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Journal of Mathematical Physics

Mathematical problems of irreversible statistical mechanics for quantum systems. II: On the singularities of (Ψ(z)−z)−1 and the pseudo-Markovian equation. Application to Lee model

M. Courbage

Published Apr 1, 1982• 8 citations
Publisher

Abstract

We study in the frame of the superspace of the Hilbert–Schmidt operators the contributions of some complex singularities of the analytic continuation of (Ψ(z)−z)−1 to the diagonal part of the solution of the Liouville–von Neumann equation. Under some conditions, the θ̄ operator of the pseudo-Markovian master equation can be explicitly constructed. It is necessary to specify the diagonal representation and the class of initial conditions having regularity properties. This Hilbertian structure does not allow the construction of a closed subspace which reduces the Liouville–von Neumann operator L, giving an exact irreversible subdynamics; more elaborated mathematical structures are therefore necessary. The above methods are illustrated in the case of the Lee model.

DOI
10.1063/1.525412

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We study in the frame of the superspace of the Hilbert–Schmidt operators the contributions of some complex singularities of the analytic continuation of (Ψ(z)−z)−1 to the diagonal part of the solution of the Liouville–von Neumann equation. Under some conditions, the θ̄ operator of the pseudo-Markovian master equation can be explicitly constructed. It is necessary to specify the diagonal representation and the class of initial conditions having regularity properties. This Hilbertian structure does not allow the construction of a closed subspace which reduces the Liouville–von Neumann operator L, giving an exact irreversible subdynamics; more elaborated mathematical structures are therefore necessary. The above methods are illustrated in the case of the Lee model.
We study some mathematical problems posed in nonequilibrium statistical mechanics and subdynamics theory developed by Prigogine and coworkers. We study in the superspace of the Hilbert–Schmidt operators the solution of the Liouville–von Neumann equation. The application in this frame of the spectral deformation methods yields expression of analytic continuations of a class of matrix elements of the resolvent of the Liouville–von Neumann operator, and this allows the analytic continuation of the collision and destruction operators. However, it is impossible to obtain simultaneously analytic continuation of the creation operator in this frame. The above results will be used in the second part of the article in order to study the pseudo-Markovian equation.
The singular continuous spectrum of the Liouville operator of quantum statistical physics is, in general, properly included in the difference of the spectral values of the singular continuous spectrum of the associated Hamiltonian. The absolutely continuous spectrum of the Liouvillian may arise from a purely singular continuous Hamiltonian. We provide the correct formulas for the spectrum of the Liouville operator and show that the decaying states of the singular continuous subspace of the Hamiltonian do not necessarily contribute to the absolutely continuous subspace of the Liouvillian.
One of us (C.G) has developed a transformation theory in nonequilibrium statistical mechanics that generalizes the usual transformation theory of quantum mechanics in the framework of the resolvent formalism of the Liouville-von Neumann operator extensively used by the Brussels school. Prigogine, George, and Henin have shown that the evolution of a dissipative system can be decomposed into separate subdynamics in orthogonal subspaces. The π subspace, containing all thermodynamics, can be seen as an extension of the subspace of the invariants in the absence of dissipation. In this subspace a suitable contracted description of the system can be given through a dressing operator χ, which has the property that HR = χ−1H0 can be considered as the renormalized energy. A differential equation that determines χ has been proposed by Mandel. It is useful to see, even for a nondissipative system, what relation the transformation theory in the Liouville-von Neumann formalism has to the standard transformations used in quantum mechanics. In this paper we consider a system that can be completely diagonalized by the Bogoliubov transformation. It is shown that in this case the Mandel equation can be solved and that χ−1H0 = HD, where HD is the diagonalized Hamiltonian, obtained by the Bogoliubov transformation.
We consider a system perturbed by an external field and subject to dissipative processes. From the von Neumann equation for such a system in the weak coupling limit we derive an inhomogeneous master equation, i.e., a master equation with dissipative terms and streaming terms, using Zwanzig’s projection operator technique in Liouville space. From this equation the response function, as well as expressions for the generalized conductivity and susceptibility, is obtained. It is shown that for large times only the diagonal part of the density operator is required. The various expressions are found to be in complete harmony with previous results (Part I) obtained via the van Hove limit of the Kubo–Green linear response formulas. In order to account for the properties at quantum frequencies, the evolution of the nondiagonal part in the weak coupling limit is also established. The complete time dependent behavior of the dynamic variables in the van Hove limit is expressed by B (t) =exp[−(Λd−iℒ0) t] B, where Λd is the master operator and L0 the Liouville operator in the interaction picture. The cause of irreversibility is discussed. Finally, the inhomogeneous master equation is employed to obtain as first moment equation a Boltzmann equation with streaming terms, applicable to quantum systems.
The exact treatment of Markovian open quantum systems, when based on numerical diagonalization of the Liouville super-operator or averaging over quantum trajectories, is severely limited by Hilbert space size. Perturbation theory, standard in the investigation of closed quantum systems, has remained much less developed for open quantum systems where a direct application to the Lindblad master equation is desirable. We present such a perturbative treatment which will be useful for an analytical understanding of open quantum systems and for numerical calculation of system observables which would otherwise be impractical.