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Theoretical and Mathematical Physics

On the number of discrete levels in the quantum problem of three particles

Dimitri R. Yafaev

Published Apr 1, 1976• 7 citations
Publisher
DOI
10.1007/bf01036549

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arXiv:1308.3921•Aug 19, 2013•0 citations
Using techniques developed by Greenspoon and Pathria, and by Chaba and Pathria, a rigorous asymptotic analysis of the onset of Bose-Einstein condensation in a finite three-dimensional system at constant pressure, under Dirichlet boundary conditions, is carried out. Finite size corrections arising from a modification of the density of states of the system, as well as from the discreteness of the single-particle energy levels, play an important role in the critical region. At the critical temperature Tc{T}_{c}Tc​, the volume of the system changes abruptly from being proportional to the total number of particles NNN to being proportional to N34{N}^{\frac{3}{4}}N43​, the number of particles in the condensate rises sharply from $\ensuremath{\propto}{N}^{\frac{1}{4}}$ to $\ensuremath{\propto}N$, and the specific heat CP{C}_{P}CP​ turns out to be proportional to N98{N}^{\frac{9}{8}}N89​. At somewhat lower temperatures, the finite size effects arising from the discreteness of the single-particle energy levels become dominant and the volume of the system, together with CP{C}_{P}CP​, becomes $\ensuremath{\propto}{N}^{\frac{3}{5}}$.
The theory of discrete extension, introduced here, demonstrates that various re-sults from elementary, non-relativistic quantum mechanics can be obtained without recourse to eigenvalue problems, operators, or state vectors in Hilbert space. Us-ing a mathematical structure similar to that of Newtonian mechanics, the theory generates correct, quasi-discrete values of action increments and energy levels for bound states of quantum-level systems. Quantization of the harmonic oscillator provides a simple illustration. Like Newtonian mechanics the theory provides intuitive conceptualizations for basic entities and kinematics. However, in place of the classical concepts of particle and field, the non-classical, unitary concept of a discretely extended ob-ject emerges from the theory as an alternative characterization of the nature of quantum-level entities. Because such an object is well-defined and unitary, the theory avoids the dilemmas of wave-particle dualism and complementarity. The theory offers insight into the nature of a number of quantum effects such as the zero-point energy of a harmonic oscillator. It also makes a number of testable predictions that distinguish it from standard quantum theory and from Bohmian mechanics.