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Physical Review A

Observability of quaternionic quantum mechanics

A. J. Davies, Bruce H. J. McKellar

Published Oct 1, 1992• 83 citations
Publisher

Abstract

Beginning with the quaternionic generalization of the Schr\"odinger equation, we present a simple system consisting of two successive square barriers of general (quaternionic) height, and discuss situations in which the predictions of quaternionic quantum mechanics differ from those of the usual complex theory. Specifically, we show that the transmission coefficient may pick up a phase change on reversal of the barrier order. We comment on why this phase change would not necessarily be observed in experiments. Finally, we present a necessary condition for the magnitude of the transmission coefficient to change under reversal of the direction of traversal of the barrier.

DOI
10.1103/physreva.46.3671

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In principle, the lattice of elementary propositions of a generic quantum system admits a representation in real, complex or quaternionic Hilbert spaces as established by Solèr’s theorem (1995) closing a long standing problem that can be traced back to von Neumann’s mathematical formulation of quantum mechanics. However up to now there are no examples of quantum systems described in Hilbert spaces whose scalar field is different from the set of complex numbers. We show that elementary relativistic systems cannot be described by irreducible strongly-continuous unitary representations of SL(2, C) on real or quaternionic Hilbert spaces as a consequence of some peculiarity of the generators related with the theory of polar decomposition of operators. Indeed such a ”naive” attempt leads necessarily to an equivalent formulation on a complex Hilbert space. Although this conclusion seems to give a definitive answer to the real/quaternionic-quantum-mechanics issue, it lacks consistency since it does not derive from more general physical hypotheses as the complex one does. Trying a more solid approach, in both situations we end up with three possibilities: an equivalent description in terms of a Wigner unitary representation in a real, complex or quaternionic Hilbert space. At this point the ”naive” result turns out to be a definitely important technical lemma, for it forbids the two extreme possibilities. \nIn conclusion, the real/quaternionic theory is actually complex. This improved approach is based upon the concept of von Neumann algebra of observables. Unfortunately, while \nthere exists a thorough literature about these algebras on real and complex Hilbert spaces, an analysis on the notion of von Neumann algebra over a quaternionic Hilbert space is \ncompletely absent to our knowledge. There are several issues in trying to define such a mathematical object, first of all the inability to construct linear combination of operators \nwith quaternionic coeffients. Restricting ourselves to unital real *-algebras of operators we are able to prove the von Neumann Double Commutant Theorem also on quaternionc \nHilbert spaces. Clearly, this property turns out to be crucial.

•Jan 1, 2018•1 citation
Beginning with the quaternionic generalization of the Schr"odinger equation, we present a simple system consisting of two successive square barriers of general (quaternionic) height, and discuss situations in which the predictions of quaternionic quantum mechanics differ from those of the usual complex theory. Specifically, we show that the transmission coefficient may pick up a phase change on reversal of the barrier order. We comment on why this phase change would not necessarily be observed in experiments. Finally, we present a necessary condition for the magnitude of the transmission coefficient to change under reversal of the direction of traversal of the barrier.
In this paper, we analyze, by using a matrix approach, the dynamics of a nonrelativistic particle in presence of a quaternionic potential barrier. The matrix method used to solve the quaternionic Schrödinger equation allows us to obtain a closed formula for the transmission coefficient. Up to now, in quaternionic quantum mechanics, almost every discussion on the dynamics of nonrelativistic particle was motivated by or evolved from numerical studies. A closed formula for the transmission coefficient stimulates an analysis of qualitative differences between complex and quaternionic quantum mechanics and by using the stationary phase method, gives the possibility to discuss transmission times.
A new kind of quantum mechanics using inner products, matrix elements, and coefficients assuming values that are quaternionic (and thus noncommutative) instead of complex is developed. This is the most general kind of quantum mechanics possessing the same kind of calculus of assertions as conventional quantum mechanics. The role played by the new imaginaries is studied. The principal conceptual difficulty concerns the theory of composite systems where the ordinary tensor product fails due to noncommutativity. It is shown that the natural resolution of this difficulty introduces new degrees of freedom similar to isospin and hypercharge. The problem of the Schrödinger equation, ``which i should appear?'' is studied and a generalization of Stone's theorem is used to resolve this problem.
By using the recent mathematical tools developed in quaternionic differential operator theory, we solve the Schrödinger equation in the presence of a quaternionic step potential. The analytic solution for the stationary states allows one to explicitly show the qualitative and quantitative differences between this quaternionic quantum dynamical system and its complex counterpart. A brief discussion on reflected and transmitted times, performed by using the stationary phase method, and its implication on the experimental evidence for deviations of standard quantum mechanics is also presented. The analytic solution given in this paper represents a fundamental mathematical tool to find an analytic approximation to the quaternionic barrier problem (up to now solved by numerical method).
Abstract We revisit the formulation of quantum mechanics over the quaternions and investigate the dynamical structure within this framework. Similar to standard complex quantum mechanics, time evolution is then mediated by a unitary operator which can be written as the exponential of the generator of time shifts. By imposing physical assumptions on the correspondence between the energy observable and the generator of time shifts, we prove that quaternionic quantum theory admits a time evolution only for systems with a quaternionic dimension of at most two. Applying the same strategy to standard complex quantum theory, we reproduce that the correspondence dictated by the Schrödinger equation is the only possible choice, up to a shift of the global phase.
In principle, the lattice of elementary propositions of a generic quantum system admits a representation in real, complex or quaternionic Hilbert spaces as established by Solèr’s theorem (1995) closing a long standing problem that can be traced back to von Neumann’s mathematical formulation of quantum mechanics. However up to now there are no examples of quantum systems described in Hilbert spaces whose scalar field is different from the set of complex numbers. We show that elementary relativistic systems cannot be described by irreducible strongly-continuous unitary representations of SL(2, C) on real or quaternionic Hilbert spaces as a consequence of some peculiarity of the generators related with the theory of polar decomposition of operators. Indeed such a ”naive” attempt leads necessarily to an equivalent formulation on a complex Hilbert space. Although this conclusion seems to give a definitive answer to the real/quaternionic-quantum-mechanics issue, it lacks consistency since it does not derive from more general physical hypotheses as the complex one does. Trying a more solid approach, in both situations we end up with three possibilities: an equivalent description in terms of a Wigner unitary representation in a real, complex or quaternionic Hilbert space. At this point the ”naive” result turns out to be a definitely important technical lemma, for it forbids the two extreme possibilities. \nIn conclusion, the real/quaternionic theory is actually complex. This improved approach is based upon the concept of von Neumann algebra of observables. Unfortunately, while \nthere exists a thorough literature about these algebras on real and complex Hilbert spaces, an analysis on the notion of von Neumann algebra over a quaternionic Hilbert space is \ncompletely absent to our knowledge. There are several issues in trying to define such a mathematical object, first of all the inability to construct linear combination of operators \nwith quaternionic coeffients. Restricting ourselves to unital real *-algebras of operators we are able to prove the von Neumann Double Commutant Theorem also on quaternionc \nHilbert spaces. Clearly, this property turns out to be crucial.