Recently, Lippmann showed that a time operator might exist in quantum theory and that its explicit form is i ∂/∂E in the energy representation. In this paper, we wish to stress that i ∂/∂E actually represents only the time which the particle used to move from the scattering center to a certain point at the outside. (Later on, we shall call this time the "time of motion.") We also show that, although it is possible to define an operator for the "time of motion" of the particle in the energy representation, it is necessary to introduce a new conjugate representation of the energy representation, the "time representation," to overcome difficulties which may arise in the evaluation of the mean time of motion [Formula: see text]. If the position representation is used for the calculation instead, we shall meet these difficulties. The reason is that time of motion T, position x, and energy E are not two-by-two compatible variables. Bearing in mind that i ∂/∂E only represents the time of motion of the particle, we can then deduce the explicit form of the delay time operator Q in terms of the scattering matrix S directly from the time of motion operator by simple reasoning. This form is Q = −i(∂S/∂E)·S† as was found previously. Some interesting features of the delay time operator will also be sketched at the end of the paper.
In time-dependent scattering theory, the collision problem is described by assuming that a particle was localized outside the interaction domain where V = 0. After collision, there exists a definite probability that the particle is deflected from its impact direction at a certain scattering angle. After collision, there exists a definite probability that the particle is deflected from its impact direction at a certain scattering angle. This probability cannot be directly observed in experiments but is indirectly accessible to measurements through differential cross sections. The unitarity of the operator S is one of the most important properties of the S-matrix theory of scattering. Of course, the study of the S-matrix will greatly be facilitated by the knowledge that the S-operator belongs to a narrower class of the unitary operators.
Abstract In this chapter we explain how particle scattering can be described by local observables. First we introduce the concept of the S-matrix, which is an idea common to classical and quantum mechanics. We show the construction of incoming and outgoing states which have a certain asymptotic behaviour at time −∞ and +∞, and we also show that the constructed states have an acceptable physical asymptotic behaviour. Then we derive the representation of the S-matrix given by these scattering states and discuss its properties.
The Quantum Mechanical Theory of Collis3ions. I»-In the present course we shall consider the quantum mechanical treatment of problems of particle interactions in which at least one of the particles is unbound and therefore able to travel large distances freely.In effect such particles are able to communicate the results of their interaction directly to macroscopic detection apparatus* The interpretation of the resulting data is in general the most direct way of forming conclusions about the interactions.A considerable variety of physical phenomena involves unbound particles» Among the simplest are scattering processes ;in particular the deflection of particles from a collinated beam.More general collision processes which induce reactions of various sorts also lie within the class we shall examine, Our chief concern willbe with the means of solving problems in which well-defined models have been postulated to describe the basic interactions.We shall restrict ourselves, in fact, to the treatment of fairly simple models, and shall discuss a number of approaches to the problems they raise.We begin by discussing the scattering of particles by a simple potential field, fixed in space» The problem of two free particles with a potential between them of course assumes this form in the center-of-mass system.By imagining that a beam of particles of constant strenght is at all times being scattered by the potential, we cay seek to describe the situation with the stationary-state Schrb'dinger equation.
The orders of the perturbation approximation to the Schroedinger-picture time evolution operator in powers of the presumed-small perturbation part of the Hamiltonian operator are developed by the iteration of an identity; the possibly confusing switch to the interaction picture isn't needed. Those time-evolution operator approximations are sandwiched between two orthogonal, normalized eigenstates of the unperturbed part of the Hamiltonian operator to produce the transition amplitude approximations, whose calculation is reduced to quadrature when every occurrence of the perturbation part of the Hamiltonian operator in them is expanded in the unperturbed basis. That expansion also reveals the time-dependent parts of those approximations to be multiply nested integrals which in the long-time limit approach simple products of non-singular inverses (principle value plus delta function) of differences of unperturbed energy eigenvalues. Closely related to the long-time limits of transition amplitudes are the long-time averages of transition rates. When the unperturbed basis is that of free-particle states, sums over relevant final states of transition rates from an initial state, divided by the initial state's particle flux, produce cross sections. Here the perturbation approximations to generic quantum transition rates are parlayed to the corresponding approximations to differential cross sections for nonrelativistic-particle potential scattering.
The purpose of these lectures is to give an accessible and self contained introduction to quantum scattering theory in one dimension. Part A defines the theoretical playground, and develops basic concepts of scattering theory in the time domain (Asymptotic Condition, in- and out- states, scattering operator
S^). The aim of Part B is then to build up, in a step-by-step fashion, the time independent scattering theory in energy domain. This amounts to introduce the Lippmann-Schwinger equation for the stationary scattering states (denoted as
∣ψE(±1)±⟩), to discuss fundamental properties of
∣ψE(±1)±⟩, and subsequently to construct
S^ and
T^ operators in terms of
∣ψE(±1)±⟩. Physical contents of the
S^ and
T^ operators is then illuminated by deriving explicit formulas for the probability of transmission/reflection of our quantum particle through/from the interaction region of the potential. An illustrative numerical example is given, which also highlights an existence of scattering resonances. Finally, Part C elaborates the nonhermitian scattering theory (Siegert pseudostate formalism), which offers an extremely powerful tool suitable for clear cut understanding of the resonance phenomena.