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Physica A Statistical Mechanics and its Applications

Master equation vs. partition function: canonical statistics of ideal Bose–Einstein condensates

Martin Holthaus, Kishore T. Kapale, Vitaly V. Kocharovsky, Marlan O. Scully

Published Nov 1, 2001• 26 citations
Publisher
DOI
10.1016/s0378-4371(01)00367-3

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The atom fluctuation statistics of an ideal, mesoscopic, Bose-Einstein condensate are investigated from several different perspectives. By generalizing the grand canonical analysis (applied to the canonical ensemble problem), we obtain a self-consistent equation for the mean condensate particle number that coincides with the microscopic result calculated from the laser master equation approach. For the case of a harmonic trap, we obtain an analytic expression for the condensate particle number that is very accurate at all temperatures, when compared with numerical canonical ensemble results. Applying a similar generalized grand canonical treatment to the variance, we obtain an accurate result only below the critical temperature. Analytic results are found for all higher moments of the fluctuation distribution by employing the stochastic path integral formalism, with excellent accuracy. We further discuss a hybrid treatment, which combines the master equation and stochastic path integral analysis with results obtained based on the canonical ensemble quasiparticle formalism [Kocharovsky et al., Phys. Rev. A 61, 053606 (2000)], producing essentially perfect agreement with numerical simulation at all temperatures.
We open a new discussion of generalized canonical partition function in standard statistical mechanics and apply it for the study of Bose-Einstein condensation. We discuss the possible cases for the generalized canonical partition function and arrives at a conclusion that the system of trapped bose gas will not be existing at absolute zero. We analyse the present study with an experimental result and point out the general difficulties in the analyses of experimental observations, which can possibly suppress the effect of generalized canonical partition function over standard canonical partition function. We mention that the experimental studies with ideal condensates at absolute zero with an unbiased approach towards the traditional Bose-Einstein condensation theory can bring out the effect of generalized canonical partition function.