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Physical review. B, Condensed matter

Edge states in antiferromagnetic quantum spin chains

Tai Kai Ng

Published Jul 1, 1994• 94 citations
Publisher

Abstract

The structure of edge states in general finite antiferromagnetic quantum spin chains with arbitrary spin value S is discussed within the framework of the nonlinear-sigma model (NL\ensuremath{\sigma}M) plus a topological \ensuremath{\theta} term. Based on a large-N theory of SU(N) quantum antiferromagnets and strong-coupling expansion, we argue that edge states with fractionalized spin quantum number S' exist in all spin chains with S\ensuremath{\ge}1, with S'=S/2 for integer spin chains and S'=(S-1/2)/2 for half-integer spin chains.

DOI
10.1103/physrevb.50.555

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The structure of edge states in general finite antiferromagnetic quantum spin chains with arbitrary spin value S is discussed within the framework of the nonlinear-sigma model (NL\ensuremath{\sigma}M) plus a topological \ensuremath{\theta} term. Based on a large-N theory of SU(N) quantum antiferromagnets and strong-coupling expansion, we argue that edge states with fractionalized spin quantum number S' exist in all spin chains with S\ensuremath{\ge}1, with S'=S/2 for integer spin chains and S'=(S-1/2)/2 for half-integer spin chains.
We report our results in investigating edge effects of open antiferromagnetic Heisenberg spin chains with spin magnitudes S=1/2,1,3/2,2 using the density-matrix renormalization-group method initiated by White. For integer spin chains, we find that edge states with spin magnitude Sedge{\mathit{S}}_{\mathrm{edge}}Sedge​=S/2 exist, in agreement with the valence-bond-solid model picture. For half-integer spin chains, we find that no edge states exist for the S=1/2 spin chain, but an edge state exists in the S=3/2 spin chain with a Sedge{\mathit{S}}_{\mathrm{edge}}Sedge​=1/2, in agreement with a previous conjecture by Ng. The properties of the edge state in the S=3/2 chain is studied in detail. Strong finite-size effects associated with spin dimerization in half-integer spin chains are also discussed.
The manifestations of topological effects in finite antiferromagnetic Heisenberg chains are examined by density-matrix renormalization-group techniques. We find that the difference between integer and half-integer spin chains shows up in ground-state energy per site when the length of the spin chain is longer than \ensuremath{\sim}\ensuremath{\xi}, where $\ensuremath{\xi}\ensuremath{\sim}\mathrm{exp}(\ensuremath{\pi}S)$ is a spin-spin correlation length, for spin magnitudes S up to 5/2.5/2.5/2. For open chains with spin magnitudes S=5/2S=5/2S=5/2 to S=5,S=5,S=5, we verify that end states with fractional spin quantum numbers ${S}^{\ensuremath{'}}$ exist and are visible in the structure of the low-energy excitation spectrum even when the chain length is much smaller than the correlation length \ensuremath{\xi}. The robustness of end states points to the possibility of the existence of general hidden topological order in quantum spin chains with spin magnitudes S> 1.S>~1.S> 1.
The one-dimensional quantum Heisenberg antiferromagnet with exchange alternation is related to the nonlinear 0(3) sigma model with a topological ‘‘θ term’’ in the Langrangian. The models with parity symmetry (θ=0 or π) are respectively related to the integer and half-integer spin models without exchange alternation. The nonlinear quantum physics of Heisenberg antiferromagnets is placed in a wider context of topologically nontrivial field theories and the spin-Peierls effect in half-integer spin systems (and its absence in integer spin systems) explained.
The relation between quantum spin chains and conformal field theories is reexamined. Using a generalized Hubbard model representation it is argued that the critical theory for generic half-odd-integer spin antiferromagnets is the Wess-Zumino-Witten model (WZW model) with topological coupling, k=1, whereas generic integer spin antiferromagnets have an energy gap. The higher-k WZW models (which describe integrable higher spin models) are multicritical points in the space of all spin Hamiltonians. The k=1 WZW model represents a stable fixed point for many theories including WZW models of arbitrary odd k with relevant operators added, generalized Hubbard or Thirring models with an odd number of colors and the O(3) \ensuremath{\sigma} model at topological angle \ensuremath{\theta}=\ensuremath{\pi}.
The antiferromagnetic Heisenberg spin chain with integer spin has a short-range magnetic order and an excitation energy gap above the ground state. This so-called Haldane gap is proportional to the exchange coupling constant J of the Heisenberg chain. In this study, we discuss recent results about the spin dependence of the Haldane gap and conjecture an analytical formula valid asymptotically for large spin values. We then discuss the robustness of the edge states of the spin-1 chain by studying a spin-1 ladder using the density matrix renormalization group (DMRG) algorithm. We show that the peculiar hidden topological order of the spin-1 chain disappears smoothly by increasing the ladder rung coupling without any intervening phase transition. This is evidence for the fragile character of the topological order of the spin-1 chain.
We demonstrate the existence of nonlocal topological (string) order in half-integer-spin antiferromagnetic Heisenberg chains on macroscopic scale on the basis of analytical scaling analysis and density matrix renormalization group calculations. Strong numerical evidence leads to a conjecture that chains with S = (2m-1)/2 and m (m = integers) belong to the same topological class defined by the topological angle theta/pi = 1/m that plays a role similar to the fictitious gauge field in the fractional quantum Hall effect.