity of the mathematics involved in this new framework, the underlying classical and quantum equations show many similarities. The probability distribution in classical physics becomes the Wigner distribution, a probability distribution usually featuring negative values. In 2013, O. Steuernagel and D. Kakofengitis, inspired by the work of H. Bauke [7] and E. Wigner [91], identified the quantum analogue of the classical phase space flow: the Wigner current J [83]. This Wigner current allows the visualisation of quantum dynamics through a quantum fluid dynamics perspective in phase space. This thesis is written by collection of five articles. They are prefaced by an introduction into the basics of quantum phase space theory and its link with both classical phase space dynamics and the standard Schrödinger approach, followed by the articles published during this PhD. Article 1 shows the importance of the integral form of the Wigner current. We use it to derive the Ehrenfest’s theorem, as well as to refute some propositions made within the community. Article 2 shows that, using the Wigner current, an Eulerian and Lagrangian point of view do not always give the same results for the quantum case. We demonstrate that the negativities of the Wigner distribution, sign of quantumness of the system, are created by the Wigner velocity field singularities. The Wigner velocity field is the quantum analogue of the classical phase space velocity field. In Article 3, we see that even though Wigner distributions of quantum systems feature spotty structures which saturate on scales ɑZ [97], the construction of a superoscillating Wigner distribution allows one to generate much smaller structures, of the order of ɑZ /α with α a positive constant potentially very large. In Article 4, we introduce the concept of quantum shear suppression in phase space. The Wigner current features an effective quantum “viscosity”, suppressing classical dynamics fine details. This viscosity is the mechanism by which the Zurek scale is enforced dynamically onto the state in phase space. In Article 5, we apply the previous ideas to Kerr-type oscillators. Its Wigner current is derived, and using it we show that its values are conserved on a ring during the time evolution of the Kerr oscillator. The shear suppression is also studied.