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Physical Review Letters

Scaling Function for Critical Scattering

Michael Ellis Fisher, Amnon Aharony A

Published Nov 12, 1973• 92 citations
Publisher

Abstract

The zero-field, two-point correlation function of an $n$-vector system in $d=4\ensuremath{-}\ensuremath{\epsilon}$ dimensions is calculated to order ${\ensuremath{\epsilon}}^{2}$ for $T>~{T}_{c}$. The scaling function is obtained as a closed, cutoff-independent integral. As $t=\frac{(T\ensuremath{-}{T}_{c})}{{T}_{c}}\ensuremath{\rightarrow}0$ at fixed wave vector $q$, the leading variation is ${{\stackrel{^}{E}}_{1}}^{n,d}(q){t}^{1\ensuremath{-}\ensuremath{\alpha}}+{{\stackrel{^}{E}}_{2}}^{n,d}(q)t$, where $\ensuremath{\alpha}$ is the specific-heat exponent; thence the maximum in the scattering above ${T}_{c}$ is located, in good agreement with high-$T$ series-expansion estimates.

DOI
10.1103/physrevlett.31.1238

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Scaling function for two-point correlations. II. Expansion to order 1n

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Dispersion-theory approach to the correlation function for critical scattering

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Critical exponents of ferromagnets with dipolar interactions: Second-order ε expansion

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Theory of Critical-Point Scattering and Correlations. I. The Ising Model

Michael Ellis Fisher, Robert J. Burford

The theory of the correlations and critical scattering of two- and three-dimensional nearest-neighbor Ising models is discussed critically. A distinction is drawn between $\ensuremath{\kappa}(T)$, the true inverse range of exponential decay of the correlations, and ${\ensuremath{\kappa}}_{1}(T)$, the effective range determined from the low-angle scattering intensity. Ten to eleven terms of appropriate high-temperature series exapnsions for $\ensuremath{\kappa}$ and ${\ensuremath{\kappa}}_{1}$ are determined for the square and simple cubic lattices, and shorter series are given for the triangular, fcc, and bcc lattices. For the former lattices, the complete correlation expansions are obtained to the same order. It is shown that $\ensuremath{\kappa}$ and ${\ensuremath{\kappa}}_{1}$ vary as ${(T\ensuremath{-}{T}_{0})}^{\ensuremath{\nu}}$ when $T\ensuremath{\rightarrow}{T}_{c}$, with $\ensuremath{\nu}=1$ for dimensionality $d=2$, but $\ensuremath{\nu}=0.6430\ifmmode\pm\else\textpm\fi{}0.0025\ensuremath{\simeq}\frac{9}{14}$ for $d=3$. The asymptotic decay of correlation at $T={T}_{c}$ is found to be $\frac{1}{{r}^{d\ensuremath{-}2+\ensuremath{\eta}}}$, where $\ensuremath{\eta}$ is related to the exponent $\ensuremath{\gamma}$ of the divergence of the susceptibility by $(2\ensuremath{-}\ensuremath{\eta})\ensuremath{\nu}=\ensuremath{\gamma}$, Numerical values are $\ensuremath{\eta}=\frac{1}{4}$ for $d=2$ and $\ensuremath{\eta}=0.056\ifmmode\pm\else\textpm\fi{}0.008\ensuremath{\simeq}\frac{1}{18} \mathrm{for} d=3$. The relative scattering intensity $\stackrel{^}{\ensuremath{\chi}}$ as a function of wave number k is given to high accuracy for all $T>~{T}_{c}$ by $\stackrel{^}{\ensuremath{\chi}}(\mathbf{k},T)\ensuremath{\simeq}\left(\frac{a}{{r}_{1}}\right)\frac{^{2\ensuremath{-}\ensuremath{\eta}}[{({\ensuremath{\kappa}}_{1}a)}^{2}+{\ensuremath{\varphi}}^{2}{a}^{2}{K}^{2}(\mathbf{k})]^{\frac{\ensuremath{\eta}}{2}}}{[{({\ensuremath{\kappa}}_{1}a)}^{2}+\ensuremath{\psi}{a}^{2}{K}^{2}(\mathbf{k})]},$ where (i) $a$ is the lattice spacing, (ii) ${a}^{2}{K}^{2}=2d[1\ensuremath{-}{q}^{\ensuremath{-}1}\ensuremath{\Sigma}\mathrm{exp}(i\mathbf{k}\ifmmode\cdot\else\textperiodcentered\fi{}\mathbf{r})]\ensuremath{\simeq}{(\mathrm{ka})}^{2}$, the sum being over the $q$ nearest-neighbor lattice sites, (iii) ${r}_{1}(T)$ is a slowly-varying decreasing function near ${T}_{c}$, (iv) $\ensuremath{\psi}=1+\frac{1}{2}\ensuremath{\eta}{\ensuremath{\varphi}}^{2}$, and $(\mathrm{v}) \ensuremath{\varphi}(T)$ is slowly varying with a magnitude at ${T}_{c}$ of 0.03 for $d=2$ and of 0.06 to 0.09 for $d=3$. Explicit formulas are given for ${\ensuremath{\kappa}}_{1}$, ${r}_{1}$, and $\ensuremath{\varphi}$ as functions of $T$. The correlations and the scattering are isotropic near ${T}_{c}$. The critical scattering isotherm is curved for low $k$ according to ${\stackrel{^}{\ensuremath{\chi}}}^{\ensuremath{-}1}\ensuremath{\sim}{k}^{2\ensuremath{-}\ensuremath{\eta}}$ and it intersects the isotherms for $T>{T}_{c}$. Correspondingly, $\stackrel{^}{\ensuremath{\chi}}(\mathbf{k},T)$ exhibits a maximum for fixed k, at a temperature above ${T}_{c}$; for $d=2$ the maxima are very well marked, but for $d=3$ they are smaller and occur closer to ${T}_{c}$. The theory is compared favorably with recent neutron-scattering experiments on pure beta-brass.

Physical Review•Apr 10, 1967•753 citations

Theory of Critical-Point Scattering and Correlations. II. Heisenberg Models

Douglas S. Ritchie, Michael Ellis Fisher

The spin-spin correlation functions and the critical-scattering intensity for Heisenberg models of general spin, $S=\frac{1}{2}$ to $\ensuremath{\infty}$, on the sc, bcc, and fcc lattices are studied on the basis of high-temperature series expansions along the lines developed in Paper I [M. E. Fisher and R. J. Burford, Phys. Rev. 156, 583 (1967)]. Subject to increased uncertainties for low spin, it is concluded that the exponents $\ensuremath{\gamma}={1.375}_{\ensuremath{-}0.01}^{+0.02}$, $2\ensuremath{\nu}={1.405}_{\ensuremath{-}0.01}^{+0.02}$, and $\ensuremath{\eta}=0.043\ifmmode\pm\else\textpm\fi{}0.014$ describe all lattices and all spin. Explicit formulas are presented for the susceptibility/zero-angle scattering ${\ensuremath{\chi}}_{0}(T)$, for the inverse correlation length ${\ensuremath{\kappa}}_{1}(T)$, for the effective interaction range ${r}_{1}(T)$, and using the Fisher-Burford approximant, for the total scattering $\stackrel{^}{\ensuremath{\chi}}(\stackrel{\ensuremath{\rightarrow}}{\mathrm{k}},T)$. The shape parameter ${\ensuremath{\varphi}}_{c}$ attains the "universal" value ${\ensuremath{\varphi}}_{c}\ensuremath{\simeq}0$. 11 for large spin but shows signs of spin dependence (and lattice dependence) for low spin. At fixed k the scattering is predicted to display a maximum above ${T}_{c}$ determined by $\frac{{\ensuremath{\kappa}}_{1}({T}_{max})}{k}\ensuremath{\simeq}0.10 (\mathrm{for} S\ensuremath{\gtrsim}2)$ to 0.15. A detailed study is made of the structure dependence of the critical-point correlations ${〈{S}_{0}^{z}{S}_{\stackrel{\ensuremath{\rightarrow}}{\mathrm{r}}}^{z}〉}_{c}$ for various models. This leads to the revised, universal estimate ${\ensuremath{\varphi}}_{c}\ensuremath{\simeq}0$. 15 for all three cubic lattice, spin-\textonehalf{} Ising models. The results are compared d briefly with various experiments which support $\ensuremath{\eta}\ensuremath{\gtrsim}0.05$.

Physical review. B, Solid state•Apr 1, 1972•196 citations
The zero-field, two-point correlation function of an nnn-vector system in d=4\ensuremath−\ensuremathϵd=4\ensuremath{-}\ensuremath{\epsilon}d=4\ensuremath−\ensuremathϵ dimensions is calculated to order \ensuremathϵ2{\ensuremath{\epsilon}}^{2}\ensuremathϵ2 for T> TcT>~{T}_{c}T> Tc​. The scaling function is obtained as a closed, cutoff-independent integral. As t=(T\ensuremath−Tc)Tc\ensuremath→0t=\frac{(T\ensuremath{-}{T}_{c})}{{T}_{c}}\ensuremath{\rightarrow}0t=Tc​(T\ensuremath−Tc​)​\ensuremath→0 at fixed wave vector qqq, the leading variation is {{\stackrel{^}{E}}_{1}}^{n,d}(q){t}^{1\ensuremath{-}\ensuremath{\alpha}}+{{\stackrel{^}{E}}_{2}}^{n,d}(q)t, where \ensuremathα\ensuremath{\alpha}\ensuremathα is the specific-heat exponent; thence the maximum in the scattering above Tc{T}_{c}Tc​ is located, in good agreement with high-TTT series-expansion estimates.
The zero-field two-point correlation function of an nnn-vector system in ddd dimensions is calculated to order 1n\frac{1}{n}n1​ for $T\ensuremath{\ge}{T}_{c}$ and 2<d<42<d<42<d<4. The critical-point scaling function is obtained as a closed cutoff-independent integral. As $t=\frac{(T\ensuremath{-}{T}_{c})}{{T}_{c}}\ensuremath{\rightarrow}0$ at fixed wave vector qqq, the variation of the Fourier transform of the correlation function is ${\stackrel{^}{E}}_{1}(q){t}^{1\ensuremath{-}\ensuremath{\alpha}}+{\stackrel{^}{E}}_{2}(q)t+{\stackrel{^}{E}}_{3}(q){t}^{2}+\ensuremath{\cdots}$, where $\ensuremath{\alpha}$ is the specific-heat exponent and ${\stackrel{^}{E}}_{2}$, ${\stackrel{^}{E}}_{3}$ are of order 1n\frac{1}{n}n1​. At d=3d=3d=3 the term t2{t}^{2}t2 is modified by logarithmic corrections. As $q\ensuremath{\rightarrow}0$ at fixed nonzero ttt, deviations of the scaling function from the Ornstein-Zernike form ${(1+{\ensuremath{\xi}}^{2}{q}^{2})}^{\ensuremath{-}1}$ are of order $\frac{{10}^{\ensuremath{-}3}{\ensuremath{\xi}}^{4}{q}^{4}}{n}$. Results are compared with high-temperature series-expansion estimates and with the $\ensuremath{\epsilon}$-expansion results of previous work.
A detailed calculation to order ${\ensuremath{\epsilon}}^{2}$ of the two-point correlation function in the zero-field critical region ($T\ensuremath{\ge}{T}_{c}$) is presented for an nnn-vector system in $d=4\ensuremath{-}\ensuremath{\epsilon}$ dimensions. Scaling behavior is verified over the full parameter range and the scaling function is obtained as a universal explicit convergent integral (independent of any cutoffs). Study of the scaling function as $T\ensuremath{\rightarrow}{T}_{c}$ in the finite ($q\ensuremath{\ne}0$) momentum limit, confirms the presence of terms varying as ${t}^{1\ensuremath{-}\ensuremath{\alpha}}$ and as ttt [with $t=\frac{(T\ensuremath{-}{T}_{c})}{{T}_{c}}$]; explicit evaluation of their amplitudes reliably determines the form of the scattering intensity at fixed qqq and locates the corresponding maximum accurately.
A dispersion-theory approach provides an exact representation of the two-point correlation function $G(\stackrel{\ensuremath{\rightarrow}}{\mathrm{q}},t)=C{t}^{\ensuremath{-}\ensuremath{\gamma}}g({q}^{2}{\ensuremath{\xi}}^{2})$, where $t=\frac{(T\ensuremath{-}{T}_{c})}{{T}_{c}}$ and $\ensuremath{\xi}$ is the correlation length, which describes the critical scattering near a second-order phase transition. The threshold property of the spectral weight function $F(\frac{x}{3})\ensuremath{\propto}\mathrm{Im}{g}^{\ensuremath{-}1}(\ensuremath{-}{x}^{2})$ is used to motivate an approximation to the scaling function g(x2)g({x}^{2})g(x2) based on the asymptotically exact Fisher-Langer approximant ${g}_{\mathrm{FL}}({x}^{2})=(\frac{{C}_{1}}{{x}^{2\ensuremath{-}\ensuremath{\eta}}})(1+\frac{{C}_{2}}{{x}^{\frac{(1\ensuremath{-}\ensuremath{\alpha})}{\ensuremath{\nu}}}}+\frac{{C}_{3}}{{x}^{\frac{1}{\ensuremath{\nu}}}})$, where $\ensuremath{\alpha}$, $\ensuremath{\eta}$, $\ensuremath{\nu}$ are the usual critical exponents. The approximation consists of truncating the spectral function associated with ${g}_{\mathrm{FL}}^{\ensuremath{-}1}({x}^{2})$ in a manner designed to simulate the known threshold property of the exact spectral function, namely F(x3)=0F(\frac{x}{3})=0F(3x​)=0 for $x\ensuremath{\le}3$. The new approximant is checked on the two-dimensional Ising model and shown to agree with the exact result to better than 0.03% for all xxx. Near four dimensions, the agreement with exact results is also excellent. A phenomenological approach to the intermediate three-dimensional case is presented, and shown to be in good agreement with high-temperature series and $\ensuremath{\epsilon}$-expansion results. The dispersion-theory approach is also shown to provide a convenient framework for calculations within the $\ensuremath{\epsilon}$ expansion and is used to compute g(x2)g({x}^{2})g(x2) to $O({\ensuremath{\epsilon}}^{3})$, a new result.
The zero-field critical behavior of ferromagnets above Tc{T}_{c}Tc​, with both isotropic exchange coupling and dipolar interactions, is studied by renormalization-group techniques in $d=4\ensuremath{-}\ensuremath{\epsilon}$ dimensions with n(=d)n (=d)n(=d) component spins. The critical exponents are calculated to order ${\ensuremath{\epsilon}}^{2}$, and are found to be numerically very close to their nondipolar analogs. In particular the correlation length exponent is given by $2\ensuremath{\nu}=1+(\frac{9}{34})\ensuremath{\epsilon}+(\frac{7013}{58956}){\ensuremath{\epsilon}}^{2}+O({\ensuremath{\epsilon}}^{3})$. The value of the specific-heat exponent ${\ensuremath{\alpha}}_{s} (=2\ensuremath{-}d\ensuremath{\nu})$ seems inconsistent with experimental data (at d=3d=3d=3, $\ensuremath{\epsilon}=1$). The critical scattering function is shown to have the form ${\ensuremath{\Gamma}}^{\ensuremath{\alpha}\ensuremath{\beta}}(\stackrel{\ensuremath{\rightarrow}}{\mathrm{q}})=C{t}^{\ensuremath{-}\ensuremath{\gamma}}\stackrel{^}{D}({\ensuremath{\xi}}^{2}{q}^{2})({\ensuremath{\delta}}_{\ensuremath{\alpha}\ensuremath{\beta}}\ensuremath{-}\frac{{q}^{\ensuremath{\alpha}}{q}^{\ensuremath{\beta}}}{{q}^{2}})$ to all orders in $\ensuremath{\epsilon}$. The exponents related to the leading correction to scaling, to crossovers to anisotropic exchange behavior, and to cubic dipolar behavior, are also calculated, and are found to differ significantly from their nondipolar counterparts.
The theory of the correlations and critical scattering of two- and three-dimensional nearest-neighbor Ising models is discussed critically. A distinction is drawn between $\ensuremath{\kappa}(T)$, the true inverse range of exponential decay of the correlations, and ${\ensuremath{\kappa}}_{1}(T)$, the effective range determined from the low-angle scattering intensity. Ten to eleven terms of appropriate high-temperature series exapnsions for $\ensuremath{\kappa}$ and ${\ensuremath{\kappa}}_{1}$ are determined for the square and simple cubic lattices, and shorter series are given for the triangular, fcc, and bcc lattices. For the former lattices, the complete correlation expansions are obtained to the same order. It is shown that $\ensuremath{\kappa}$ and ${\ensuremath{\kappa}}_{1}$ vary as ${(T\ensuremath{-}{T}_{0})}^{\ensuremath{\nu}}$ when $T\ensuremath{\rightarrow}{T}_{c}$, with $\ensuremath{\nu}=1$ for dimensionality d=2d=2d=2, but $\ensuremath{\nu}=0.6430\ifmmode\pm\else\textpm\fi{}0.0025\ensuremath{\simeq}\frac{9}{14}$ for d=3d=3d=3. The asymptotic decay of correlation at T=TcT={T}_{c}T=Tc​ is found to be $\frac{1}{{r}^{d\ensuremath{-}2+\ensuremath{\eta}}}$, where $\ensuremath{\eta}$ is related to the exponent $\ensuremath{\gamma}$ of the divergence of the susceptibility by $(2\ensuremath{-}\ensuremath{\eta})\ensuremath{\nu}=\ensuremath{\gamma}$, Numerical values are $\ensuremath{\eta}=\frac{1}{4}$ for d=2d=2d=2 and $\ensuremath{\eta}=0.056\ifmmode\pm\else\textpm\fi{}0.008\ensuremath{\simeq}\frac{1}{18} \mathrm{for} d=3$. The relative scattering intensity $\stackrel{^}{\ensuremath{\chi}}$ as a function of wave number k is given to high accuracy for all T> TcT>~{T}_{c}T> Tc​ by $\stackrel{^}{\ensuremath{\chi}}(\mathbf{k},T)\ensuremath{\simeq}\left(\frac{a}{{r}_{1}}\right)\frac{^{2\ensuremath{-}\ensuremath{\eta}}[{({\ensuremath{\kappa}}_{1}a)}^{2}+{\ensuremath{\varphi}}^{2}{a}^{2}{K}^{2}(\mathbf{k})]^{\frac{\ensuremath{\eta}}{2}}}{[{({\ensuremath{\kappa}}_{1}a)}^{2}+\ensuremath{\psi}{a}^{2}{K}^{2}(\mathbf{k})]},$ where (i) aaa is the lattice spacing, (ii) ${a}^{2}{K}^{2}=2d[1\ensuremath{-}{q}^{\ensuremath{-}1}\ensuremath{\Sigma}\mathrm{exp}(i\mathbf{k}\ifmmode\cdot\else\textperiodcentered\fi{}\mathbf{r})]\ensuremath{\simeq}{(\mathrm{ka})}^{2}$, the sum being over the qqq nearest-neighbor lattice sites, (iii) r1(T){r}_{1}(T)r1​(T) is a slowly-varying decreasing function near Tc{T}_{c}Tc​, (iv) $\ensuremath{\psi}=1+\frac{1}{2}\ensuremath{\eta}{\ensuremath{\varphi}}^{2}$, and $(\mathrm{v}) \ensuremath{\varphi}(T)$ is slowly varying with a magnitude at Tc{T}_{c}Tc​ of 0.03 for d=2d=2d=2 and of 0.06 to 0.09 for d=3d=3d=3. Explicit formulas are given for ${\ensuremath{\kappa}}_{1}$, r1{r}_{1}r1​, and $\ensuremath{\varphi}$ as functions of TTT. The correlations and the scattering are isotropic near Tc{T}_{c}Tc​. The critical scattering isotherm is curved for low kkk according to ${\stackrel{^}{\ensuremath{\chi}}}^{\ensuremath{-}1}\ensuremath{\sim}{k}^{2\ensuremath{-}\ensuremath{\eta}}$ and it intersects the isotherms for T>TcT>{T}_{c}T>Tc​. Correspondingly, $\stackrel{^}{\ensuremath{\chi}}(\mathbf{k},T)$ exhibits a maximum for fixed k, at a temperature above Tc{T}_{c}Tc​; for d=2d=2d=2 the maxima are very well marked, but for d=3d=3d=3 they are smaller and occur closer to Tc{T}_{c}Tc​. The theory is compared favorably with recent neutron-scattering experiments on pure beta-brass.
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