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Zeitschrift für Naturforschung A

Equilibrium States and Phase Transitions of some FCC-Multi-Lattice Systems

H.-J. Volkert, Alfred Rieckers

Published Jul 1, 1991• 5 citations
Publisher

Abstract

The general formalism which connects quantum statistical and thermodynamical phase structures, developed previously, is applied here to a class of FCC-multi-lattice systems with four sublattices. A careful treatment of the symmetries gives insights into the origins of the rich phase structure. Arguments for the existence of the limiting Gibbs states are provided. A microscopic foundation of the Landau scenario for phase transitions, which predicts the active directions and the order parameters, is formulated for the considered models.

DOI
10.1515/zna-1991-0701

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The general formalism which connects quantum statistical and thermodynamical phase structures, developed previously, is applied here to a class of FCC-multi-lattice systems with four sublattices. A careful treatment of the symmetries gives insights into the origins of the rich phase structure. Arguments for the existence of the limiting Gibbs states are provided. A microscopic foundation of the Landau scenario for phase transitions, which predicts the active directions and the order parameters, is formulated for the considered models.
The general structure of thermodynamic equilibrium states for a class of quantum mechanical (multi-lattice) systems is elaborated, combining quantum statistical and thermodynamical methods. The quantum statistical formulation is performed in terms of recent operator algebraic concepts emphasizing the role of the permutation symmetry due to homogeneous coarse graining and employing the internal symmetries. The variational principle of the free energy functional is derived, which determines together with the symmetries the general form of the limiting Gibbs states in terms of their central decomposition. The limiting minimal free energy density and its possible equilibrium states are analyzed on various levels of the description by means of convex analysis, where the Fenchel transforms of the free energies provide entropy like potentials. On the thermodynamic level a modified entropy surface is obtained, which specifies only in combination with its concave envelope the regions of pure and mixed phase states. The symmetry properties of a certain model allow to specify the (non-) differentiability of the minimal free energy density. A characterization and classification of phase transitions in terms of quantum statistical equilibrium states is proposed, and the connection to the Landau theory is established demonstrating that the latter implies a (continuous) deformation of the sets of equilibrium states along a canonically given curve.
Abstract The quantum statistical frame for infinite multi-lattice spin systems is introduced. The thermodynamic functionals specific internal energy, entropy and free energy are shown to exist on the set of permutation invariant states for polynomial mean field interactions by direct estimation methods. Their dependence on the relative sizes of the sublattice systems is made explicit. The set of homogeneous minimal free energy states is shown to be a Bauer simplex which contains all limiting Gibbs states. For the extremal minimal free energy states the self-consistency equations are derived.
We extend the analysis of the class of quantum phase transitions (QPTs) that can be interpreted as condensations in state space, first introduced in [M. Ostilli and C. Presilla, J. Phys. A 54, 055005 (2021)], by generalizing the arguments of [M. Ostilli and C. Presilla, Phys. Rev. Lett. 127, 040601 (2021)] to prove the existence and determine the location (via simple bounds) of QPTs in general one-parameter lattice Hamiltonians. Unlike our original formulation, this extension also encompasses second-order QPTs, for which we provide the explicit example of the transverse-field Ising model. Our analysis suggests that, under conditions typically satisfied in physical contexts, any QPT taking place in lattice systems can be interpreted as a condensation in state space.
The chapter is an introduction to basic equilibrium aspects of phase transitions. It starts by reviewing thermodynamics and the thermodynamic description of phase transitions. Next, lattice models, such as the paradigmatic Ising model, are introduced as simple physical models that permit a mechano-statistical study of phase transitions from a more microscopic point of view. It is shown that the Ising model can quite faithfully describe many different systems after suitable interpretation of the lattice variables. Special emphasis is placed on the mean-field concept and the mean-field approximations. The deformable Ising model is then studied as an example that illustrates the interplay of different degrees of freedom. Subsequently, the Landau theory of phase transitions is introduced for continuous and first-order transitions, as well as critical and tricritical behaviour are analysed. Finally, scaling theories and the notion of universality within the framework of the renormalization group are briefly discussed.
Abstract The microscopic dynamics for a class of long range interacting multi-lattice quantum systems is constructed in the thermodynamical limit by means of operator algebraic concepts. By direct estimations the existence of the limiting Schrödinger dynamics is proven for a set of states, which comprises also globally non-equilibrium situations. The expectation values of the classical observables in the pure phase states are shown to satisfy a set of coupled non-linear differential equations. The limiting Heisenberg dynamics is derived as a W*-automorphism group in the partially universal von Neumann algebra which corresponds to the selected set of states; it is in general, however, not σ-weakly continuous in the time parameter.
Matter exists in many different phases, for example in solid state or in liquid phase. There are also phases in which the ordering of atoms is the same, but which differ in some other respect, for example ferromagnetic and paramagnetic states. According to Landau's symmetry breaking theory every phase transition is connected to a symmetry breaking process. A solid material has discrete translational symmetry, while liquid phase has continuous translational symmetry. But it has turned out that there also exist phase transitions that can occur without a symmetry breaking. This phenomenon is called topological order. In this thesis we consider one example of a theoretical model constructed on a two dimensional lattice in which one obtains topological order.