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Journal of Mathematical Physics

Polylogarithmic analysis of chemical potential and fluctuations in a D-dimensional free Fermi gas at low temperatures

M. Howard Lee

Published Mar 1, 1995• 52 citations
Publisher

Abstract

The chemical potential and fluctuations in number of particles in a D-dimensional free Fermi gas at low temperatures are obtained by means of polylogarithms. This idea is extended to show that the density of any ideal gas, whether Fermi, Bose, or classical, can be expressed in polylogarithms. The densities of different statistics correspond to different domains of polylogarithms in such a way that there emerges a unifying picture. The density of the classical ideal gas represents a fixed point of polylogarithms. Inequalities for polylogarithms are used to provide a precise bound on errors in the fermion chemical potential at low temperatures.

DOI
10.1063/1.531116

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The chemical potential and fluctuations in number of particles in a D-dimensional free Fermi gas at low temperatures are obtained by means of polylogarithms. This idea is extended to show that the density of any ideal gas, whether Fermi, Bose, or classical, can be expressed in polylogarithms. The densities of different statistics correspond to different domains of polylogarithms in such a way that there emerges a unifying picture. The density of the classical ideal gas represents a fixed point of polylogarithms. Inequalities for polylogarithms are used to provide a precise bound on errors in the fermion chemical potential at low temperatures.
Calculations of chemical potentials for ideal monatomic gases with Bose-Einstein and Fermi-Dirac statistics as functions of temperature, across the temperature region that is typical for the collective quantum degeneracy effect, are presented. Numerical calculations are performed without any additional approximations, and explicit dependences of the chemical potentials on temperature are constructed at a fixed density of gas particles. Approximate polynomial dependences of chemical potentials on temperature are obtained that allow for the results to be used in further studies without re-applying the involved numerical methods. The ease of using the obtained representations is demonstrated on examples of deformation of distribution for a population of energy states at low temperatures, and on the impact of quantum statistics (exchange interaction) on the equations of state for ideal gases and some of the thermodynamic properties thereof. The results of this study essentially unify two opposite limiting cases in an intermediate region that are used to describe the equilibrium states of ideal gases, which are well known from university courses on statistical physics, thus adding value from an educational point of view.
The chemical potential of a D-dimensional free Fermi gas at low temperatures has been obtained using some ideas due to Barker and Blankenbechler [J. Math. Phys. 97, 302 (1986); Am. J. Phys. 25, 279 (1957)]. There is an interesting even–odd-dimensional effect in the behavior of the chemical potential, also observed in other properties of a free Fermi gas, such as the susceptibility. For D=2, it is possible to give a closed form expression, thus valid both in the high- and low-temperature regions, probably not possible in any other even or odd dimensions.
Abstract Knowledge of the chemical potential is essential in application of the Fermi–Dirac and the Bose–Einstein distribution functions for the calculation of properties of quantum gases. We give expressions for the chemical potential of ideal Fermi and Bose gases in 1, 2 and 3 dimensions in terms of inverse polylogarithm functions. We provide Mathematica functions for these chemical potentials together with low- and high-temperature series expansions. In the 3d Bose case we give also expansions about TBT_{{{{\mathrm {B}}}}}TB​ T B . The Mathematica routines for the series allow calculation to arbitrary order.
The effects of low dimensionality on the thermodynamics of a Fermi gas trapped by isotropic power-law potentials are analyzed. Particular attention is given to different characteristic temperatures that emerge, at low dimensionality, in the thermodynamic functions of state and in the thermodynamic susceptibilities (isothermal compressibility and specific heat). An energy-entropy argument that physically favors the relevance of one of these characteristic temperatures, namely, the nonvanishing temperature at which the chemical potential reaches the Fermi energy value, is presented. Such an argument allows interpreting the nonmonotonic dependence of the chemical potential on temperature, as an indicator of the appearance of a thermodynamic regime, where the equilibrium states of a trapped Fermi gas are characterized by larger fluctuations in energy and particle density as is revealed in the corresponding thermodynamics susceptibilities.
In this paper, the chemical potential of two-dimensional (2D) and quasi-one-dimensional (Q1D) multisubband charged Fermi gases is evaluated. We start with a rather general formula for the thermodynamic potential of an ideal quantum statistical system with arbitrary occupation-number to calculate, as a particular case, the chemical potential of the multisubband 2D Fermi gas described by a quadratic energy spectrum. The chemical potential is also studied in the case of a low-dimensional Fermi gas in the presence of a quantizing magnetic field. The same approach is used to study the chemical potential of a multisubband Q1D Fermi gas. The influence of temperature is considered. We found interesting analytical results for special limits as well as numerical results that may be important for the description of both the thermodynamic and kinetic properties of Fermi systems in low dimensionality.
The properties of an ideal Fermi gas in an external potential in any dimensional space are studied, based on the semiclassical (Thomas-Fermi) approximation. The general analytical expressions of the total particle number N,N,N, density of states $D(\ensuremath{\varepsilon}),$ Fermi energy EF,{E}_{F},EF​, total energy E,E,E, and heat capacity CCC have been derived, where N,N,N, E,E,E, and CCC are expressed by the Fermi integration. Moreover, the analytical expressions of the total energy E,E,E, chemical potential \ensuremath{\mu}, and heat capacity CCC in the high- and low-temperature approximations are given. From these results, how the characteristics of the Fermi gas depend on an external potential and the dimension of space is discussed.