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Physical Review

Quantum States and Transitions in Weakly Connected Superconducting Rings

Arnold H. Silver, James Edward Zimmerman

Published May 10, 1967• 310 citations
Publisher

Abstract

This paper reports the results of an experimental and phenomenological investigation of the static and dynamic behavior of weakly connected superconducting rings. The configuration is essentially a macroscopic superconducting ring of inductance $L$ incorporating a point contact as a weak link which determines the critical supercurrent in the ring, ${i}_{c}$. A phenomenological model for the stationary quantum states of the system as a function of an applied field is developed. The dynamic behavior is obtained directly from the time dependence of the applied fields. Experiments demonstrating both the stationary and the time-dependent magnetic behavior are described. The stationary behavior was obtained with a magnetometer incorporating a weakly connected ring as a sensor to measure the flux through the ring under test. The experimental results confirm the phenomenological model if the critical curr\`ent ${i}_{c}$ is greater than $\frac{{\ensuremath{\Phi}}_{0}}{2L(1+\ensuremath{\gamma})}$, where ${\ensuremath{\Phi}}_{0}=\frac{h}{2e}$ is the flux quantum and $\ensuremath{\gamma}$ is a material and geometric parameter which is usually small compared to unity. In the regime $L{i}_{c}>\frac{{\ensuremath{\Phi}}_{0}}{2(1+\ensuremath{\gamma})}$, the quantum states are discrete, and the transitions between states are well defined and irreversible. If the critical current is not too large, the transitions generally occur only between adjacent states; that is, $\ensuremath{\Delta}k=\ifmmode\pm\else\textpm\fi{}1$. At large critical current, multiple quantum jumps are observed. On the other hand, if $L{i}_{c}<\frac{{\ensuremath{\Phi}}_{0}}{2(1+\ensuremath{\gamma})}$, the quantum states merge into one another continuously and reversibly. In this case the magnetic behavior inthe neighborhood of the half-quantum points is related to the depairing or gapless regime in superconductivity. Measurements of the ac properties of the weakly connected ring at 30 MHz are interpreted directly in terms of the static properties under the influence of a time-varying applied field. In fact, no qualitative corrections to the theory are expected up to frequencies of the order of the superconducting energy gap.

DOI
10.1103/physrev.157.317

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This paper reports the results of an experimental and phenomenological investigation of the static and dynamic behavior of weakly connected superconducting rings. The configuration is essentially a macroscopic superconducting ring of inductance LLL incorporating a point contact as a weak link which determines the critical supercurrent in the ring, ic{i}_{c}ic​. A phenomenological model for the stationary quantum states of the system as a function of an applied field is developed. The dynamic behavior is obtained directly from the time dependence of the applied fields. Experiments demonstrating both the stationary and the time-dependent magnetic behavior are described. The stationary behavior was obtained with a magnetometer incorporating a weakly connected ring as a sensor to measure the flux through the ring under test. The experimental results confirm the phenomenological model if the critical curr`ent ic{i}_{c}ic​ is greater than \ensuremathΦ02L(1+\ensuremathγ)\frac{{\ensuremath{\Phi}}_{0}}{2L(1+\ensuremath{\gamma})}2L(1+\ensuremathγ)\ensuremathΦ0​​, where \ensuremathΦ0=h2e{\ensuremath{\Phi}}_{0}=\frac{h}{2e}\ensuremathΦ0​=2eh​ is the flux quantum and \ensuremathγ\ensuremath{\gamma}\ensuremathγ is a material and geometric parameter which is usually small compared to unity. In the regime Lic>\ensuremathΦ02(1+\ensuremathγ)L{i}_{c}>\frac{{\ensuremath{\Phi}}_{0}}{2(1+\ensuremath{\gamma})}Lic​>2(1+\ensuremathγ)\ensuremathΦ0​​, the quantum states are discrete, and the transitions between states are well defined and irreversible. If the critical current is not too large, the transitions generally occur only between adjacent states; that is, \ensuremathΔk=\ifmmode±\else\textpm\fi1\ensuremath{\Delta}k=\ifmmode\pm\else\textpm\fi{}1\ensuremathΔk=\ifmmode±\else\textpm\fi1. At large critical current, multiple quantum jumps are observed. On the other hand, if Lic<\ensuremathΦ02(1+\ensuremathγ)L{i}_{c}<\frac{{\ensuremath{\Phi}}_{0}}{2(1+\ensuremath{\gamma})}Lic​<2(1+\ensuremathγ)\ensuremathΦ0​​, the quantum states merge into one another continuously and reversibly. In this case the magnetic behavior inthe neighborhood of the half-quantum points is related to the depairing or gapless regime in superconductivity. Measurements of the ac properties of the weakly connected ring at 30 MHz are interpreted directly in terms of the static properties under the influence of a time-varying applied field. In fact, no qualitative corrections to the theory are expected up to frequencies of the order of the superconducting energy gap.
New experiments demonstrating macroscopic coherence and quantization in partially resistive superconducting rings with point contacts are described. These include: (1) the observation of quantized magnetic transitions for frequencies $\ensuremath{\omega}>{\ensuremath{\omega}}_{1}=\frac{R}{L}$, where RRR is the resistance and LLL the inductance of the ring, and (2) the measurement of coherent oscillations at frequencies limited by thermal noise fluctuations, $\frac{8{k}_{B}\mathrm{TR}}{{{\ensuremath{\Phi}}_{0}}^{2}}$, where kB{k}_{B}kB​ is Boltzmann's constant, TTT the absolute temperature, and ${\ensuremath{\Phi}}_{0}$ the flux quantum. These results are interpreted by introducing into the phenomenological model of weakly connected superconducting rings a continuous time dependence of the quantum states.
We have analyzed the quantum interference effects in the macroscopic “superconducting molecule.” The composite system consists of two massive superconducting rings, each interrupted by a Josephson junction, which are at the same time weakly coupled with one another. The special case of coupling via the Josephson four-terminal junction is considered. The structure of the macroscopic quantum states in an applied magnetic field is calculated. It is shown that, depending on the values of the magnetic fluxes through each ring, the system displays two groups of states, the “orthostates” with both induced currents going in the same direction, and the “parastates” with the opposite currents and with the total induced flux locked to zero value. The transition to the flux locked state with changing of the total applied flux is sudden and is preserved in a certain interval which is determined by the difference of the fluxes applied through each ring. It makes the system sensitive to small gradients of the external magnetic field.
The behavior of a superconducting ring incorporating a point contact, coupled inductively to an oscillatory circuit (hf SQUID), with the rate of change of the magnetic flux in the ring being comparable, to the inverse energy relaxation time of excitations in the superconductor τϵ−1, is examined. For T ∽ Tc the results of the microscopic theory of the nonstationary behavior of point contacts, in which the coupling between the phase difference and the current of the Josephson junction differs from the usual expression I = V/R + Icsinφ in the resistive model, are used. It is shown that the nonequilibrium behavior of a weak link for ω≳τϵ−1 significantly changes the amplitude–frequency and signal characteristics of the SQUID as compared with the case ωτϵ−1≪1, for which the results based on the resistive model are valid. The characteristics of the SQUID in the nonequilibrium situation are sensitive to the ratio between the size of the contact and the mean free path of electrons relative to scattering by impurities.
Multiple and single measurements of quantum states of mesoscopic superconducting loops are carried out in order to investigate a possibility of macroscopic quantum superposition and of creation of a superconductor quantum register. Asymmetric superconducting rings are used in order to be convinced that single measurement gives result corresponding to one of permitted states and multiple one gives an average value on these states. We have measured magnetic dependencies of resistance, rectified voltage and critical current on these rings. The observed quantum oscillations of the resistance and the rectified voltage, corresponding to multiple measurement of quantum states, give evidence of two permitted states at the magnetic flux inside the ring divisible by half of the flux quantum. But the observed quantum oscillations of the critical current, corresponding to single measurement, not only does not confirm these two quantum states, but are in a direct contradiction with the observed oscillations of the resistance. It is assumed that the observed contradiction between the results of measurements made on the same ring can testify to violation of the principle of realism on the mesoscopic level that is a necessary condition for an opportunity of creation of a quantum computer.
The mechanisms of the decay of metastable current states in the superconducting loop of an rf SQUID in the hysteresis state are studied. Clamped point contacts are used as the Josephson weak link. The first derivative of the radio-frequency IVC dVT/dIRF, which gives the dependence of the decay probability density on the amplitude of the oscillations of the magnetic flux in the ring, was measured experimentally. Studies of the temperature dependence of the width of the probability distribution in the interval from 4.2 to 0.5 K show that for most high-resistance Nb–Nb, Nb–Ag–Nb contacts the quantum mechanisms of decay become dominant at a temperature of the order of 2 K. The experimentally measured parameters of the decay probability distribution in the quantum limit are compared with the theoretical values calculated based on the theory of macroscopic quantum tunneling in the limit of strong and weak dissipation. The experimental magnitude of the width of the probability density as well as the characteristic quantum temperature exceed the theoretical values, which can be explained by the deviation of the current-phase dependence of the contact from a sinusoidal dependence. In addition, some contacts apparently correspond to the case of an intermediate magnitude of dissipation. When the frequency of the rf oscillations changed from 30 to 6 MHz, the width of the distribution remained unchanged, which follows from the theory of quantum tunneling decay of the metastable current state in the loop in the limit of strong damping. At low temperatures (T ∼ 50 K) and for a sufficiently small damping coefficient, anomalous peaks were observed in the probability density with an amplitude of the rf oscillations significantly smaller than the critical magnitude of the magnetic flux in the loop.
We present an extensive theoretical analysis of the supercurrent of a superconducting point contact of arbitrary transparency in the presence of a microwave field. Our paper is mainly based on two different approaches: a two-level model that describes the dynamics of the Andreev bound states in these systems and a fully microscopic method based on the Keldysh--Green function technique. This combination provides both a deep insight into the physics of irradiated Josephson junctions and quantitative predictions for arbitrary range of parameters. The main predictions of our analysis are: (i) for weak fields and low temperatures, the microwaves can induce transitions between the Andreev states, leading to a large suppression of the supercurrent at certain values of the phase; (ii) at strong fields, the current-phase relation is strongly distorted and the corresponding critical current does not follow a simple Bessel-function-like behavior; and (iii) at finite temperatures, the microwave field can enhance the critical current by means of transitions connecting the continuum of states outside the gap region and the Andreev states inside the gap. Our paper is of relevance for a large variety of superconducting weak links as well as for the proposals of using the Andreev bound states of a point contact for quantum computing applications.