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American Journal of Physics

Negative Kelvin temperatures: Some anomalies and a speculation

Ralph J. Tykodi

Published Mar 1, 1975• 18 citations
Publisher
DOI
10.1119/1.10069

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Work Storage in States of Apparent Negative Thermodynamic Temperature

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Inverted quantum states provide a challenge to classical thermodynamics, since they appear to contradict the classical formulation of the second law of thermodynamics. Ramsey interpreted these states as stable equilibrium states of negative thermodynamic temperature, and added a provision to allow these states to the Kelvin-Planck statement of the second law [N. F. Ramsey, Phys. Rev. 103, 20 (1956)PHRVAO0031-899X10.1103/PhysRev.103.20]. Since then, Ramsey's interpretation has prevailed in the literature. Here, we present an alternative option to accommodate inverted states within thermodynamics, which strictly enforces the original Kelvin-Planck statement of the second law, and reconciles inverted states and the second law by interpreting the former as unstable states, for which no temperature-positive or negative-can be defined. Specifically, we recognize inverted quantum states as temperature-unstable states, for which all processes are in agreement with the original Kelvin-Planck statement of the second law, and positive thermodynamic temperatures in stable equilibrium states. These temperature-unstable states can only be created by work done to the system, which is stored as energy in the unstable states, and can be released as work again, just as in a battery or a spring.

Physical Review Letters•Jun 21, 2018•36 citations
The conformal anomaly indicates the breaking of conformal symmetry (angle-preserving transformations) in the quantum theory by quantum fluctuations and is a close cousin of the gravitational anomaly. We show, for the first time, that the conformal anomaly controls the variance of the local magnetization MlocM_{loc}Mloc​ at finite temperatures in spin chains and spin ladders. This effect is perceived at constant and variable temperature across the sample. The change of MlocM_{loc}Mloc​ induced by the conformal anomaly is of the order of 3-5\% of the maximal spin at one Kelvin for DIMPY or CuPzN and increases linearly with temperature. Further, for a temperature gradient of 10\% across the sample, the time-relaxation of the non-equilibrium MlocM_{loc}Mloc​ is of the order of nanoseconds. Thus, we believe that experimental techniques such as neutron scattering, nuclear magnetic resonance~(NMR), spin noise and ultrafast laser pumping should pinpoint the presence of the conformal anomaly. Therefore, we pave the road to detect the conformal anomaly in spin observables of strongly interacting low-dimensional magnets.
Inverted quantum states provide a challenge to classical thermodynamics, since they appear to contradict the classical formulation of the second law of thermodynamics. Ramsey interpreted these states as stable equilibrium states of negative thermodynamic temperature, and added a provision to allow these states to the Kelvin-Planck statement of the second law [N. F. Ramsey, Phys. Rev. 103, 20 (1956)PHRVAO0031-899X10.1103/PhysRev.103.20]. Since then, Ramsey's interpretation has prevailed in the literature. Here, we present an alternative option to accommodate inverted states within thermodynamics, which strictly enforces the original Kelvin-Planck statement of the second law, and reconciles inverted states and the second law by interpreting the former as unstable states, for which no temperature-positive or negative-can be defined. Specifically, we recognize inverted quantum states as temperature-unstable states, for which all processes are in agreement with the original Kelvin-Planck statement of the second law, and positive thermodynamic temperatures in stable equilibrium states. These temperature-unstable states can only be created by work done to the system, which is stored as energy in the unstable states, and can be released as work again, just as in a battery or a spring.