Recent attempts to establish a space-time description of single-photon emission from single atoms (or molecules) are reviewed. In the wake of historical remarks on the so-called Lorenz zone of molecular influence, characteristics of the power-law confined birth domain of the photon are discussed within the framework of a field-unquantized formalism. In contrast to the common believe it is shown that the birth domain can be (and is) exponentially localized if the photon emerges from a pure spin transition. As a paradigm of exponential localization we discuss the emergence of a radio-frequency photon from the hydrogen hyperfine structure. Starting from the first-quantized description of the energy wave function of a polychromatic photon in vacuo, we introduce a propagator description of the photon embryo, and argue that the single-photon tunnelling process is a fingerprint of our inability to localize photons in space-time. With this understanding optical tunnelling appears as an indispensable part of all single photon-atom scattering processes. In the final part of the review we briefly describe how the formalism can be upgraded from single-photon wave mechanics to a field-quantized description based on wave packet (wave train) electrodynamics. In this new formalism, in which the polychromatic photon embryo is included as an integral part of the polychromatic field quanta, the electrons of the atom (or molecule) move not only in the self-consistent Coulomb potential but also in the transverse potential created by the particles themselves. A rigorous relativistic quantum electrodynamic theory of wave train photon emission from single atoms emerges in the horizon.
Recent attempts to establish a space-time description of single-photon emission from single atoms (or molecules) are reviewed. In the wake of historical remarks on the so-called Lorenz zone of molecular influence, characteristics of the power-law confined birth domain of the photon are discussed within the framework of a field-unquantized formalism. In contrast to the common believe it is shown that the birth domain can be (and is) exponentially localized if the photon emerges from a pure spin transition. As a paradigm of exponential localization we discuss the emergence of a radio-frequency photon from the hydrogen hyperfine structure. Starting from the first-quantized description of the energy wave function of a polychromatic photon in vacuo, we introduce a propagator description of the photon embryo, and argue that the single-photon tunnelling process is a fingerprint of our inability to localize photons in space-time. With this understanding optical tunnelling appears as an indispensable part of all single photon-atom scattering processes. In the final part of the review we briefly describe how the formalism can be upgraded from single-photon wave mechanics to a field-quantized description based on wave packet (wave train) electrodynamics. In this new formalism, in which the polychromatic photon embryo is included as an integral part of the polychromatic field quanta, the electrons of the atom (or molecule) move not only in the self-consistent Coulomb potential but also in the transverse potential created by the particles themselves. A rigorous relativistic quantum electrodynamic theory of wave train photon emission from single atoms emerges in the horizon.
A review is given of the space-time wave mechanics of single photons, a subject with an almost century long history. The Landau-Peierls photon wave function, which is related nonlocally to the electromagnetic field is first described, and thereafter the so-called energy wave function, based on the positive-frequency Riemann-Silberstein vectors, is discussed. Recent attempts to understand the birth process of a photon emerging from a single atom are summarized. The polychromatic photon concept is introduced, and it is indicated how the wave mechanics of polychromatic photons can be upgraded to wave train quantum electrodynamics. A brief description of particle (photon) position operators is given, and it is shown that photons usually are only algebraically confined in an emission process. Finally, it is demonstrated that the profile of the birth domain of a radio-frequency photon emitted in a hyperfine spin transition shows an exponential falloff with the distance from the atomic nucleus. The length parameter in this falloff is the Bohr radius.
It is argued that the photon tunneling process originates in an inability to localize photons completely in space. Seen in this perspective, optical tunneling experiments might allow one to obtain rich information on the photon localizability problem, that until now has been studied mainly theoretically. A rigorous analysis of the electrodynamics in the near-field zone of matter enables us to identify the transverse vector field and subsequently to use it to construct a first-quantized space–time theory for the photon birth process and to determine the source region of the photon. The present theory shows that optical tunneling never appears outside the photon’s source domain, and it is shown that an apparently superluminal response occurs as a consequence of the lack of complete photon localizability. No fundamental velocity is attached to this effect, which stems solely from quantum nonlocality. Starting from the Riemann–Silberstein vectors, which permit the introduction of a space–time description of a free polychromatic photon’s so-called energy wave function, a theoretical investigation of the near-field scattering of a single photon from a mesoscopic or microscopic (molecular, atomic) particle is presented. Inasmuch as the photon tunneling phenomenon appears to be an indispensable part of the near-field scattering process, it might be possible to establish a rigorous first-quantized theory of one-photon tunneling between macroscopic molecular solids by adding the tunneling contributions from the individual molecules.
Starting from the postulate that the electromagnetic field appearing in the transverse set of microscopic Maxwell-Lorentz equations governing field-matter interactions, properly normalized, can be looked upon as describing one-photon-emission and -absorption processes in space and time, a first-quantized initiation of photon emission by a single atom is presented. The wave function for the emerging photon is introduced as a six-vector object constructed from the complex analytical signals of the Riemann-Silberstein vectors belonging to opposite photon helicities. When the atom is no longer electrodynamically active, the emitted photon is described in first quantization by the so-called energy wave function well known for photons in free space. From the momentum representation of the emerging photon wave function a condition on the analytical part of the transverse atomic current density is established which ensures that precisely one photon is emitted. A propagator description of the emerged photon dynamics in the coordinate representation is established. The photon propagator is introduced as a two-component spinor, where upper and lower tensor components are constructed, respectively, from positive and negative helicity combinations of the propagators describing the time-space evolution of the transverse electric and magnetic fields. It is shown that the emission region for the photon coincides with the region in space where the transverse atomic current density is nonvanishing. For a photon emitted in an electric dipole transition the emission region essentially is the near-field zone of the atom, and this zone therefore determines the initial (and best) spatial confinement of the photon. The photon emerging from an atom active for a finite time necessarily is of the polychromatic sort and the associated wave packet essentially is confined between spherical shells moving outwards with the vacuum speed of light. To illustrate the main principles of the fundamental theory in a heuristic fashion we apply it to a study of the emission of a one-photon sinusoidal wavetrain from a pointlike atom. It is found that the atomic current density needed to create just one photon is independent of the oscillation period in the train and thus depends only on the number of periods in the wave train. An explicit expression for the one-photon energy is derived, and it is shown that only for extremely short pulse trains pronounced deviations from the textbook result, $E=\ensuremath{\Elzxh}{\ensuremath{\omega}}_{0},$ occur. The radial energy flow in the coupled atom-photon system in the near-field zone of the atom is investigated, and the cycle-averaged outwards energy transport carried by the emerging photon in a given distance from the atom is determined.
Elements of a new quantum electrodynamic theory which might enable one to obtain a better understanding of the linear and nonlinear interaction between atomic systems in near-field contact is presented. To follow the space-time dynamics in the atomic near-field zone an electromagnetic propagator formalism with polychromatic photons is constructed. A first-quantized description based on the photon energy wave function for free polychromatic photons is extended in such a manner that the birth process of the photon, which takes place in the near-field zone of the source, can be followed. In order to be able to describe harmonic generation processes in near-field optics polychromatic photons of the simple wave-train type are used. The wave mechanical (first-quantized) description based on wave-train photons is upgraded to a field-theoretic (second-quantized) formalism using a new so-called propagator gauge which is closely related to the Poincaré gauge underlying the multipole description of quantum electrodynamics.
A field-quantized electromagnetic propagator description emphasizing the spatial localization of light emitted from a single-electron atom is presented. With the aim of obtaining a better insight into the quantum electrodynamics in the near-field zone of the atom, two approaches, formally different but equivalent in respect to their physical predictions, are studied. From the Maxwell equations, among the transverse operators, a transverse propagator picture in which the source region for the field is identified with the spatial domain occupied by the transverse current density of the atom emerges. In this picture the field propagation is isotropic and always retarded. By identifying the source region with that of the total atomic current, the transverse propagator becomes anisotropic, and attains a nonretarded self-field part and a near-field part different from zero only for spacelike events. By changing the Coulomb Lagrangian, a nonrelativistic Hamiltonian formalism adequate for reconciling the photon concept with the anisotropic propagator picture is introduced. In this formalism the transverse self-field energy is transferred to the particle Hamiltonian, and the interaction Hamiltonian now includes an interaction between the retarded field and the transverse self-field dynamics. The link between the standard (nonpropagator) theory, often used to argue that the total electromagnetic field is always retarded, and the transverse propagator theory is established. The equivalence between the two approaches is proved by demonstrating that the standard theory in fact includes a nonretarded response in the spatial domain occupied by the longitudinal part of the induced atomic current density.
A brief account of the connection between the photon little group and gauge in- variance is given, considering the four-potential as the wave function of the photon. In most textbooks single photons are associated to the quanta of monochromatic plane-wave components of the electromagnetic field. However, polychromatic superposition of such states may also represent single photons. Having established the framework for polychromatic single-photon states in Hilbert space, and upon a discussion of the mean value and variance of the photon Hamilton operator for polychromatic states, we turn our attention to- wards the single-photon description in direct space. A photon wave function in direct space is obtained via the inner product of the photon mean position state (introduced in Chapter 3 ) and the Hilbert space polychromatic single-photon state. Noting that the photon is a relativistic object a rigorous polychromatic photon wave function is, in the continuum superposition of monochromatic plane-wave components, obtained noting the form of the relativistically invari- ant volume element in wave-vector space. We establish a wave-packet basis for single-photon states in Hilbert space, and the related photon wave functions. Thereafter, multi-photon wave packets are discussed, and the equal-time com- mutator relations between the wave packets are discussed, and the equal-time commutator relations between the wave-packet annihilation and creation oper- ators set up. As an example, we focus on two-photon wave packet states. We finish the chapter by a discussion of the two-photon concept and two-photon wave mechanics, analysing in particular the physical difference between two photons and bi-photons (an entangled state of two photons).