A critical Ising strip with confining boundaries characterized by arbitrary and different surface magnetic field variables is considered by the exact variational formulation of Mikheev and Fisher. As one of the most important scaling densities in films we study the universal functions of the energy density profiles which exhibit strong nonmonotonous behavior near the confining boundaries. We also examine their short-distance expansion that reveals novel universal amplitudes associated with the distant-wall corrections. They manifest nontrivial crossover behaviors from positive to negative values as the fields variables are freely varied. As an indispensable part of our new formulation of the generalized distant-wall correction de Gennes-Fisher universal amplitude we derive in a self-contained manner within the present approach the Casimir amplitudes that may change their nature twice under the strong influence of surface fields: from repulsive to attractive and vice versa along certain trajectories. Our findings strongly suggest a surprising role of the stress-tensor within one of the distant-wall corrections, given that similar discovery for standard extraordinary and ordinary surface universality classes was based on the conformal invariance symmetry which is broken under the present boundary conditions. We also show that a constituent part of the de Gennes-Fisher amplitude, defined in a generalized sense, is not hyperuniversal in two dimensions, contrary to earlier results for standard boundary conditions in this dimension.
A critical Ising strip with confining boundaries characterized by arbitrary and different surface magnetic field variables is considered by the exact variational formulation of Mikheev and Fisher. As one of the most important scaling densities in films we study the universal functions of the energy density profiles which exhibit strong nonmonotonous behavior near the confining boundaries. We also examine their short-distance expansion that reveals novel universal amplitudes associated with the distant-wall corrections. They manifest nontrivial crossover behaviors from positive to negative values as the fields variables are freely varied. As an indispensable part of our new formulation of the generalized distant-wall correction de Gennes-Fisher universal amplitude we derive in a self-contained manner within the present approach the Casimir amplitudes that may change their nature twice under the strong influence of surface fields: from repulsive to attractive and vice versa along certain trajectories. Our findings strongly suggest a surprising role of the stress-tensor within one of the distant-wall corrections, given that similar discovery for standard extraordinary and ordinary surface universality classes was based on the conformal invariance symmetry which is broken under the present boundary conditions. We also show that a constituent part of the de Gennes-Fisher amplitude, defined in a generalized sense, is not hyperuniversal in two dimensions, contrary to earlier results for standard boundary conditions in this dimension.
I use an exact variational formulation of Mikheev and Fisher to study the critical Ising strip with a grain boundary and confining surfaces characterized by arbitrary and different surface magnetic fields. Energy density profiles that serve as order parameters of the system within the used method show strong nonmonotonous behavior in the vicinity of confining surfaces. I consider short-distance expansion of energy density profiles. New universal amplitudes associated with distant-wall corrections exhibit nontrivial crossover behaviors from positive to negative values as the field's variables are continuously varied. Casimir amplitudes calculated in a self-contained manner are characterized by complex manifolds which may comprise two disconnected positive wings separated by an area of negative values. I define and determine the generalized de Gennes-Fisher amplitude, which strongly suggests that a stress tensor is present within one of the distant-wall corrections. This is an unanticipated result given that a similar discovery for standard extraordinary (E) and ordinary (O) surface universality classes was based on the conformal invariance symmetry, which is broken under the present boundary conditions. A grain boundary essentially influences both energy density profiles and Casimir amplitudes, besides surface fields with a number of accompanying features that are examined in detail. We present closed analytic forms of energy density profiles for standard (N) and (O) BCs: ɛNN(x,g),ɛOO(x,g),ɛNO(x,g) [(N) is the normal surface universality class, g is the grain boundary's strength, x is the relative distance x:=z/L with L as a film width], thus enabling us to deduce their important symmetry properties and to have a detailed insight into their general behaviors.
The critical behavior near a surface that breaks the order parameter symmetry is analyzed with field-theoretic renormalization-group methods. We study the short-distance expansions of the order parameter and the energy density about the surface and investigate various density profiles and correlation functions in the half-space and film geometries. Our results confirm Cardy's conjecture that the stress-energy tensor appears as the leading surface density. Its universal prefactor C in the expansions determines several physical properties of interest in the critical adsorption of fluids: In a film at the bulk critical temperature Tc, C determines the amplitude ratio of the Fisher-de Gennes distant-wall correction to the order-parameter profile and the Casimir correction to the free energy. In the half-space close to Tc, C determines the amplitude ratio of the ${(\frac{z}{\ensuremath{\xi}})}^{d}$ term in the order parameter profile to the Ferer-Stauffer-Wortis term in the bulk free energy. Here z is the distance from the surface and $\ensuremath{\xi}$ the bulk correlation length. In the half-space at Tc, C also determines the universal short-distance amplitudes of layer susceptibilities, which should be observable in computer experiments. We calculate C to second order in $\ensuremath{\epsilon}=4\ensuremath{-}d$ and estimate its value for d=3. C is closely related to the stress-stress correlation in a half-space, for which we obtain the bulk to surface crossover. We present a simple argument showing why this crossover depends, in general, on the surface universality class except in two dimensions.
With conformal-invariance methods, Burkhardt, Guim, and Xue studied the critical Ising model, defined on the upper half plane y>0 with different boundary conditions a and b on the negative and positive x axes. For ab=-+ and f+, they determined the one- and two-point averages of the spin σ and energy ε. Here +,-, and f stand for spin-up, spin-down, and free-spin boundaries, respectively. The case +-+-+⋯, where the boundary condition switches between + and - at arbitrary points, ζ_{1},ζ_{2},⋯ on the x axis was also analyzed. In the first half of this paper a similar study is carried out for the alternating boundary condition +f+f+⋯ and the case -f+ of three different boundary conditions. Exact results for the one- and two-point averages of σ,ε, and the stress tensor T are derived with conformal-invariance methods. From the results for 〈T〉, the critical Casimir interaction with the boundary of a wedge-shaped inclusion is derived for mixed boundary conditions. In the second half of the paper, arbitrary two-dimensional critical systems with mixed boundary conditions are analyzed with boundary-operator expansions. Two distinct types of expansions-away from switching points of the boundary condition and at switching points-are considered. Using the expansions, we express the asymptotic behavior of two-point averages near boundaries in terms of one-point averages. We also consider the strip geometry with mixed boundary conditions and derive the distant-wall corrections to one-point averages near one edge due to the other edge. Finally we confirm the consistency of the predictions obtained with conformal-invariance methods and with boundary-operator expansions, in the the first and second halves of the paper.
The conformal-invariance approach is extended to two-dimensional critical systems with mixed ab boundary conditions. The profiles 〈\ensuremath{\varphi}(r)〉ab of the magnetization and the energy density in Ising and Q-state Potts strips with +- and fixed-free boundary conditions are derived. The profile of an arbritrary operator degenerate at level 2 is expressed in terms of hypergeometric functions. The universal amplitudes AabBab of the Casimir force and the Fisher--de Gennes distant-wall correction to the profile satisfy Bab=-4\ensuremath{\pi}${\mathit{x}}_{\mathrm{\ensuremath{\varphi}}}$${\mathit{c}}^{\mathrm{\ensuremath{-}}1}$Aab. Here ${\mathit{x}}_{\mathrm{\ensuremath{\varphi}}}$ is the scaling dimension of \ensuremath{\varphi}(r) and c is the central charge.
We obtain an exact solution of the d = 2 infinite Ising strip with surface fields of opposite signs , . Earlier predictions by Parry et al are confirmed of the crucial importance of wetting for a system confined between two parallel walls that exert competitive surface fields. The transition of the magnetization profile m(z) from the partial wetting regime below the critical wetting temperature at a single wall with a surface field , to the soft-mode single phase in the temperature range , where is the critical temperature of the bulk system, is described in detail. A scaling ansatz is verified for the singular part of the surface excess free energy, and for the profile, . The modification of the magnetization profile near one wall, due to wetting, is studied. Near the (-) wall at the profile is found to be a linear function of the scaled distance but its slope is different than for the case of perfect asymmetry system hence these two cases belong to the different universality regime.
We investigate two dimensional critical Ising films of width L with surface fields H(1)=H(L) in the crossover between ordinary (H(1)=0) and normal (H(1)=infinity) transitions. Using exact transfer-matrix diagonalization and density matrix renormalization-group (DMRG) methods, we calculate magnetization profiles m(z), the excess magnetization Gamma, and the analog of the solvation force f(solv) as functions of H1 for several L. Scaling functions of the above quantities deviate substantially from their asymptotic forms at fixed points for a broad region of the scaling variable LH21 approximately L/l(1), where l(1) is the length induced by the surface field H1. The scaling function for /f(solv)/ has a deep minimum near LH(2)(1)=1, which is about one order of magnitude smaller than its value at both fixed points (the "Casimir" amplitude). For weak H1 (l(1)>L) the magnetization profile has a maximum at the center of the film, and f(solv) decays much faster than L-2. For stronger H1 (1<l(1)<L), the magnetization has two maxima at a distance approximately l(1) from the walls, and the solvation force decays much slower than L-2. For L>>l(1) the solvation force decays according to the universal power law f(solv) approximately L(-2). The results of the approximate DMRG method show remarkable agreement with the exact ones.