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European Journal of Physics

Constant of motion for the hydrogen atom in an external field: a classical view

O J Campuzano-Cardona, H. N. Núñez‐Yépez, A. L. Salas‐Brito, Gerardo I. Sanchez-Ortiz

Published Sep 1, 1995• 5 citations
Publisher

Abstract

Using the Hamilton vector, a well-known constant of motion of the unperturbed hydrogen atom, and simple classical mechanics, a scalar constant quantity for the hydrogen atom interacting with an external electric field is obtained. This constant quantity Omega is algebraically related to the Hamilton vector. Our purely classical analysis qualitatively reveals some observed properties of the corresponding quantum system.

DOI
10.1088/0143-0807/16/5/005

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Using the Hamilton vector, a well-known constant of motion of the unperturbed hydrogen atom, and simple classical mechanics, a scalar constant quantity for the hydrogen atom interacting with an external electric field is obtained. This constant quantity Omega is algebraically related to the Hamilton vector. Our purely classical analysis qualitatively reveals some observed properties of the corresponding quantum system.
A relativistically invariant representation of the generalized momentum of a particle in an external field is proposed. In this representation, the dependence of the potentials of the interaction of the particle with the field on the particle velocity is taken into account. The exact correspondence of the expressions of energy and potential energy for the classical Hamiltonian is established, which makes identical the solutions to the problems of mechanics with relativistic and nonrelativistic approaches. The invariance of the proposed representation of the generalized momentum makes it possible to equivalently describe a physical system in geometrically conjugate spaces of kinematic and dynamic variables. Relativistic invariant equations are proposed for the action function and the wave function based on the invariance of the representation of the generalized momentum. The equations have solutions for any values of the constant interaction of the particle with the field, for example, in the problem of a hydrogen-like atom, when the atomic number of the nucleus is Z > 137. Based on the parametric representation of the action, the expression for the canonical Lagrangian, the equations of motion, and the expression for the force acting on the charge are derived when moving in an external electromagnetic field. The Dirac equation with the correct inclusion of the interaction for a particle in an external field is presented. In this form, the solutions of the equations are not limited by the value of the interaction constant. The solutions of the problem of charge motion in a constant electric field, the problems for a particle in a potential well and the passage of a particle through a potential barrier, the problems of motion in an exponential field (Morse), and also the problems of a hydrogen atom are given.
The unique properties of the hydrogen atom, especially those that result from the dynamic symmetry of the 1/r potential, are presented from both classical and quantal points of view. Using these properties as a starting point, the response of a classical hydrogen atom, an electron executing a Keplerian ellipse about a proton, to a weak electric field is described. Because the field is weak, the elliptical orbit may be treated as a dynamical element itself, variations in its shape and orientation depicting the classical Stark effect. The behavior of this orbit is then correlated with the quantum mechanical description of the first-order Stark effect in hydrogen, a subject that is included in most introductory courses in quantum mechanics.
Relativistic invariant equations are proposed for the action function and the wave function based on the invariance of the representation of the generalized momentum. The equations have solutions for any values of the interaction constant of a particle with a field, for example, in the problem of a hydrogen-like atom, when the atomic number of the nucleus Z > 137. Based on the parametric representation of the action, the expression for the canonical Lagrangian, the equations of motion and the expression for the force acting on the charge during motion in an external electromagnetic field are derived. The Dirac equation with the correct inclusion of the interaction for a particle in an external field is presented. In this form, the solutions of the equations are not limited by the value of the interaction constant. The solutions of the problem of charge motion in a constant electric field, problems for a particle in a potential well, and penetration of a particle through a potential barrier, as well as problem of a hydrogen atom are presented.
In this paper, the classical Bohr’s model of the hydrogen atom has been revisited. Two values of fundamental physical properties of an electron in the hydrogen atom has been identified. These physical properties ( & ) are constant in nature. The aim for the review was to contribute to the solution of disagreement between the Bohr’s wavelength ( ) and the Balmer’s experimental observation ( ) for the emission spectrum of hydrogen atom. There are two other constants and that were identified in the Bohr’s equation of the hydrogen atom. The four fundamental physical constants are intrinsic properties of an electron and can be applied to multi-electron system. They can also be obtained from Schrodinger’s equation for hydrogen atom at steady state. These constants may be subjected to scrutiny for their determination for better understanding. Also, since Bohr’s model of hydrogen atom is based on classical mechanics, this paper has provided an alternate method of solving simple problems in atomic physics under Bohr’s model to aid good mental picture of hydrogen atom to scientists.
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State transition in the multiple-levels system has the great potential applications in the quantum technology. In this article we employ a deterministic approach in complex space to analyze the dynamics of the 1s-2p electron transition in the hydrogen atom. The electron’s spin motion is embodied in the framework of quantum Hamilton mechanics that allows us to examine the transition dynamics more precisely. The transition is driven by an oscillating electric field in the z-direction. The electron’s transition process can be visualized by monitoring its motion in the complex space. The quantum potential and the total energy proposed in this paper provide new indices to observe the dynamic changes of electrons in the transition process.