An exact Hamiltonian formulation of nonrelativistic quantum mechanics that simplifies to ordinary classical mechanics as \ensuremath{\Elzxh}\ensuremath{\rightarrow}0 is presented. The theory allows one to treat a quantum system as the corresponding classical system mechanically connected to an infinite number of additional classical degrees of freedom. The onset of quantum effects such as tunneling and interference results from the mechanical interactions between the different parts of the overall infinite system. The formalism is applied to the one-dimensional motion of a particle in a symmetric double well. It is shown that the tunneling in that system involves multidimensional classical motion that circumvents the barrier.
An exact Hamiltonian formulation of nonrelativistic quantum mechanics that simplifies to ordinary classical mechanics as \ensuremath{\Elzxh}\ensuremath{\rightarrow}0 is presented. The theory allows one to treat a quantum system as the corresponding classical system mechanically connected to an infinite number of additional classical degrees of freedom. The onset of quantum effects such as tunneling and interference results from the mechanical interactions between the different parts of the overall infinite system. The formalism is applied to the one-dimensional motion of a particle in a symmetric double well. It is shown that the tunneling in that system involves multidimensional classical motion that circumvents the barrier.
It is shown that application of the time-dependent variational principle to trial wave functions of a particular form results in a description of the quantum system as a classical system consisting of two mutually interacting parts: the ordinary classical analog of the quantum system and a (generally finite) number of additional degrees of freedom. This holds out the prospect of simulating quantum dynamics by coupling the corresponding classical system to additional degrees of freedom, and it is pointed out that such calculations have, in effect, already been performed. Since the trial wave functions that qualify for this treatment may be arbitrarily accurate, there is no limitation to the accuracy of the resulting classical description. In a particular case, the canonical coordinates and momenta for all degrees of freedom of the overall classical system are identified and investigated. In general, certain parameters appearing in the trial wave functions treated in this work may become redundant at certain times, leading to singularities in the Hamiltonian equations of motion. It is shown, however, that in certain such cases, a classical formalism for the quantum dynamics remains valid if the Hamiltonian function is suitably modified. Calculations applying the present Hamiltonian formalism are carried out that demonstrate that it has better convergence properties than an alternative, nonvariational, Hamiltonian technique suggested by previous work. These numerical studies also suggest that the observed spreading of wave packets and development of complicated structure in wave functions may be interpreted classically in terms of energy transfer among the various degrees of freedom in the overall classical system.
Quantum-classical mixing is studied by a group-theoretical approach, and a quantum-classical equation of motion is derived. The quantum-classical bracket entering the equation preserves the Lie algebra structure of quantum and classical mechanics, and, therefore, leads to a natural description of interaction between quantum and classical degrees of freedom. The exact formalism is applied to coupled quantum and classical oscillators. Various approximations, such as the mean-field and the multiconfiguration mean-field approaches, which are of great utility in studying realistic multidimensional systems, are derived. Based on the formulation, a natural classification of the previously suggested quantum-classical equations of motion arises, and several problems from earlier works are resolved.
A new method for the quantization of classical Hamiltonian systems is presented. This method is based upon the correspondence between the Liouville formulation of classical mechanics and the Liouville–von Neumann formulation of quantum mechanics. It does not distinguish between integrable and nonintegrable systems, and consequently, is equally applicable to both types of systems. Further, it treats the indistinguishability of identical particles correctly, and thus, the semiclassical eigenstates have the correct symmetry properties. Application of the method is illustrated by a series of examples. The results are in excellent agreement with quantum mechanics and represent an improvement over results obtained using the uniform semiclassical approximation.
The formal mathematical structure of the truly Hamiltonian formulations of nonrelativistic and relativistic quantum mechanics is critically examined for both spin 0 and spin 12 particles with nonzero mass. It is shown that the relativistic quantum mechanics can, in principle, at least be fitted into a truly covariant Hamiltonian procedure where the Hamiltonian is a Lorentz-invariant world scalar (and is the negative of 12 the rest energy of the particle, regardless of its spin). In particular, a truly covariant Hamiltonian theory of the electron is presented. It will be seen that the Lorentz-invariant Dirac theory of the electron does not fall within the framework of a truly covariant Hamiltonian procedure. Further, the dynamical variables associated with the translational degree of freedom of the particle (such as the position, the canonical momentum, and the velocity four-vectors of the relativistic quantum mechanics) correspond precisely to the same variables of the truly covariant formulation of relativistic classical mechanics. The mathematical structure of relativistic quantum mechanics is seen to be rather similar to that of nonrelativistic quantum mechanics for both spin 0 and spin 12 particles with nonzero mass.
In this initial paper in a series, we first discuss why classical motions of small particles should be treated statistically. Then we show that any attempted statistical description of any nonrelativistic classical system inevitably yields the multi-coordinate Schrödinger equation, with its usual boundary conditions, as an essential statistical equation for the system. We derive the general "canonical quantization" rule, that the Hamiltonian operator must be the classical Hamiltonian in the N-dimensional metric configuration space defined by the classical kinetic energy of the system, with the classical conjugate momentum N-vector replaced by −iℏ times the vector gradient operator in that space. We obtain these results by using conservation of probability, general tensor calculus, the Madelung transform, the Ehrenfest theorem and/or the Hamilton-Jacobi equation, and comparison with results for the charged harmonic oscillator in stochastic electrodynamics. We also provide two illustrative examples and a discussion of how coordinate trajectories could be compatible with wave properties such as interference, diffraction, and tunneling.
The objective of this series of three papers is to axiomatically derive quantum mechanics from classical mechanics and two other basic axioms. In this first paper, Schroedinger's equation for the density matrix is fist obtained and from it Schroedinger's equation for the wave functions is derived. The momentum and position operators acting upon the density matrix are defined and it is then demonstrated that they commute. Pauli's equation for the density matrix is also obtained. A statistical potential formally identical to the quantum potential of Bohm's hidden variable theory is introduced, and this quantum potential is reinterpreted through the formalism here proposed. It is shown that, for dispersion free {\\it ensembles% }, Schroedinger's equation for the density matrix is equivalent to Newton's equations. A general non-ambiguous procedure for the construction of operators which act upon the density matrix is presented. It is also shown how these operators can be reduced to those which act upon the wave functions.