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Physica A Statistical Mechanics and its Applications

Effect of the density-gradient term in the free energy expression on critical exponents

O. K. Rice, D.R. Chang

Published Jan 1, 1976• 0 citations
Publisher
DOI
10.1016/0378-4371(75)90025-4

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Abstract Some properties of an ideal gas of massive bosons in a mean field potential and, confined between two infinite parallel slabs in a d-dimensional configuration space are investigated systematically. Here, one particle density of states approach is employed to study the critical temperature, shift of density, Casimir effects and critical exponents, starting from the evaluation of the grand canonical free energy in d-dimension. We have found that, the shift of density, Casimir force and the critical temperature depend on the space dimensionality. But the Casimir force decays as an inverse power law of the distance between two slabs in the condensate and, decays exponentially in the non-condensed state situated very close to the point of phase transition. Specifically, this study enabled us to predict the shift of the density of boson in the excited states due to mean field potential, and also the dimensional dependence of the critical exponent. The form of the critical exponent is found to be 1 d − 2 for the imperfect Bose gas. This leads to a value of critical exponent 1 for d = 3. Most interestingly, in the limit when the mean field potential goes to zero the resulting expressions for the above properties coincide with those of the ideal Bose gas.
The definitions and determination of the thermodynamic magnetic critical point exponents α, α′, β, γ, γ′ and δ are reviewed, and ``gap exponents'' Δ and Δ′ for the divergences of higher derivatives of the free energy with respect to the field are introduced. The rigorous inequalities relating the exponents are discussed. The ``microdomain'' or ``cluster'' model of ferromagnetism leads to relations between these exponents since it expresses them in terms of two underlying exponents σ and τ. The exponent σ is directly related to the effective surface free energy of a large microdomain and thence to the dimensionality. This yields some insight into the meaning of the observed exponent values and of the differences between the critical behavior of the Ising and Heisenberg models. The recently developed homogeneity and scaling arguments are presented. These generate the same thermodynamic exponent relations and further ones for the correlation exponents η, ν and ν′. They also indicate that a general law of corresponding states might hold in the critical region. Theoretical and experimental evidence on the validity of these various ideas is briefly reviewed.
Phenomenological models with "planar-spin" and "antiferromagnetic" dynamics are introduced, and their critical behavior is analyzed using renomalization-group methods. Dynamic scaling is shown to hold for these models to all orders in $\ensuremath{\epsilon}=4\ensuremath{-}d$, and the dynamic exponents are expressed entirely in terms of static exponents, in agreement with earlier phenomenological and mode-coupling theories. The magnitudes of the diverging transport and kinetic coefficients are expressed purely in terms of static properties and of universal constants which are calculated to second order in $\ensuremath{\epsilon}$. Matching conditions are proved between the characteristic frequencies above and below Tc{T}_{c}Tc​, and the corresponding universal amplitude ratios are calculated to second order in $\ensuremath{\epsilon}$. The principal applications are to liquid helium and the Heisenberg antiferromagnet RbMnF3{\mathrm{F}}_{3}F3​, where the experimental exponents and amplitudes both agree reasonably well with theory. In the case of liquid helium ("asymmetric" case with $\ensuremath{\alpha}<0$) the asymptotic critical behavior is somewhat masked by correction terms, due to the slow approach of the spectific heat to its finite value at ${T}_{\ensuremath{\lambda}}$. These correction terms are analyzed in detail, and a proposal is made for extracting the true asymptotic behavior from the data. The effects of other conserved fields such as the mass density and momentum in helium, and the energy density in the magnet, are considered, and shown to be irrelevant for the critical behavior of the order parameter.