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Journal of Experimental and Theoretical Physics

Calculation of the wave functions of the ground and weakly excited states of helium II

Maksim Tomchenko

Published Jan 1, 2006• 2 citations
Publisher

Abstract

The wave functions of the ground (Ψ 0 ) and the first excited (Ψ k ) states of He II in the second-order approximation, i.e., up to the first two corrections to the corresponding solutions for a weakly nonideal Bose gas, are determined by the collective variable method, which was proposed by Bogolyubov and Zubarev and developed in the studies by Yukhnovskii and Vakarchuk. The functions Ψ 0 and Ψ k = ψ k Ψ 0 are determined as the eigenfunctions of the N -particle Schrödinger equation from a system of coupled equations for Ψ 0 , Ψ k , and the quasiparticle spectrum E ( k ) of helium II. The results consist in the following: (1) these equations are solved numerically for a higher order approximation compared with those investigated earlier (the first-order approximation), and (2) Ψ 0 and ψ k are derived from a model potential of interaction between He 4 atoms (rather than from the structure factor as earlier) in which the potential barrier is joined with the attractive potential found from experiment. The height V 0 of the potential barrier is a free parameter. Except for V 0 , the model does not have any free parameters or functions. The calculated values of the structure factor, the ground-state energy E 0 , and the quasiparticle spectrum E ( k ) of He II are in agreement with the experimental values for V 0 ≈ 100 K. The second-order correction to the logarithm of Ψ 0 significantly affects the value of E 0 and provides the asymptotics E ( k → 0) = ck , while the second-order correction to ψ k slightly affects the E ( k ). The second-order corrections to Ψ 0 and ψ k have a smaller effect on the results compared with the first-order corrections, whereby the theory is in agreement with experiment; therefore, one may assume that the truncated Ψ 0 and ψ k well describe the microstructure of He II. Thus, the series for Ψ 0 and Ψ k can be truncated in spite of the fact that the expansion parameter is not very small (∼1/2).

DOI
10.1134/s106377610601016x

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The wave functions of the ground (Ψ 0 ) and the first excited (Ψ k ) states of He II in the second-order approximation, i.e., up to the first two corrections to the corresponding solutions for a weakly nonideal Bose gas, are determined by the collective variable method, which was proposed by Bogolyubov and Zubarev and developed in the studies by Yukhnovskii and Vakarchuk. The functions Ψ 0 and Ψ k = ψ k Ψ 0 are determined as the eigenfunctions of the N -particle Schrödinger equation from a system of coupled equations for Ψ 0 , Ψ k , and the quasiparticle spectrum E ( k ) of helium II. The results consist in the following: (1) these equations are solved numerically for a higher order approximation compared with those investigated earlier (the first-order approximation), and (2) Ψ 0 and ψ k are derived from a model potential of interaction between He 4 atoms (rather than from the structure factor as earlier) in which the potential barrier is joined with the attractive potential found from experiment. The height V 0 of the potential barrier is a free parameter. Except for V 0 , the model does not have any free parameters or functions. The calculated values of the structure factor, the ground-state energy E 0 , and the quasiparticle spectrum E ( k ) of He II are in agreement with the experimental values for V 0 ≈ 100 K. The second-order correction to the logarithm of Ψ 0 significantly affects the value of E 0 and provides the asymptotics E ( k → 0) = ck , while the second-order correction to ψ k slightly affects the E ( k ). The second-order corrections to Ψ 0 and ψ k have a smaller effect on the results compared with the first-order corrections, whereby the theory is in agreement with experiment; therefore, one may assume that the truncated Ψ 0 and ψ k well describe the microstructure of He II. Thus, the series for Ψ 0 and Ψ k can be truncated in spite of the fact that the expansion parameter is not very small (∼1/2).
With the pair Hamiltonian model as the starting point, perturbation theory calculations are performed for the average energy and the momentum distribution through second order in the two-body interaction potential. A phenomenological theory of helium II is proposed. The chief underlying feature of this phenomenological theory, which is shown to have a firm basis in the microscopic theory, is the presence of a double quasiparticle spectrum. Phenomenological expressions for the average energy and other quantities of interest are also proposed. Simple prescriptions are obtained for calculating the quasiparticle energies and the chemical potential from the average energy. Via these prescriptions, the quasiparticle energies and the chemical potential are calculated through second order in the interaction potential at T ≠ 0 °K, and the results are compared with earlier work in the literature.
In a previous paper a trial wave function of the form ψ = D II i<i f ( x ij ) was used variationally to calculate the ground-state energy of an interacting electron gas, D being a determinant of plane waves and f ( x ij ) a correlation function. In this work attention is focused on the nature of the wave function; in particular, the correlation function f ( x ij ) and the pair distribution function are calculated and numerical results are presented for two widely different densities. In the course of this work, further light is thrown on the approximations made in the earlier energy calculations. Finally, the use of a wave function of the type ψ = II i<j f ( x ij ) in the calculation of the ground-state energy of a system of charged bosons is discussed and the exact high-density result of Foldy obtained.
The paradoxes and disparities in the contemporary microscopic theory of superfluid helium (He–II) are discussed along with possible ways of resolving them by taking pair correlations of He4 atoms into consideration. It is shown that most paradoxes are associated with the commonly accepted initial assumption concerning the dominating role of single-particle Bose condensate (SPBC) in the quantum microstructure of the superfluid component ρs. The existence of intensive SPBC leads to a strong hybridization of the elementary excitation branches and to a common dispersion law for all boson branches, which is identified with the quasiparticle spectrum E(p) observed experimentally from slow neutron scattering in liquid helium. However, the stability of this spectrum during a transition through the λ-point and the large value of the gap in the vicinity of the “rotonic” minimum contradict both the Landau theoretical criterion of superfluidity and the small value of experimentally measured critical velocity. At the same time, a strong interaction between particles in the Bose liquid He4 strongly suppresses the SPBC which amounts to less than 1% of all He4 atoms and hence cannot be the main constituent of the superfluid component, unlike the case of a weakly nonideal Bose gas. Moreover, for a quite strong attraction between particles in a certain region of the momentum space, bound pairs of bosons can be formed in the superfluid Bose liquid, and a coherent pair condensate (CPC) analogous to the Cooper pair condensate in superconductors may appear. Such a strong CPC may completely suppress the weak SPBC. In this case, the one-particle spectrum ε(p) of elementary excitations does not hybridize with the collective (two-particle) spectrum and does not appear in the structure of the dynamic form factor S(p,ε), i.e., does not coincide with the spectrum measured from neutron scattering. The dispersion of one-particle spectrum is defined by the momentum dependence of the pair order parameter Ψ̃(p) and may have a minimum or a point of inflection at p≠0. This peculiarity in the one-particle spectrum of a Bose liquid with CPC but without SPBC vanishes together with Ψ̃(p) at the temperature Tc=Tλ of the phase transition from the superfluid to the normal state (unlike the rotonic minimum in the collective spectrum), while the corresponding critical velocity vc=min[ε(p)/p] vanishes at the λ-point in accordance with the Landau criterion and the experimental data. The assumption that the strong “Cooper-like” CPC is responsible for the quantum structure of the superfluid component ρs is confirmed indirectly by the successful application of the Justrow approximation (based on strong pair correlations) for describing the properties of liquid He4 and quantum liquid mixtures He3–4He on one hand, and by an anomalously large effective mass of He3 impurity atoms in He4, which is approximately equal to total mass of He3 and He4 atoms, thus pointing to the existence of helium atoms in superfluid liquid He–II. The value of the superfluid velocity circulation quantum in the Onsager–Feynman vortices in a Bose liquid with CPC but without SPBC is discussed as well as the critical velocities of superfluid He4 in ultrathin films and channels in which the creation and motion of quantum vortices are ruled out, and the quasiparticle spectrum undergoes dimensional quantization.
The ground-state energy of an interacting many-boson system obtained by Bogoliubov and Zubarev using the collective-coordinate method is shown to be equivalent through second order to the variation-perturbation energy evaluated in the uniform limit by means of the method of correlated basis functions. It is also shown that the wave function derived with a slight modification of the Bogoliubov-Zubarev approach is equivalent to that determined formally from the Rayleigh-Schr\"odinger perturbation theory in the uniform limit.
Abstract We derive and analyze the coupled equations of quadratic approximation of the Bogoliubov model for a weakly interacting Bose gas. The first equation determines the condensate density as a variational parameter and ensures the minimum of the grand thermodynamic potential. The second one provides a relation between the total number of particles and chemical potential. Their consistent theoretical analysis is performed for a number of model interaction potentials including contact (local) and nonlocal interactions, where the latter provide nontrivial dependencies in momentum space. We demonstrate that the derived equations have no solutions for the local potential, although they formally reproduce the well-known results of the Bogoliubov approach. At the same time, it is shown that these equations have the solutions for physically relevant nonlocal potentials. We show that in the regimes close to experimental realizations with ultracold atoms, the contribution of the terms originating from the quadratic part of the truncated Hamiltonian to the chemical potential can be of the same order of magnitude as from its c -number part. Due to this fact, in particular, the spectrum of single-particle excitations in the quadratic approximation acquires a gap. The issue of the gap is also discussed.
In Chapter 6, we derived a generalized Gross–Pitaevskii condensate equation which is coupled to a kinetic equation for the distribution function for the thermal atoms. However, the kinetic equation in Chapter 6 is only valid in the semiclassical limit. It involves the assumption that the thermal energy k B T is much greater than the spacing between the harmonic trap energy levels ( k B T ≫ω 0 where ω 0 is the trap frequency) and also much greater than the average interaction energy ( k B T ≫ gn ). The ZNG model, based on HF excitations, is still expected to be adequate down to quite low temperatures in trapped Bose gases, as will be shown by the results in Chapter 12. However, the ZNG model will break down at very low temperatures, where the Hartree–Fock excitations must be replaced by the Bogoliubov spectrum. To deal with this, one has to derive a kinetic equation for the Bogoliubov quasiparticle excitations. This is the goal of the present chapter. In this chapter, we use the second-order Beliaev approximation to discuss the nonequilibrium dynamics of a trapped Bose-condensed gas at finite temperatures. In doing to, we combine the second-order Beliaev self-energies with the lower-order Bogoliubov excitation spectrum, including off-diagonal single-particle propagators but still omitting the anomalous correlation functions. This last condition defines the Bogoliubov–Popov approximation. In this chapter, we consider only the damping which arises from collisions. We will not explicitly calculate corrections that are second-order in g to the quasiparticle energy spectrum or to the condensate chemical potential, both of which are associated with the real parts of the second-order Beliaev self-energies. The present chapter is a natural generalization of work presented in Chapter 6 for the simpler HF excitation spectrum assumed in the ZNG analysis.