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Physical Review E

Interacting Bose gas: Mean field and fluctuations revisited

Angel Alastuey, J. Piasecki

Published Oct 17, 2011• 5 citations
Publisher

Abstract

We present the description of thermodynamic properties of a Bose gas by considering the hierarchy of equations satisfied by imaginary-time Green functions. In the case of an ideal gas the appearance of the off-diagonal long-range order (presence of condensate) is derived in a particularly simple way. The simplicity of the analysis persists at the level of the mean-field theory. Using Kac's scaling of the repulsive binary potential we then determine asymptotic corrections to the mean-field theory for thermodynamic states far from the region of the mean-field condensation. Our predictions are in accordance with rigorous results obtained previously, whereas the Hartree-Fock approximation is shown to neglect a whole class of equally important contributions.

DOI
10.1103/physreve.84.041122

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We present the description of thermodynamic properties of a Bose gas by considering the hierarchy of equations satisfied by imaginary-time Green functions. In the case of an ideal gas the appearance of the off-diagonal long-range order (presence of condensate) is derived in a particularly simple way. The simplicity of the analysis persists at the level of the mean-field theory. Using Kac's scaling of the repulsive binary potential we then determine asymptotic corrections to the mean-field theory for thermodynamic states far from the region of the mean-field condensation. Our predictions are in accordance with rigorous results obtained previously, whereas the Hartree-Fock approximation is shown to neglect a whole class of equally important contributions.
We study a homogeneous Bose gas with purely repulsive forces. Using the Kac scaling of the binary potential we derive analytically the form of the thermodynamic functions of the gas for small but finite values of the scaling parameter in the low density regime. In this way we determine dominant corrections to the mean-field theory. It turns out that repulsive forces increase the pressure at fixed density and decrease the density at given chemical potential (the temperature is kept constant). They also flatten the Bose momentum distribution. However, the present analysis cannot be extended to the region where the mean-field theory predicts the appearance of condensate.
The density fluctuation in a Bose gas interacting via a strong short-range repulsive potential and a weak long-range attractive potential is studied by the methods of quantum-field theory. The density-density correlation function is generated by taking the functional derivative of the single-particle matrix Green's function G1(1,2){G}_{1}(1,2)G1​(1,2) with respect to an auxiliary scalar field. For G1(1,2){G}_{1}(1,2)G1​(1,2), we use the Hartree approximation for the attractive potential and the Hartree-Fock approximation for the short-range repulsive potential. We show that the density fluctuation spectrum is identical to the Beliaev approximation for the single-particle excitation spectrum.
This paper presents a conserving gapless mean-field theory for weakly interacting Bose gases. We first construct a mean-field Luttinger-Ward thermodynamic functional in terms of the condensate wave function ΨΨΨ and the Nambu Green's function G^\hat{G}G^ for the quasiparticle field. Imposing its stationarity respect to ΨΨΨ and G^\hat{G}G^ yields a set of equations to determine the equilibrium for general non-uniform systems. They have a plausible property of satisfying the Hugenholtz-Pines theorem to provide a gapless excitation spectrum. Also, the corresponding dynamical equations of motion obey various conservation laws. Thus, the present mean-field theory shares two important properties with the exact theory: ``conserving'' and ``gapless.'' The theory is then applied to a homogeneous weakly interacting Bose gas with s-wave scattering length aaa and particle mass mmm to clarify its basic thermodynamic properties under two complementary conditions of constant density nnn and constant pressure ppp. The superfluid transition is predicted to be first-order because of the non-analytic nature of the order-parameter expansion near TcT_{c}Tc​ inherent in Bose systems, i.e., the Landau-Ginzburg expansion is not possible here. The transition temperature TcT_{c}Tc​ shows quite a different interaction dependence between the nnn-fixed and ppp-fixed cases. In the former case TcT_{c}Tc​ increases from the ideal gas value T0T_{0}T0​ as Tc/T0=1+2.33an1/3T_{c}/T_{0}= 1+ 2.33 an^{1/3}Tc​/T0​=1+2.33an1/3, whereas it decreases in the latter as Tc/T0=1−3.84a(mp/2πℏ2)1/5T_{c}/T_{0}= 1- 3.84a(mp/2π\hbar^{2})^{1/5}Tc​/T0​=1−3.84a(mp/2πℏ2)1/5. Temperature dependences of basic thermodynamic quantities are clarified explicitly.
Abstract We consider a Bose gas with two-body Kac-like scaled interactions where is a given repulsive and integrable potential, while is a positive parameter which controls the range of the interactions and their amplitude at a distance r. Using the Hartree–Fock (HF) approximation we find that, at finite non-zero temperatures, the Bose–Einstein (BE) condensation is destroyed by the repulsive interactions when they are sufficiently long-range. More precisely, we show that for sufficiently small but finite the off-diagonal part of the one-body density matrix always vanishes at large distances. Our analysis sheds light on the coupling between critical correlations and long-range interactions, which might lead to the breakdown of the off-diagonal long-range order even beyond the HF approximation. Furthermore, our HF analysis shows the existence of a threshold value above which the BE condensation is restored. Since is an unbounded increasing function of the temperature this implies for a fixed , namely for a fixed scaled potential, that a condensate cannot form above some critical temperature whatever the value of the density.
Abstract We analyze the correspondence between two formalisms describing an interacting Bose gas, namely the standard Feynman diagrammatic expansion on the one hand, and the hierarchy equations for the imaginary-time Green functions on the other hand. We show that the Hartree–Fock approximation, as well as its first corrections at low density derived by Baym et al (2001 Eur. Phys. J. B 24 107–24), can be equivalently formulated in both formalisms. Within the hierarchy approach, the two-body correlations are expressed at lowest order in the interactions in terms of the full one-body Green function. This sheds light on the physical content of the corrections to the Hartree–Fock theory. Moreover, this representation of can be extended to higher orders, opening the way to systematic calculations of further corrections to the ideal critical temperature when the density increases.
We study the condensation of a homogeneous interacting Bose gas in the presence of a superimposed weak periodic potential. In contrast to, e.g., a harmonic trap, the periodic potential does not reduce the significance of long-wavelength fluctuations and thus influences the phase transition in a more profound way. We present general thermodynamic descriptions of the system above condensation in terms of mean-field as well as renormalization-group theory. Our approaches are based on describing the interplay between the effects of the interactions and the potential by means of a renormalization of the potential amplitude. These theories are then used to study the critical chemical potential and particle density and their dependence on the properties of the applied potential. A main result of our investigations concerns the characteristic nonperturbative momentum scale kc{k}_{c}kc​ of the critical interacting Bose gas. It is shown that the existence of this momentum scale becomes macroscopically manifest in the behavior of the critical thermodynamic properties.