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Annalen der Physik

The velocity of probability transport in quantum mechanics

G.F. Melloy, Anthony J. Bracken

Published Dec 1, 1998• 20 citations
Publisher

Abstract

In his study of the ‘time of arrival’ problem in the nonrelativistic quantum mechanics of a single particle, Allcock [1] noted that the direction of the probability flux vector is not necessarily the same as that of the mean momentum of a wave packet, even when the packet is composed entirely of plane waves with a common direction of momentum. Packets can be constructed, for example for a particle moving under a constant force, in which probability flows for a finite time in the opposite direction to the momentum. A similar phenomenon occurs for the Dirac electron. The maximum amount of probabilitiy backflow which can occur over a given time interval can be calculated in each case.

DOI
10.1002/(sici)1521-3889(199812)7:7/8<726::aid-andp726>3.0.co;2-p

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In his study of the ‘time of arrival’ problem in the nonrelativistic quantum mechanics of a single particle, Allcock [1] noted that the direction of the probability flux vector is not necessarily the same as that of the mean momentum of a wave packet, even when the packet is composed entirely of plane waves with a common direction of momentum. Packets can be constructed, for example for a particle moving under a constant force, in which probability flows for a finite time in the opposite direction to the momentum. A similar phenomenon occurs for the Dirac electron. The maximum amount of probabilitiy backflow which can occur over a given time interval can be calculated in each case.
Abstract In his study of the ‘time of arrival’ problem in the nonrelativistic quantum mechanics of a single particle, Allcock [1] noted that the direction of the probability flux vector is not necessarily the same as that of the mean momentum of a wave packet, even when the packet is composed entirely of plane waves with a common direction of momentum. Packets can be constructed, for example for a particle moving under a constant force, in which probability flows for a finite time in the opposite direction to the momentum. A similar phenomenon occurs for the Dirac electron. The maximum amount of probabilitiy backflow which can occur over a given time interval can be calculated in each case.
It is known that for a non-relativistic quantum particle traveling freely on the xxx-axis, the positional probability can flow in the opposite direction to the particle's velocity. The maximum possible amount of such backflow that can occur over any time interval has been determined previously as the largest positive eigenvalue of a certain hermitian observable, with the value 0.0384517…0.0384517\dots0.0384517…, or about 4%4\%4% of the total probability on the line. The eigenvalue problem is now considered numerically in the more general case of states with momentum restricted to the range $p_0
Pure states of a free particle in non-relativistic quantum mechanics are described, in which the probability of finding the particle to have a negative x-coordinate increases over an arbitrarily long, but finite, time interval, even though the x-component of the particle's velocity is certainly positive throughout that time interval. It is shown that, for any state of this type, the greatest amount of probability which can flow back from positive to negative x-values in this counter-intuitive way, over any given time interval, is equal to the largest eigenvalue of a certain Hermitian operator, and it is estimated numerically to have a value near 0.04. This value is not only independent of the length of the time interval and the mass of the particle, but is also independent of the value of Planck's constant. It reflects the structure of Schrodinger's equation, rather than the values of the parameters appearing there. Backflow of positive probability is related to the non-positivity of Wigner's density function, and can be regarded as arising from a flow of negative probability in the same direction as the velocity. Generalizations are indicated, to the relativistic free electron, and to non-relativistic cases in which probability backflow occurs even in opposition to an arbitrarily strong constant force.
Classical mechanics traces a particle’s movement through space and time through x(t). For example, one may consider the case of a particle moving at constant speed (momentum p) in one direction or a particle bouncing back and forth at constant speed in a box. These problems are described in time and have direction and position associated with time etc. It is possible to define a probability P(x,t) in the classical picture based on delta time, the amount of time a particle spends in a little region of space dx. P(x,t), by itself, loses much relevant information present in the x(t) scenario because a particle moving to the right, or to the left, or bouncing back and forth all have the same probability, 1/L, where L is length. Furthermore, this probability is the same for all p (momentum) values. Thus a probability description, without extra information, is a subset of the relevant information in the problem. As a result, to describe the classical picture fully, one might say that a particle has a probability of 1/L, but also a mass mo and velocity +v (i.e. momentum mov nonrelativistically). For the particle bouncing back and forth in a box with constant p, one needs to give the initial position at time=0 and then a subsequent time (as well as the initial velocity and mo) in order to fully describe the problem, even though probability = 1/L. In the literature (see (1)), there have been many attempts to derive the quantum Schrodinger equation from a classical Fockker-Planck equation or a continuity equation (which follows from the Fokker-Planck equation as shown in (1)). The continuity equation contains a probability P(x,t) and a velocity(x,t) and is generally argued to represent classical physics. It does, if one retains appropriate classical conditions such as the discontinuity of density for a particle in a box (i.e. density=0 outside the box, but 1/L inside) and the notion of differing directions within the box. In fact, one may write density=W*(x,t)W(x,t) where W(x,t) is an ad hoc complex function and still retain compatibility with classical physics. If one does not, however, retain the classical conditions completely, nonclassical physics is introduced, even if density(x,t)=1/L. For example, in quantum mechanics density(x) is considered to be continuous in all x. Thus for a particle moving in a box, density outside the box is 0 so at the box wall it must also be 0. In the classical case, the density is 1 inside the box and 0 outside. There is a discontinuity classically and this cannot be changed and this contradicts the quantum mechanical picture. Thus quantum mechanics does not follow form classical Fokker-Planck or continuity equations which retain classical conditions.. Furthermore, because time is completely removed in the FP-continuity approach as applied to quantum mechanics, one cannot distinguish between forwards and backwards motion. As seen by the velocity field given in (1), v is zero for a bound particle which completely removes the sense of time and violates the classical physics conditions. It is, however, not zero for a particle moving in one direction. Thus there seems to be no issue in describing a Fokker-Planck-continuity equation as describing classical physics. One may even introduce density(x,t)= W*(x,t)W(x,t) provided one retains classical conditions allowing for discontinuity in density and different W(x,t) values at different times i.e. a discontinuity in W(x,t) at a box wall. If these conditions, however, are not met, then one no longer describes classical physics, but a new kind of physics (quantum physics). Thus one cannot argue that quantum mechanics follows from classical statistical Fokker-Planck-continuity equations. It may follow from these if one adds a set of extra conditions. Given these extra conditions, however, one could derive quantum mechanics without starting with classical density.
Quantum backflow is a counterintuitive phenomenon in which the probability density of a quantum particle propagates opposite to its momentum. Experimental observation of backflow has remained elusive due to two main challenges: (i) the effect is intrinsically small, with less than 4% of the probability able to flow backward, and (ii) it requires wave packets with a well-defined momentum direction, which are difficult both to prepare and to verify under realistic, noisy conditions. Here, we overcome these challenges by introducing a general formulation of quantum backflow applicable to arbitrary momentum distributions. The framework recovers the standard backflow limit for unidirectional states and identifies general backflow as probability flow exceeding that predicted by the particle's momentum distribution alone. We show that this excess can reach nearly 13%, surpassing the standard backflow bound by more than a factor of three. Furthermore, we extend the framework to the closely related phenomenon of quantum reentry, provide explicit examples of quantum states exhibiting large general backflow and reentry, and discuss the foundational implications of these nonclassical effects. Our results open a pathway toward the experimental observation of quantum backflow in realistic settings.
The usual textbook discussions of the velocity and spreading of a wave packet are based on special cases and approximations which have a limited range of validity. In this paper more general relations are obtained by considering the time dependence of the moments of a wave packet. Both a packet of real sinusoidal plane waves (a real pulse, e.g., sound) and a packet of complex exponential plane waves (e.g., the quantum-mechanical wave function of a free particle) are considered. The results are similar if the real wave packet contains no standing wave components. It is shown that the centroid of a wave packet moves at a constant velocity which is a weighted average of the group velocity. The spreading of the wave packet depends on the product of the variance of the group velocity and the square of the time interval before or after the time of minimum packet width. The packet moves and spreads like a collection of particles in free flight, in which the velocities of the particles are the group velocities of the wave components of the packet.