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Applied Physics Letters

Observation of gain in the violet bands of sodium vapor

John T. Bahns, William C. Stwalley

Published May 1, 1984• 45 citations
Publisher

Abstract

We report our observations attributable to optical gain through stimulated emission in the violet when sodium vapor is optically pumped with the 350.7-nm line of a krypton ion laser. In addition we present the accompanying fluorescence spectrum which shows previously unreported discrete structure on the short wavelength side of the violet bands.

DOI
10.1063/1.94954

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We report our observations attributable to optical gain through stimulated emission in the violet when sodium vapor is optically pumped with the 350.7-nm line of a krypton ion laser. In addition we present the accompanying fluorescence spectrum which shows previously unreported discrete structure on the short wavelength side of the violet bands.
This paper reports the UV and violet diffuse band radiation generated by two-photon pumping in Na2 by focusing the pumping beam (~ 10 mJ) from a pulsed dye laser into a heat-pipe oven containing sodium. Measurable forward stimulated diffuse band radiation existed at 350.0-385.0 nm and 405.0-460.0 nm over the whole pumping region from 620.0 to 670.0 nm. The radiation corresponded to transitions from different high-lying triplet g states to the lowest triplet state. The signal intensity related to the pumping wavelength. The stronger signals were there where two-photon pumping was enhanced by singlet-triplet mixing levels. The weaker signals were assumed to relate to the collisions either transferring energy from the A ′ Σ u + to the b3Π g state after the first photon excitation and then pumped by the second photon excitation from the b3Π g state to a high-lying state, or were due to collisional transfer from a high-lying singlet to a nearby triplet state.
The formation of Na+{\mathrm{Na}}^{+}Na+ and Na2+{\mathrm{Na}}_{2}^{+}Na2+​ in laser-irradiated sodium vapor has been studied using a nitrogen-laser-pumped dye laser. The effects of irradiation by this pulsed laser are substantially different from those reported previously using a cw device, but otherwise identical experimental conditions. In contrast to the earlier experiments, in which ions were observed only when the cw laser was tuned to a DDD line, relatively large "background" ion signals are observed at all excitation wavelengths, a result of multiphoton processes involving the Na2{\mathrm{Na}}_{2}Na2​ component of the vapor. It is shown that the laser bandwidth and pulse duration are extremely important parameters; a wide bandwidth effectively magnifying the importance of the dimer component of the vapor and a short pulse duration minimizing the effects of interactions between excited atoms and molecules.