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Optics Communications

Direct measurements of magnetic hyperfine constants of (3)3ΠΩg states in Na2

H.-R. Xia, Li Ma, Jianhua Xu, M. Yuan, Isaac Cheng

Published May 1, 1990• 3 citations
Publisher
DOI
10.1016/0030-4018(90)90264-t

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The simple structure of the BH molecule makes it an excellent candidate for direct laser cooling. We measure the branching ratios for the decay of the A^{1}Pi (v'=0) state to vibrational levels of the ground state, X^{1}Sigma^{+}, and find that they are exceedingly favourable for laser cooling. We verify that the branching ratio for the spin-forbidden transition to the intermediate a^{3}Pi state is inconsequentially small. We measure the frequency of the lowest rotational transition of the X state, and the hyperfine structure in the relevant levels of both the X and A states, and determine the nuclear electric quadrupole and magnetic dipole coupling constants. Our results show that, with a relatively simple laser cooling scheme, a Zeeman slower and magneto-optical trap can be used to cool, slow and trap BH molecules.
Direct measurements of the ground-state magnetically insensitive hyperfine transition | F = 2 , m F = 0 〉 → | F = 1 , m F = 0 〉 of Be + 9 ions have been performed using microwave-driven state transfer. The Be + 9 ions are confined and laser cooled in a linear Paul trap, forming a Coulomb crystal. The transition frequencies have been measured over a magnetic-field range of ± 0.5 mT centered at zero magnetic field and the acquired data were fitted accounting for the high-order Zeeman effect. The hyperfine constant A is determined to be − 625.008 840 ( 35 ) MHz, achieving a relative precision of 5.6 × 10 − 8 .