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Physical Review

Chemical Potential and Low-Lying Excitation in the Many-Body Bose System

K. Sawada, Ludwig W. Bruch

Published Aug 1, 1963• 2 citations
Publisher

Abstract

For a Bose system interacting through a two-body potential there is a large occupation number in the zero-momentum state with small fluctuations. Thus, we can express the chemical potential and low-lying excitation energy in terms of the density fluctuation only. The formulas derived are shown to coincide with well-established results in the low-density Bose gas. The use of experimental neutron scattering data is suggested to improve the numerical answer. A particular application is made to the ${\mathrm{He}}^{4}$ case. If we utilize the Feynman variational excited state as the (approximate) true state vector, which is correct experimentally for low-momentum excitations, we get an explicit phonon excitation for actual ${\mathrm{He}}^{4}$.

DOI
10.1103/physrev.131.1379

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Chemical Potential and Low-Lying Excitations in the Many-Boson System. II

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The approximate description of a many-boson system by its density fluctuations is considered. The representation of the chemical potential by a scattering matrix is compared with an exact solution in one dimension. It is found to be valid exactly in the low coupling limit and valid to within 10% for intermediate coupling strengths. In the case treated, the ground-state properties are given quite accurately for intermediate coupling strengths. The excitation spectrum is described less accurately. The velocity of sound obtained from the slope of the phonon spectrum is formally different from that obtained using the compressibility. Here, the sound velocities obtained from the two methods are found to agree numerically. Data for actual ${\mathrm{He}}^{4}$ and a simple linear approximation to the density dependence of the scattering matrix are used. The sound velocity obtained is in rough agreement with the experimentally observed velocity in liquid ${\mathrm{He}}^{4}$.

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Low-density expansions for the homogeneous dipolar Bose gas at zero temperature

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The low-density expansions for the energy, chemical potential, and condensate depletion of the homogeneous dilute dipolar Bose gas are obtained by regularizing the dipole-dipole interaction at long distances. It is shown that the leading term, proportional to the density, allows a simple physical interpretation and consistently describes the thermodynamic stability of the system. The long-range asymptotics are obtained analytically for the normal and anomalous one-particle correlation functions and the pair distribution function. We discuss the properties of the two-body scattering with zero relative momentum for the dipole-dipole interaction; in particular, we derive the asymptotics of the wave function and a correction to the scattering length for small values of the dipolar range. We show how the density expansions can be derived within the Bogoliubov model of weakly interacting particles without any divergence from the assumption of universality of the expansions at low densities.

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Bose-Einstein Gas with Repulsive Interactions: General Theory

K. A. Brueckner, K. Sawada

The properties of a Bose-Einstein gas with repulsive interparticle interactions are determined at low temperature. It is shown that the contribution to the energy arising from particle excitation with small momentum transfers computed in conventional perturbation theory is divergent, but that this difficulty can be avoided by an alternative procedure. An exact method is developed for dealing with that part of the Hamiltonian which gives rise to the perturbation divergence and an exact solution is obtained. The treatment of the region of large momentum transfers is then carried out by introducing the concept of the scattering length of the interaction. The energy is given by the well-known result of the optical theorem corrected by a series in powers of ${(\ensuremath{\rho}{a}^{3})}^{\frac{1}{2}}$, where $\ensuremath{\rho}$ is the density and $a$ the scattering length. Examination of the processes contributing to the energy shows that 95.8% of the correction of order ${(\ensuremath{\rho}{a}^{3})}^{\frac{1}{2}}$ results from a simple alteration of the perturbation energy denominators which takes into account the interaction energy of excited pairs with the unexcited pairs of the medium. The remaining 4.2% arises from multiple particle excitation. These methods also predict the existence of phonon excitation with phonon energies that are linear in the phonon momentum for small excitation and approach $\frac{{q}^{2}}{2M}$ for large momentum. The detailed consideration of this spectrum forms part of the following paper.The results are compared with the theory of fermion systems with strong interactions, where again the largest correction to the first-order "optical" energy arises from alteration of the two-particle propagator which is required to take into account interactions with the many unexcited particles of the medium. The propagator corrections in the fermion and boson systems are similar except for a characteristic difference arising from the statistics. The theory for bosons is shown to be essentially identical with that given by Brueckner and Levinson in their general formulation of the theory of many-body systems with strong interactions.Systems with attractive but saturating interactions are also considered and some new difficulties are shown to arise which cannot be treated by a straightforward application of the methods of this paper.

Physical Review•Jun 15, 1957•225 citations
For a Bose system interacting through a two-body potential there is a large occupation number in the zero-momentum state with small fluctuations. Thus, we can express the chemical potential and low-lying excitation energy in terms of the density fluctuation only. The formulas derived are shown to coincide with well-established results in the low-density Bose gas. The use of experimental neutron scattering data is suggested to improve the numerical answer. A particular application is made to the He4{\mathrm{He}}^{4}He4 case. If we utilize the Feynman variational excited state as the (approximate) true state vector, which is correct experimentally for low-momentum excitations, we get an explicit phonon excitation for actual He4{\mathrm{He}}^{4}He4.
The approximate description of a many-boson system by its density fluctuations is considered. The representation of the chemical potential by a scattering matrix is compared with an exact solution in one dimension. It is found to be valid exactly in the low coupling limit and valid to within 10% for intermediate coupling strengths. In the case treated, the ground-state properties are given quite accurately for intermediate coupling strengths. The excitation spectrum is described less accurately. The velocity of sound obtained from the slope of the phonon spectrum is formally different from that obtained using the compressibility. Here, the sound velocities obtained from the two methods are found to agree numerically. Data for actual He4{\mathrm{He}}^{4}He4 and a simple linear approximation to the density dependence of the scattering matrix are used. The sound velocity obtained is in rough agreement with the experimentally observed velocity in liquid He4{\mathrm{He}}^{4}He4.
Now that the low temperature properties of quantum-mechanical many-body systems (bosons) at low density, ρρρ, can be examined experimentally it is appropriate to revisit some of the formulas deduced by many authors 4-5 decades ago. For systems with repulsive (i.e. positive) interaction potentials the experimental low temperature state and the ground state are effectively synonymous -- and this fact is used in all modeling. In such cases, the leading term in the energy/particle is 2πℏ2aρ/m2π\hbar^2 a ρ/m2πℏ2aρ/m where aaa is the scattering length of the two-body potential. Owing to the delicate and peculiar nature of bosonic correlations (such as the strange N7/5N^{7/5}N7/5 law for charged bosons), four decades of research failed to establish this plausible formula rigorously. The only previous lower bound for the energy was found by Dyson in 1957, but it was 14 times too small. The correct asymptotic formula has recently been obtained by us and this work will be presented. The reason behind the mathematical difficulties will be emphasized. A different formula, postulated as late as 1971 by Schick, holds in two-dimensions and this, too, will be shown to be correct. With the aid of the methodology developed to prove the lower bound for the homogeneous gas, two other problems have been successfully addressed. One is the proof by us that the Gross-Pitaevskii equation correctly describes the ground state in the `traps' actually used in the experiments. For this system it is also possible to prove complete Bose condensation, as we have shown. Another topic is a proof that Foldy's 1961 theory of a high density Bose gas of charged particles correctly describes its ground state energy.
This paper is concerned with the application of sum rules satisfied by the density correlation function to the calculation of properties of the interacting Bose system, particularly liquid He4{\mathrm{He}}^{4}He4 and the hard-core gas. In addition to the two well-known sum rules which have been extensively discussed in the literature, we derive a third useful relation which directly involves the two-body interaction. The assumption that a single excitation exhausts all the sum rules (which is known to lead to the Feynman theory when only the first two sum rules are used) now provides, with the help of the additional sum rule, an explicit integral equation for the liquid structure factor S(k)S(k)S(k). This equation can be solved quite easily for the hard-core gas, and we find the low-lying excitation spectrum to have the form ${{\ensuremath{\omega}}_{\mathrm{hc}}}^{2}(k)={k}^{2}{{v}_{T}}^{2}+{\left(\frac{{k}^{2}}{2m}\right)}^{2}+4\left(\frac{{k}^{2}}{2m}\right)\left[\left(\frac{P}{\ensuremath{\rho}}\ensuremath{-}\frac{2}{3}\frac{〈\mathrm{KE}〉}{〈N〉}\right)({\mathcal{P}}_{1}(\mathrm{ka})\ensuremath{-}{\mathcal{P}}_{1}(0))+\left(m{{v}_{T}}^{2}\ensuremath{-}\frac{2P}{\ensuremath{\rho}}\ensuremath{-}\frac{2}{3}\frac{〈\mathrm{KE}〉}{〈N〉}\right)({\mathcal{P}}_{2}(\mathrm{ka})\ensuremath{-}{\mathcal{P}}_{2}(0))\right],$ where vT{v}_{T}vT​, PPP, 〈KE〉〈N〉\frac{〈\mathrm{KE}〉}{〈N〉}〈N〉〈KE〉​ and aaa are, respectively, the sound velocity, pressure, kinetic energy per particle, and core diameter. P1{\mathcal{P}}_{1}P1​ and P2{\mathcal{P}}_{2}P2​ are sinusoidal functions given in the text. Although the sum rules themselves are exact, there are several difficulties associated with the use, even in the low-kkk limit, of the sharp resonance assumption in all such integral relations. In spite of these difficulties, which are discussed briefly, we have pursued the consequences of the sharp-resonance approximation to obtain an integral equation for the liquid structure factor S(k)S(k)S(k) together with the above closed-form solution for the hard-core gas excitation spectrum. The speculation that the approximation becomes essentially exact in the low-kkk limit provides, through the third sum rule, an expression for the sound velocity in terms of the two-body potential v(r)v(r)v(r) and the radial distribution function S(r)S(r)S(r). We apply this relation to the case of liquid He4{\mathrm{He}}^{4}He4 and discuss extensions of the single-resonance approximation which can be made with the help of the third sum rule.
We explore the zero-temperature behavior of an assembly of bosons interacting through a zero-range, attractive potential.Because the twobody interaction admits a bound state, the many-body model is best described by a Hamiltonian that includes the coupling between atomic and molecular components.Due to the positive scattering length, the low-density collection is expected to remain stable against collapse despite the attraction between particles.Although a variational many-body analysis indicates a collapsing solution with only a molecular component to its condensate at low density, the expected atomic condensate solution can be obtained if the chemical potential is allowed to be complex valued.In addition to revealing two discrete eigenfrequencies associated with the molecular case, an expansion in small oscillations quantifies the imaginary part of the chemical potential as proportional to a coherent decay rate of the atomic condensate into a continuum of collective phonon excitations about the collapsing lower state.
The low-density expansions for the energy, chemical potential, and condensate depletion of the homogeneous dilute dipolar Bose gas are obtained by regularizing the dipole-dipole interaction at long distances. It is shown that the leading term, proportional to the density, allows a simple physical interpretation and consistently describes the thermodynamic stability of the system. The long-range asymptotics are obtained analytically for the normal and anomalous one-particle correlation functions and the pair distribution function. We discuss the properties of the two-body scattering with zero relative momentum for the dipole-dipole interaction; in particular, we derive the asymptotics of the wave function and a correction to the scattering length for small values of the dipolar range. We show how the density expansions can be derived within the Bogoliubov model of weakly interacting particles without any divergence from the assumption of universality of the expansions at low densities.
The properties of a Bose-Einstein gas with repulsive interparticle interactions are determined at low temperature. It is shown that the contribution to the energy arising from particle excitation with small momentum transfers computed in conventional perturbation theory is divergent, but that this difficulty can be avoided by an alternative procedure. An exact method is developed for dealing with that part of the Hamiltonian which gives rise to the perturbation divergence and an exact solution is obtained. The treatment of the region of large momentum transfers is then carried out by introducing the concept of the scattering length of the interaction. The energy is given by the well-known result of the optical theorem corrected by a series in powers of ${(\ensuremath{\rho}{a}^{3})}^{\frac{1}{2}}$, where $\ensuremath{\rho}$ is the density and aaa the scattering length. Examination of the processes contributing to the energy shows that 95.8% of the correction of order ${(\ensuremath{\rho}{a}^{3})}^{\frac{1}{2}}$ results from a simple alteration of the perturbation energy denominators which takes into account the interaction energy of excited pairs with the unexcited pairs of the medium. The remaining 4.2% arises from multiple particle excitation. These methods also predict the existence of phonon excitation with phonon energies that are linear in the phonon momentum for small excitation and approach q22M\frac{{q}^{2}}{2M}2Mq2​ for large momentum. The detailed consideration of this spectrum forms part of the following paper.The results are compared with the theory of fermion systems with strong interactions, where again the largest correction to the first-order "optical" energy arises from alteration of the two-particle propagator which is required to take into account interactions with the many unexcited particles of the medium. The propagator corrections in the fermion and boson systems are similar except for a characteristic difference arising from the statistics. The theory for bosons is shown to be essentially identical with that given by Brueckner and Levinson in their general formulation of the theory of many-body systems with strong interactions.Systems with attractive but saturating interactions are also considered and some new difficulties are shown to arise which cannot be treated by a straightforward application of the methods of this paper.