The exact solution is obtained for the dynamics of a two-level system with unequal relaxation times subjected to the field of a pulse of arbitrary duration and amplitude. The shape of the pulse for which this exact solution can be obtained is found by the inverse problem method.
A theoretical analysis is made of the interaction between a two-level quantum-mechanical system and an electromagnetic field which is frequency- and amplitude-modulated. Attention is drawn to the fact that, subject to certain general assumptions, the usual methods for population inversion in such a system—(2 n + l)π pulses and adiabatic inversion methods—apply also if the pump field is of the wide-band type. Exact solutions are obtained for the nature of the time dependence of the instantaneous field frequency at which a population inversion occurs under nonadiabatic conditions.
Effect of relaxation time on the performance of photonic crystal optical bistable switches based on Kerr nolinearity is discussed. This paper deals with optical pulses with the duration of about 50 ps. In such cases the steady state response of the optical device can be used to approximate the pulse evolution if the nonlinearity is assumed instantaneous, hence analytical solutions such as the coupled mode theory can be used to obtain the time evolution of the electromagnetic fields. However if the relaxation time of the material nonlinear response is also considered, changes in the power levels and in the shape of the hystersis loop is observed. In this case, we use the nonlinear finite difference time domain method (NL-FDTD) to follow the system dynamics and get the bistability hystersis loop. Codes are developed to analyze the instantaneous Kerr materials and the Kerr materials with finite response times. Depending on the material, the relaxation times of the order of 1-10fs should be considered in studying bistability to obtain the right shape of the output pulses. It is observed that the relaxation leads to larger input power and threshold and hence degrades the performance of the switch in pulse shaping.
Spin dynamics in pulsed Nuclear Magnetic Resonance (NMR) spectroscopy are studied theoretically using spin density operator formulation. The theory exploits the use of irreducible spherical tensor (multipole) operators of spin angular momentum in developing alternative treatments to spin dynamical problems. Applications in spin decoupling and soft pulse dynamics are considered, giving new analytical solutions for the complete density matrix. The focus of the thesis, however, is on the development of two distinctly new methods of solution to the quantum Liouville equation for NMR field modulation. The first method derives a linear integral equation for the magnetization and provides a rapidly converging integral series solution which is useful in explaining many pulse shapes. The second method uses the Wei-Norman Lie algebra approach$ sp{ rm 96}$ which reduces the complete arbitrary spin I problem to a Riccati equation. Novel exact analytical solutions for a class of temporal field modulations are obtained. In contrast to all other existing formulations, the theory provides the first known examples of exactly soluble nonrectangular pulse shapes for all resonance off-set, all field amplitudes, all time and valid for all spin I $ geq$ 1/2. In addition, a new series expansion for the complete spin density matrix is obtained. The theory is applied to producing spin inversion profiles which show applicability to selective excitation.