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Europhysics Letters (EPL)

Green function hierarchy for open shells

Christian Brouder

Published Jul 26, 2005• 7 citations
Publisher

Abstract

In many systems containing open shell ions, the wave function of the ions cannot be described by a single Slater determinant. This invalidates standard many-body theory and requires the use of nonequilibrium quantum field theory with initial correlations. Quantum group techniques are used here to deal with this combinatorially complex theory. The hierarchy of interacting Green functions for general initial correlations is derived and the case of a system with two-particle correlations is treated in detail.

DOI
10.1209/epl/i2005-10134-y

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In many systems containing open shell ions, the wave function of the ions cannot be described by a single Slater determinant. This invalidates standard many-body theory and requires the use of nonequilibrium quantum field theory with initial correlations. Quantum group techniques are used here to deal with this combinatorially complex theory. The hierarchy of interacting Green functions for general initial correlations is derived and the case of a system with two-particle correlations is treated in detail.
\n \nIn many systems containing open shell ions, the wave function of\nthe ions cannot be described by a single Slater determinant. This\ninvalidates standard many-body theory and requires the use of\nnonequilibrium quantum field theory with initial correlations.\nQuantum group techniques are used here to deal with this\ncombinatorially complex theory. The hierarchy of interacting\nGreen functions for general initial correlations is derived and\nthe case of a system with two-particle correlations is treated in\ndetail.\n\n
The many-body theory of degenerate systems is described in detail. More generally, this theory applies to systems with an initial state that cannot be described by a single Slater determinant. The double-source (or closed-time-path) formalism of nonequilibrium quantum field theory is used to derive an expression for the average value of a product of interacting fields when the initial state is not the vacuum or a Slater determinant. Quantum group techniques are applied to derive the hierarchy of unconnected Green functions and the hierarchy of connected ones.
In quantum field theory the Green function is usually calculated as the expectation value of the time-ordered product of fields over the vacuum. In some cases, especially in degenerate systems, expectation values over general states are required. The corresponding Green functions are essentially more complex than in the vacuum, because they cannot be written in terms of standard Feynman diagrams. Here a method is proposed to determine the structure of these Green functions and to derive nonperturbative equations for them. The main idea is to transform the cumulants describing correlations into interaction terms.
Abstract The method of the equation of motion is used to derive the Martin–Schwinger hierarchy for the nonequilibrium Green’s functions. The formal closure of the hierarchy is reached by using the selfenergy which provides a recipe for how to construct selfenergies from approximations of the two-particle Green’s function. The Langreth–Wilkins rules for a diagrammatic technique are shown to be equivalent to the weakening of initial correlations. The quantum transport equations are derived in the general form of Kadanoff and Baym equations. The information contained in the Green’s function is discussed. In equilibrium this leads to the Matsubara diagrammatic technique.