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Physica A Statistical Mechanics and its Applications

Derivation of the generalized nonequilibrium statistical operator from the extremum of the Von Neumann Entropy

Z. Onyszkiewicz

Published May 1, 1987• 8 citations
Publisher
DOI
10.1016/0378-4371(87)90069-0

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For the general class of quasifree fermionic right mover/left mover systems over the infinitely extended two-sided discrete line introduced in Aschbacher [Rev. Math. Phys. 35, 2330001 (2023)] within the algebraic framework of quantum statistical mechanics, we study the von Neumann entropy of a contiguous subsystem of finite length in interaction with its environment. In particular, under the assumption of spatial translation invariance, we analyze the asymptotic behavior of the von Neumann entropy for large subsystem lengths and prove that its leading order density is, in general, nonvanishing and displays the signature of a mixture of the independent thermal species underlying the right mover/left mover system. As special cases, the formalism covers so-called nonequilibrium steady states, thermal equilibrium states, and ground states. Moreover, for general Fermi functions, we derive a necessary and sufficient criterion for the von Neumann entropy density to vanish.
A central open question in quantum thermodynamics is the identification of thermodynamic entropy away from equilibrium. Although thermodynamic entropy coincides with the von Neumann entropy for a Gibbs state at equilibrium, the thermodynamic role of quantum coherence generated during nonequilibrium evolution remains unclear. Here, we show that von Neumann entropy does not, in general, represent the thermodynamic entropy governing heat exchange in coherent nonequilibrium quantum systems. By integrating the resource theory of quantum coherence with thermodynamic principles, we develop a general framework for nonequilibrium quantum thermodynamics. We identify thermodynamic entropy with the energy entropy derived from energy-measurement statistics and introduce a dynamical temperature extending the equilibrium concept to nonequilibrium states. Consequently, we obtain an exact entropy-balance relation separating the entropy flux associated with heat exchange from the coherence-loss contribution to entropy production, establishing an operational connection between quantum coherence, heat flow, and total entropy change. Unlike approaches relying on equilibrium reference states or stationary Gibbs ensembles, our framework uses instantaneous dynamical quantities and remains valid throughout transient nonequilibrium evolution. It provides consistent dynamical definitions of temperature, work, heat, and free energy. Applying the formalism to an exactly solvable open quantum system, we show that the first and second laws hold throughout transient evolution and that equilibrium thermodynamics emerges dynamically in the weak-coupling long-time limit. Our results establish a unified framework for coherent nonequilibrium quantum thermodynamics and suggest opportunities for controlling heat dissipation through coherence engineering in quantum thermal technologies.