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Physical Review A

Stimulated and spontaneous radiative frequency shifts of a two-level system

F. T. Hioe, Joseph H. Eberly

Published Apr 1, 1975• 24 citations
Publisher

Abstract

The quantum-electrodynamic frequency shifts of a two-level system in spontaneous emission and in an intense quantized radiation field are given up to eighth order in the coupling parameter, using the recursive perturbation method developed previously by one of the authors. The first six orders of the latter agree with the semiclassical result of Shirley and thus disagree with Chang and Stehle's calculation. The eighth-order term agrees with a recent semiclassical calculation by Ahmad and Bullough. The transition from the quantum mechanical case (the number of photons small) to the classical case (the number of photons very large) is also exhibited in our approach.

DOI
10.1103/physreva.11.1358

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The quantum-electrodynamic frequency shifts of a two-level system in spontaneous emission and in an intense quantized radiation field are given up to eighth order in the coupling parameter, using the recursive perturbation method developed previously by one of the authors. The first six orders of the latter agree with the semiclassical result of Shirley and thus disagree with Chang and Stehle's calculation. The eighth-order term agrees with a recent semiclassical calculation by Ahmad and Bullough. The transition from the quantum mechanical case (the number of photons small) to the classical case (the number of photons very large) is also exhibited in our approach.
An improved form of semiclassical radiation theory is developed which includes the effect of the atom's radiation field back on the atom. This formalism is applied to the problem of a single "two-level atom" interacting with a monochromatic field. The resulting equations are solved without resorting to time-dependent perturbation theory, and are found to predict the behavior of the system over times long compared with the lifetime for spontaneous transitions. Not only stimulated emission and absorption, but also spontaneous emission with the proper Einstein AAA coefficient, and a frequency shift which agrees at least semiquantitatively with the Lamb shift are described. In addition, several nonlinear effects involving the interference between spontaneous and stimulated radiation are described, and new experiments which might detect such effects are suggested.
An improved form of semiclassical radiation theory is developed which includes the effect of the atom's radiation field back on the atom. This formalism is applied to the problem of a single two-level atom interacting with a monochromatic field. The resulting equations are solved without resorting to time-dependent perturbation theory, and are found to predict the behavior of the system over times long compared with the lifetime for spontaneous transitions. Not only stimulated emission and absorption, but also spontaneous emission with the proper Einstein AAA coefficient, and a frequency shift which agrees at least semiquantitatively with the Lamb shift are described. In addition, several nonlinear effects involving the interference between spontaneous and stimulated radiation are described, and new experiments which might detect such effects are suggested.
The spontaneous radiative decay to the ground state of an atomic system initially in the higher of two excited states, coupled in a radiationless fashion by an external field, is investigated by the method of multiple-time-scale perturbation theory. The coupled differential equations of motion for the probability amplitudes are solved to second order, while the usual secular behavior of conventional time-dependent perturbation theory is eliminated in terms of two natural time scales: a fast time scale corresponding to the reciprocal of the level transition frequency and a slower time scale associated with the inverse of the radiation linewidth. Expressions are obtained to this order for the energy shifts and decay characteristics of the excited states and the energy distribution of the final-state photons, quantities previously determined by Fourier analysis and contour integration and by the phenomenological approach of Weisskopf and Wigner. A detailed comparison of these various methods of solution includes conditions under which the present results agree to second order with the previous calculations.
Reports a natural all-order decorrelation procedure for the interaction of a single two-level atom with all modes of the radiation field which replaces the semiclassical boson approximation for the atom by an exact fermion treatment. In consequence, the spontaneous emission of the semiclassical theory is extended to include stimulated emission, a semiclassical Lamb-type shift is explicitly replaced by a shift satisfying the Bethe formula manifestly due to vacuum fluctuations, and there can be two intensity-dependent terms, one of which generalizes the Bethe formula.
A general approximation method is developed for the treatment of bound quantum systems in the presence of an intense external electromagnetic field of long wavelength. The method is based upon a unitary transformation which approximately removes the electromagnetic field from the problem. The accuracy of the technique increases with the number of photons involved in any given process; and in the case of large photon number, the results have a simple, concise form resembling first-order perturbation theory. It is possible to handle intense-field problems with small numbers of photons also, but then the formalism takes on a complexity analogous to the corresponding perturbation expressions for the same number of photons. The theory is extended to the case where two electromagnetic field modes are present, one or both of which may be intense. Bound-bound transitions in a hydrogenlike atom are calculated as an illustration of the application of the method. One of the explicit nonlinear effects to appear is an intensity-dependent deviation of the transition probability behavior from In{I}^{n}In for nnn-photon transitions, where III is the field intensity. It is demonstrated that intensity effects are much more probable with bound electrons than with free electrons.
A new approach to the study of the spontaneous emission of the quantum system driven by a high-intensity laser field is developed. This approach is based on the accurate consideration of quantum system interaction with vacuum quantized field modes in the first order of perturbation theory, while the intense laser field is considered classically beyond the perturbation theory which allows to observe any-order stimulated processes governed by classical field. The proposed approach is applied to the study of a number of quantum systems in intense laser field. The obtained data are compared with those obtained in the frames of semiclassical approximation typically used for analyzing of the strong-field dynamic. It is found that the applicability of the semiclassical approach is strictly limited. It is valid for calculation of transitions to the initially populated state only if the population of this state is close to unity during the pulse and in the after-pulse regime. If its population is depleted, the semiclassical approach fails.