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Progress of Theoretical Physics

The Large Time Limit of the Evolution Kernel

Hitoshi Higurashi, R. Fukuda

Published Feb 1, 1990• 2 citations
Publisher

Abstract

In order to study the validity of the functional integral formula of the Green's function, the large time limit of the time evolution kernel exp (-iHt) of any quantum system is discussed. With the Feynman prescription, giving an infinitesimally small negative imaginary part to quadratic term of the potential in the Hamiltonian, the correct formula for this limit is obtained. It differs from the naive formula and depends on the detailed form of the potential. The usual formula holds for the perturbative expansion in terms of the potential, the proof of which is given by the path integral method. The new expression for the ground state wave function is also obtained in the course of the proof.

DOI
10.1143/ptp.83.305

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In order to study the validity of the functional integral formula of the Green's function, the large time limit of the time evolution kernel exp (-iHt) of any quantum system is discussed. With the Feynman prescription, giving an infinitesimally small negative imaginary part to quadratic term of the potential in the Hamiltonian, the correct formula for this limit is obtained. It differs from the naive formula and depends on the detailed form of the potential. The usual formula holds for the perturbative expansion in terms of the potential, the proof of which is given by the path integral method. The new expression for the ground state wave function is also obtained in the course of the proof.
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Diagrammatical expansion of the quantum field theory with the finite time interval is discussed by evaluating the time evolution kernel. The coherent state representation is adopted which is the most convenient formalism for this purpose. It is applied to quantum electrodynamics (QED) to derive the Feynman rule for the kernel. The rule for the matrix element of any operator is also given. Our method can also be a systematic approach to the time dependent perturbation theory. As an example, a full order formula of the transition amplitude between the number states is given in terms of the connected Green's functions.
There exists the well known approximate expression describing the large time behaviour of matrix elements of the evolution operator in quantum theory: =exp(at)+... This expression plays the crucial role in considerations of problems of quantum decoherence, radiation, decay, scattering theory, stochastic limit, derivation of master and kinetic equations etc. This expression was obtained in the Weisskopf-Wigner approximation and in the van Hove (stochastic) limit. We derive the exact general formula which includes the higher order corrections to the above approximate expression: =exp(At+B+C(t)). The constants A and B and the oscillating function C(t) are computed in perturbation theory. The method of perturbation of spectra and renormalized wave operators is used. The formula is valid for a general class of Hamiltonians used in statistical physics and quantum field theory.
There exists the well-known approximate expression describing the large time behavior of matrix elements of the evolution operator in quantum theory: < U(t)>≃ exp (at). This expression plays the crucial role in considerations of problems of quantum decoherence, radiation, decay, scattering theory, stochastic limit, derivation of master and kinetic equations etc. This expression was obtained in the Weisskopf–Wigner approximation and in the van Hove (stochastic) limit. We derive the exact general formula which includes the higher order corrections to the above approximate expression: <U(t)>= exp (At+B+C(t)). The constants A and B and the oscillating function C(t) are computed in perturbation theory. The method of perturbation of spectra and renormalized wave operators is used. The formula is valid for a general class of Hamiltonians used in statistical physics and quantum field theory.
We first rewrite the perturbation expansion of the time evolution operator [An Min Wang, quant-ph/0611216] in a form as concise as possible. Then we derive out the perturbation expansion of the time-dependent complete Green operator and prove that it is just the Fourier transformation of the Dyson equation. Moreover, we obtain the perturbation expansion of the complete transition amplitude in the Feynman path integral formulism, and give an integral expression that relates the complete transition amplitude with the unperturbed transition amplitude. Further applications of these results can be expected and will be investigated in the near future.
The coordinate matrix element of the time evolution operator, exp[−iĤt/ℏ], is determined by expanding (its exponent) in a power series in t. Recursion relations are obtained for the expansion coefficients which can be analytically evaluated for any number of degrees of freedom. Numerical application to the tunneling matrix element in a double well potential and to the reactive flux correlation function for a barrier potential show this approach to be a dramatic improvement over the standard short time approximation for the propagator. Its use in a Feynman path integral means that fewer ‘‘time slices’’ in the matrix product exp[(−i/ℏ)ΔtĤ]N, Δt=t/N, will be required. The first few terms in the present expansion constitute a fully quantum version of the short time propagator recently obtained by us using semiclassical methods [Chem. Phys. Lett. 151, 1 (1988)].