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Chemical Physics

Diagrammatic density matrix analysis of the Raman photon echo

Klaas Wynne, Michiel Mueller, D. Brandt, Joop D. W. van Voorst

Published Oct 1, 1988• 15 citations
Publisher
DOI
10.1016/0301-0104(88)87075-7

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Previous diagrammatic analyses of the density matrix are extended to incorporate quantum-electrodynamic processes fully by inclusion of the photon propagator and its complex conjugate. It is shown that eight fundamental time-ordered diagrams are necessary to describe radiative processes completely. For each of these, inclusion of the photon propagator permits, in addition to polarization, a direct calculation of electric field expectation values. Electric field correlations associated with the fundamental diagrams lead to a diagrammatic (quantum-electrodynamic) interpretation and derivation of the spontaneous emission limited linewidth associated with simulated emission as given by the Townes-Schawlow line narrowing formula. Stimulated Raman scattering, two-wave mixing, and parametric amplification are illustrative of the extension of these diagrammatic techniques to nonlinear optical phenomena.>