Pseudopure states of a system of twelve interacting spins are experimentally demonstrated. The system is a cluster of dipolar-coupled nuclear spins of fully labeled (13)C(6)-benzene in a liquid crystalline matrix. At present, this is the largest and the most complex composite system where individual quantum states have been addressed.
It is experimentally demonstrated that an arbitrary quantum state of a single spin 1/2, a| upward arrow+b| downward arrow, can be converted into a superposition of the two ferromagnetic states of a spin cluster: a| upward arrow upward arrow... upward arrow upward arrow+b| downward arrow downward arrow... downward arrow downward arrow. The physical system is a cluster of seven dipolar-coupled nuclear spins of single-labeled 13C-benzene molecules in a liquid-crystalline matrix. In this complex system, the pseudopure ground state and the required controlled unitary transformations have been implemented. The experimental scheme can be considered as an explicit model of quantum measurement.
We investigate numerically the multiple quantum (MQ) NMR dynamics in systems of nuclear spins 1/2 coupled by dipole-dipole interactions in the case of the pseudopure initial state. Simulations of the MQ NMR with real molecular structures such as six dipolar-coupled proton spins of benzene, hydroxyl proton chains in calcium hydroxyapatite, and fluorine chains in calcium fluorapatite open the way to experimental NMR testing of the obtained results. It was found that multiple-spin correlations are created faster in such experiments than in the usual MQ NMR experiments and can be used for the investigation of many-spin dynamics of nuclear spins in solids.