The conceptual basis of statistical operator is analysed by comparing two different ways of introducing it in quantum mechanics–subsystem method and ensemble method. The one-to-one correspondence of the statistical operator to the physical state properly characterized is contrasted with the deficient degrees of freedom of the wave function. The paradoxical features of the Einstein-Podolsky-Rosen type thought experiment and of the reduction of wave-packet at observation can be dissolved in the reformulation of quantum mechanics in which the statistical operator, instead of the wave function, is primarily introduced as the fundamental quantity to describe the state.
The conceptual basis of statistical operator is analysed by comparing two different ways of introducing it in quantum mechanics–subsystem method and ensemble method. The one-to-one correspondence of the statistical operator to the physical state properly characterized is contrasted with the deficient degrees of freedom of the wave function. The paradoxical features of the Einstein-Podolsky-Rosen type thought experiment and of the reduction of wave-packet at observation can be dissolved in the reformulation of quantum mechanics in which the statistical operator, instead of the wave function, is primarily introduced as the fundamental quantity to describe the state.
Theory of measurement is presented which is based on the statistical interpretation of quantum mechanics. The reduction of wave packet is ascribed to undue comparison of the state of an ensemble before measurement and the state of an individual system after measurement. By studying the evolution of statistical operators for subsystems and composite systems comprising an object, a measuring apparatus and an observer, one can definitely locate where the measurement is done, thus negating the principle of psycho-physical parallelism due to von Neumann. Time needed for measurement is also discussed. The Einstein-Podolsky-Rosen state is described as an eigenstate of correlation. The argument lends support to the standpoint that the physical state of a system is to be represented by the statistical operator, not by the wave function, in the conceptual foundation of quantum mechanics.
Theory of measurement is presented which is based on the statistical interpretation of quantum mechanics. The reduction of wave packet is ascribed to undue comparison of the state of an ensemble before measurement and the state of an individual system after measurement. By studying the evolution of statistical operators for subsystems and composite systems comprising an object, a measuring apparatus and an observer, one can definitely locate where the measurement is done, thus negating the principle of psycho-physical parallelism due to von Neumann. Time needed for measurement is also discussed. The Einstein-Podolsky-Rosen state is described as an eigenstate of correlation. The argument lends support to the standpoint that the physical state of a system is to be represented by the statistical operator, not by the wave function, in the conceptual foundation of quantum mechanics.
The main purpose of this tutorial is to elucidate in details what should be meant by ensemble of states in quantum mechanics, and to properly address the problem of discriminating, exactly or approximately, two different ensembles. To this aim, we review the notion and the definition of quantum ensemble as well as its relationships with the concept of statistical operator in quantum mechanics. We point out the implicit assumptions contained in introducing a correspondence between quantum ensembles and the corresponding single-particle statistical operator, and discuss some issues arising when these assumptions are not satisfied. We review some subtleties leading to apparent paradoxes, and illustrate the role of approximate quantum cloning. In particular, we review some examples of practical interest where different (but equivalent) preparations of a quantum system, i.e. different ensembles corresponding to the same single-particle statistical operator, may be successfully discriminated exploiting multiparticle correlations, or some a priori knowledge about the number of particles in the ensemble.
Throughout quantum mechanics there is statistical balance, in the collective response of an ensemble of systems to differing measurement types. Statistical balance is a core feature of quantum mechanics, underlying quantum mechanical states, and not yet explained. The concept of "statistical balance" is here explored, comparing its meaning since 2019 with its original meaning in 2001. Statistical balance now refers to a feature of contexts in which: (a) there is a prescribed probability other than 0 or 1 for the collective response of an ensemble to one measurement type; and (b) the collective response of the same ensemble to another measurement type demonstrates that no well-defined value can be attributed, for the property relevant to the original measurement type, to individual members of the ensemble. In some unexplained way, the outcomes of single runs of a measurement of the original type "balance" each other to give an overall result in line with the prescribed probability. Unexplained statistical balance prompts caution in assessing the conceptual implications of entanglement, measurement, uncertainty, and two-slit and Bell-type analyses. Physicists have a responsibility to the wider population to be conceptually precise about quantum mechanics, and to make clear that many possible conceptual implications are uncertain.
Recently, the possibility of investigating single molecule, or single spin observables, as well as the necessity of a better understanding of the mechanisms underlying quantum dynamics in order to obtain nanoscale devices and nanostructered materials suitable for quantum computing tasks, have revived the interest in foundational aspects of quantum statistical mechanics. This thesis aims to give a contribution to this field by re-considering the statistical characterization of a quantum system at the light of some paradigmatic changes in our understanding of quantum theory which have taken place in the last two decades. In particular the impressive development of quantum information theory has changed the perceptions of quantum entanglement: for a long time it has been considered a somewhat paradoxical property of the matter at the atomic scale, but now it is regarded as an essential and ubiquitous phenomenon whose consequences are affecting the very macroscopic world that we experience. Still the decoherence program has brought out the importance of considering a quantum system together with its environment in order to clarify some key aspects of quantum dynamics. Thus, we start from the idea that quantum correlations are ubiquitous and somewhat uncontrollable in systems with many degrees of freedom which are typically considered in statistical mechanics. As a consequence we assume the standpoint that quantum statistical mechanics has not to be based on the underlying idea of a collection of many, independent quantum systems but rather it has to emerge at the level of a global wavefunction (pure state) which describes the system as well as its environment as a whole. In order to investigate the consequences of these assumptions we study the equilibrium distribution of an isolated quantum system. This is defined, in analogy with the ergodic foundations of classical statistical mechanics, on the basis of the time evolution of the quantum state. Then, we study the emergence of thermodynamic properties in a quantum system by studying the probability distribution of some function of interests, as the entropy and the equilibrium state of a subsystem, on Ensembles of Pure States. Such a probability distribution is derived from the geometry of the Hilbert space, and the theoretical tools suitable for its characterization are developed. On the one hand we perform a numerical sampling of the ensemble distributions by employing Monte Carlo techniques, on the other hand simpler analytical approximation of the geometrical distributions are derived by means of a maximum entropy principle. Model systems composed of an ensemble of spins are chosen to illustrate the salient features which emerge from the developed theoretical framework: the main point is that the Ensemble Distributions of “thermodynamic observables” (entropy or equilibrium state of a subsystem) are sharply peaked around a typical value. From the analysis it emerges that each of the overwhelming majority of the wavefunctions which has appreciable weight in the considered ensemble, is characterized by the same value of the “macroscopic” functions. This is a striking evidence of the “typicality” of these properties. In the essence, our impossibility to know the state of the system in detail does not matter, just for the remarkable fact that almost all quantum states behave essentially in the same way. By virtue of this typicality the study of the behaviour of the typical values of the thermodynamic function become meaningful. Notably, under certain conditions, one recovers the results of standard statistical mechanics, that is, the equilibrium average of the state of a subsystem can be cast in the Boltzmann canonical form at the temperature given by the usual thermodynamical relation . In the second part of the thesis we consider the dynamical aspects of the equilibrium state of a subsystem interacting with its environment. The fluctuations around the equilibrium average critically depends on the entanglement between the system and the environment and on the form of the interaction Hamiltonian. The connection between the dynamics of the fluctuations of an observable at the equilibrium and the relaxation toward the equilibrium from a “non typical” initial value is also investigated with the aid of simple model systems. The study presented in this thesis was partly motivated by a critical analysis of the statistical methods available for the theoretical modelling of magnetic resonance experiments. One of these, the Stochastic Liouville Equation, has been employed in a work completed during the first year of my Ph.D. program in order to interpret some feature of a two dimensional electron spin resonance experiment, [Fresch B., Frezzato D., Moro G. J., Kothe G., Freed J. H.; J. Phys. Chem. B., 110, 24238, (2006)].
In this paper, we try to give a new approach to the quantum mechanics(QM) on the framework of quantum field theory(QFT). Firstly, we make a detail study on the (non-relativistic) Schrödinger field theory, obtaining the Schrödinger equation as a field equation, after field quantization, the Heisenberg equations for the momentum and position operators of the particles excited from the (Schrödinger) field and the Feynman path integral formula of QM are also obtained. We then give the probability concepts of quantum mechanics in terms of a statistical ensemble, realizing the ensemble(or statistical) interpretation. With these, we make a series of conceptual modifications to the standard quantum mechanics, especially propose a new assumption about the quantum measurement theory which can solve the EPR paradox from the view of the QFT. Besides, a field theoretical description to the double-slit interference experiment is developed, obtaining the required particle number distribution. In the end, we extend all the above concepts to the relativistic case so that the ensemble interpretation is still proper. Two extra topics are added, in the first one, an operable experiment is proposed to distinguish the Copenhagen interpretation from the ensemble one via very different experimental results. While the second topic concerns with the extensions of the concept of coherent state to both the Bosonic and Fermionic field cases, to obtain the corresponding classical fields. And in the concluding section, we make some general comparisons between the standard QM and the one derived from the QFT, from which we claim that the QFT is the fundamental theory.