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Journal of Physics A Mathematical and General

One integral in three ways: moments of a quantum distribution

Mark W. Coffey

Published Jan 24, 2006• 6 citations
Publisher

Abstract

Very recently, an exponential probability distribution with parameter has been used to calculate the decoherence factors for quantum states. We derive all moments of this distribution systematically in three different ways, presenting the results in terms of binomial coefficients or Pochhammer symbols, and Stirling numbers of the first and second kinds. We show how generalized harmonic numbers or polygamma functions provide another representation for the moments. Extensions of the approach are briefly mentioned.

DOI
10.1088/0305-4470/39/6/015

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Very recently, an exponential probability distribution with parameter has been used to calculate the decoherence factors for quantum states. We derive all moments of this distribution systematically in three different ways, presenting the results in terms of binomial coefficients or Pochhammer symbols, and Stirling numbers of the first and second kinds. We show how generalized harmonic numbers or polygamma functions provide another representation for the moments. Extensions of the approach are briefly mentioned.
A particular case of degenerate Clebsch-Gordan coefficient can be expressed with three binomial coefficients. Such a formula, which may be obtained using the standard ladder operator procedure, can also be derived from the Racah-Shimpuku formula or from expressions of Clebsch-Gordan coefficients in terms of 3F2_3F_23​F2​ hypergeometric functions. The O'Hara interesting interpretation of this Clebsch-Gordan coefficient by binomial random variables can also be related to hypergeometric functions (2F1_2F_12​F1​), in the case where one of the parameters tends to infinity. This emphasizes the links between Clebsch-Gordan coefficients, hypergeometric functions and, what has been less exploited until now, the notion of probability within the framework of the quantum theory of angular momentum.
Here we explore the link between the moments of the Laguerre polynomials or Laguerre moments and the generalized functions (as the Dirac delta-function and its derivatives), presenting several interesting relations. A useful application is related to a procedure for calculating mean values in quantum optics that makes use of the so-called quasi-probabilities. One of them, the P-distribution , can be represented by a sum over Laguerre moments when the electromagnetic field is in a photon-number state. Consequently, the P-distribution can be expressed in terms of Dirac delta-function and derivatives. More specifically, we found a direct relation between P-distributions and the Laguerre factorial moments .
The practical aspect of the moment problem of the P function is developed; i.e., a simple explicit expression for the P function in terms of its moments and the derivatives of the Dirac \ensuremath{\delta} function in the complex domain is derived. Its connection with the concept of the nonclassical depth of a quantum state introduced recently is explored. The basic formulas derived are used in the calculations of several specific examples that are popular in the quantum-optics community, such as photon-number state, binomial state, two-photon thermal state, squeezed-vacuum state, etc.
In this paper, four distinct ideas are combined, which under a wide range of circumstances can give very rapidly converging series expansions for functional integrals. (1) Expansion of the functional being integrated in functional Taylor series. In the familiar case arising in quantum statistical mechanics, that of the Wiener integral of exp[−∫V(x(t))dt],V(x) being the perturbing potential, this is equivalent to expanding the characteristic functional of the probability functional of V(x(t)) in central moments of V(x(t)). The lowest-order term of the series is the approximation obtained by Feynman and Hibbs through a variational method. (2) Transfer of the harmonic term of the potential, when the functional integral is the quantum-statistical density matrix (Green's function of the Bloch equation), to the weighting function. This transforms the functional integral from a Wiener to an Uhlenbeck-Ornstein integral. The formal expressions for the terms of the expansion are somewhat more complicated, but they can be worked out, and the result is a great improvement in the speed of convergence of the series with decreasing temperature and/or decreasing relative magnitude of the anharmonic part of the potential. (3) ``Reservation of variables'' in the integration. This amounts to breaking the averaging process down into an average over subsets of the distributed random function (conditional average), followed by an averaging of these averages. Any step of this kind (it may be repeated within the subsets, etc.) gives an improvement of accuracy. (4) When the quantity being evaluated through functional integration is the partition function, the device introduced by Feynman and Hibbs, of interchanging the functional integration with the integration of the Green's function over the equated initial and final configuration-space points, may be combined with the above techniques. This eliminates one integration in the terms of the expansion and seems to improve accuracy at the same time. The general series obtained is correlated with more conventional operator techniques of quantum-mechanical perturbation theory, in order to answer the perennial question, does the path-integral method bring with it anything that could not be derived by other methods? It is in some sense a Feynman-Dyson expansion of the Green's function, but one that is further modified mathematically in a way characteristic only of the path-integral point of view, and which, moreover, improves its accuracy. It thus appears unlikely that the result is merely one of standard type disguised as a functional integral result. Sample numerical calculations are given to assay the accuracy of the methods, which are shown to compare very favorably with the traditional approximation of finite subdivision of the time interval.
Multipole moments for the harmonic oscillator as well as for other familiar quantum systems can be obtained without knowledge of the wavefunction by means of simple recursion relations. The third-order differential equation satisfied by the probability density is first obtained and from it, the recursion relation for the moments is directly deduced. A general and presumably novel formula giving all the multipole moments is obtained by solving the finite difference equation generated by the recursion relation.
Lie algebra, Zassenhaus, and parameter differentiation techniques are utilized to break up the exponential of a bilinear Hamiltonian operator into a product of noncommuting exponential operators by the virtue of the theory of Wei and Norman [J. Math. Phys. 4, 575 (1963); Proc. Am. Math. Soc., 15, 327 (1964)]. There are about three different ways to find the Zassenhaus exponents, namely, binomial expansion, Suzuki formula, and q-exponential transformation. A fourth, and most reliable method, is provided. Since linearly displaced and distorted (curvature change upon excitation/emission) Hamiltonian and spin-boson Hamiltonian may be classified as bilinear Hamiltonians, the presented algebraic algorithm (exponential operator disentanglement exploiting six-dimensional Lie algebra case) should be useful in spin-boson problems. The linearly displaced and distorted Hamiltonian exponential is only treated here. While the spin-boson model is used here only as a demonstration of the idea, the herein approach is more general and powerful than the specific example treated. The optical linear dipole moment correlation function is algebraically derived using the above mentioned methods and coherent states. Coherent states are eigenvectors of the bosonic lowering operator a and not of the raising operator a(+). While exp(a(+)) translates coherent states, exp(a(+)a(+)) operation on coherent states has always been a challenge, as a(+) has no eigenvectors. Three approaches, and the results, of that operation are provided. Linear absorption spectra are derived, calculated, and discussed. The linear dipole moment correlation function for the pure quadratic coupling case is expressed in terms of Legendre polynomials to better show the even vibronic transitions in the absorption spectrum. Comparison of the present line shapes to those calculated by other methods is provided. Franck-Condon factors for both linear and quadratic couplings are exactly accounted for by the herein calculated linear absorption spectra. This new methodology should easily pave the way to calculating the four-point correlation function, F(tau(1),tau(2),tau(3),tau(4)), of which the optical nonlinear response function may be procured, as evaluating F(tau(1),tau(2),tau(3),tau(4)) is only evaluating the optical linear dipole moment correlation function iteratively over different time intervals, which should allow calculating various optical nonlinear temporal/spectral signals.