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Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

Quantum time scales and the classical limit: Analytic results for some simple systems

Adélcio C. Oliveira, Maria Carolina Nemes, K. M. Fonseca-Romero

Published Sep 23, 2003• 29 citations
Publisher

Abstract

We set up a semiclassical approximation which helps us clarify by means of several simple examples the rich variety of time scale in the quantum domain. The underlying structure of quantum and classical mechanics is so completly different that it is naive to expect to reach a classical regime by counting powers of the quantum scale variant Planck's over 2pi. We show although it is possible to define a time scale for nonclassical phenomena, but it is impossible to characterize quantum dynamics through a unique time scale, such as Ehrenfest's time. We use simple systems to critically discuss and illustrate these features of the quantum-classical limit.

DOI
10.1103/physreve.68.036214

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We set up a semiclassical approximation which helps us clarify by means of several simple examples the rich variety of time scale in the quantum domain. The underlying structure of quantum and classical mechanics is so completly different that it is naive to expect to reach a classical regime by counting powers of the quantum scale variant Planck's over 2pi. We show although it is possible to define a time scale for nonclassical phenomena, but it is impossible to characterize quantum dynamics through a unique time scale, such as Ehrenfest's time. We use simple systems to critically discuss and illustrate these features of the quantum-classical limit.
Different classical limits of quantum mechanics are discussed in the setting of a simple example, the two-dimensional motion of a spinless electron in a uniform magnetic field. Both the time-independent energy eigenstates and the time-dependent states developing from initial localized states are exactly solvable. In the first example, an ℏ→0 limit with fixed energy leads to a simple ensemble of classical orbits. In the second, ℏ→0 with fixed initial mean position and momentum leads to a unique classical orbit.
The quantum dynamics of a classically chaotic model are studied in the approach to the macroscopic limit. The quantum predictions are compared and contrasted with the classical predictions of both Newtonian and Liouville mechanics. The time-domain scaling of the optimal quantum-classical correspondence is analyzed in detail in the case of both classical theories. In both cases the correspondence for observable quantities is shown to break down on a time-scale that increases very slowly (logarithmically) with increasing system size. In the case of quantum-Liouville correspondence such a short time-scale does not imply a breakdown of correspondence since the largest quantum-Liouville differences reached on this time-scale decrease rapidly (as an inverse power) with increasing system size. Therefore the statistical properties of chaotic dynamics are, as expected, well described by quantum theory in the macroscopic limit. In contrast, the largest quantum-Newtonian differences reached on the log time-scale actually increase in proportion to the system size. Since the invariance properties of the Hamiltonian impose functional constraints on the time-varying chaotic coordinates, it is possible to show, moreover, that if the quantum predictions are believed to describe the coordinates of individual chaotic systems, then they also predict macroscopic violations of any kinematic or dynamic constants of the motion. These results for chaotic systems indicate that a valid description of the time-varying properties of individual macroscopic bodies is not available within the standard interpretive framework of quantum theory.
A classical limit of quantum dynamics can be defined by compensation of the quantum potential in the time-dependent Schrödinger equation. The quantum potential is a non-local quantity, defined in the trajectory-based form of the Schrödinger equation, due to Madelung, de Broglie, and Bohm, which formally generates the quantum-mechanical features in dynamics. Selective inclusion of the quantum potential for the degrees of freedom deemed "quantum," defines a hybrid quantum/classical dynamics, appropriate for molecular systems comprised of light and heavy nuclei. The wavefunction is associated with all of the nuclei, and the Ehrenfest, or mean-field, averaging of the force acting on the classical degrees of freedom, typical of the mixed quantum/classical methods, is avoided. The hybrid approach is used to examine evolution of light/heavy systems in the harmonic and double-well potentials, using conventional grid-based and approximate quantum-trajectory time propagation. The approximate quantum force is defined on spatial domains, which removes unphysical coupling of the wavefunction fragments corresponding to distinct classical channels or configurations. The quantum potential, associated with the quantum particle, generates forces acting on both quantum and classical particles to describe the backreaction.
A system of atoms interacting with a radiation field in a resonant cavity is studied under conditions when the dynamics in the classical limit is stochastic. This situation is called quantum chaos. Equations of motion are obtained for the quantum-mechanical expectation values which take into account the quantum correlation functions. It is shown that in a situation corresponding to quantum chaos, the quantum corrections grow exponentially, making the evolution of the system essentially quantal after a certain time tau( variant Planck's over 2pi ) has elapsed. Analytical and numerical analysis show that in this regime the time tau( variant Planck's over 2pi ) obeys the logarithmic law tau( variant Planck's over 2pi ) approximately ln N (N is the number of atoms), and not the law tau( variant Planck's over 2pi ) approximately N(alpha) (alpha is a certain constant of order unity), as would be the case in the absence of chaos.
I argue that it is possible to give an interpretation of the classical ℏ→0 limit of quantum mechanics that results in a partial explanation of the success of classical mechanics. The interpretation is novel in that it allows one to explain the success of the theoretical structure of classical mechanics. This interpretation clarifies the relationship between physical quantities and propositions in quantum theories and provides a precise notion of a quantum theory holding “approximately on certain scales.”
The standard notion of a classical limit, represented schematically by ℏ→0 , provides a method for approximating a quantum system by a classical one. In this work, we explain why the standard classical limit fails when applied to subsystems, and show how one may resolve this by explicitly modeling the decoherence of a subsystem by its environment. Denoting the decoherence time by τ , we demonstrate that a double scaling limit in which ℏ→0 and τ→0 such that the ratio Ef=ℏ/τ remains fixed leads to an irreversible open-system evolution with well-defined classical and quantum subsystems. The main technical result is showing that, for arbitrary Hamiltonians, the generators of partial versions of the Wigner, Husimi, and Glauber-Sudarshan quasiprobability distributions may all be mapped in the above-mentioned double scaling limit to the same completely positive classical-quantum generator. This provides a regime in which one can study effective and consistent classical-quantum dynamics. Published by the American Physical Society 2024