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Journal of Physics C Solid State Physics

Pair correlation function in the critical region

Cyril Domb

Published Dec 1, 1969• 4 citations
Publisher

Abstract

The form of the spin pair correlation function in the critical region is investigated assuming that there is a single coherence parameter κ(t, H )( t = T / T c −1). It is found that the equation satisfied is H 2 = κ 2Δ/ν g ( t κ −1/ν ) which is closely analogous to the equation of state for magnetization H = M δ h ( tM −1/β ). The relationship between the functions g ( u ) and h ( u ) is established.

DOI
10.1088/0022-3719/2/12/131

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The form of the spin pair correlation function in the critical region is investigated assuming that there is a single coherence parameter κ(t, H )( t = T / T c −1). It is found that the equation satisfied is H 2 = κ 2Δ/ν g ( t κ −1/ν ) which is closely analogous to the equation of state for magnetization H = M δ h ( tM −1/β ). The relationship between the functions g ( u ) and h ( u ) is established.
Simple but rigorous derivations are presented for the inequalities2−η≤dγ′/(2β+γ′)≤dγ′/(2−α′),2−η≤d(δ−1)/(δ+1),γ≤(2−η)ν.(Proofs of the first two inequalities have been given by Buckingham and Gunton.1) Here d is the dimensionality and α′, β, γ, γ′ and δ are the exponents characterizing a ferromagnet near its critical point,2 while η and ν describe the decay of the corresponding spin-spin correlation functions2 Γ2(r)=〈S0zSrz〉, according to ∑ |r|<RΓ2(r)∼R2−η(T=Tc,H=0,R→∞),κ1∼(T−Tc)ν,(T→Tc,H=0),where the inverse range of correlation κ1 may be defined by κ1−2=[Σrr2Γ2(r)]/[ΣrΓ2(r)]. The corresponding exponent ηE for the energy-energy correlation function (essentially Γ4(r, a)−[Γ(a)]2, where Γ4(r, a)=〈S0zSazSrzSr+az〉) is proved to satisfy 2−ηE≤dα′,2−ηE≤dαc/(1+ζ+αc),where the specific heat CM at T=Tc diverges with the magnetization as M−αc while the energy derivative | ∂U/∂M |Tc varies as Mζ. (Mean Field or classical values are αc=0, ζ=1.) The proofs are based on the ``intuitively obvious'' properties: (a) positivity, namely, Γ1=〈S0z〉≥0,Γ(r)−Γ12≥0,Γ4(r, a)−[Γ2(a)]2≥0, and (b) monotonic increase of Γ1, Γ2 and Γ4 under increase of magnetic field and decrease of temperature. These properties are known3 to be rigorously valid for Ising models of arbitrary spin, lattice structure and ferromagnetic coupling (Jij≥0). Their validity for real magnets together with the experimental observation δ≤4.7 leads to the significant conclusion η≥0.05.
The dynamics of critical fluctuations is treated theoretically by extending the usual macroscopic dynamical variables to include all other dynamical variables that could exhibit the critical slowing-down. The equations of motion for these generalized macroscopic dynamical variables are derived with the help of Mori's general theory of Brownian motion, which involve the “first moment frequency matrix” Ωq and the microscopic damping for these new dynamical variables, where q is the wave vector characterizing macroscopic inhomogeneity. The latter involves only the dynamical variables that perform rapid random motions and is disregarded, or is disposed of by means of a dimensional argument. Then the dynamics of critical fluctuations is completely governed by Ωq which is expressed in terms of equaltime correlations of long wave-length fluctuations only and allows the analysis with the help of the Widom-Kadanoff static scaling laws. The theory is applied to the problem of anomalous spin relaxations in ferro and antiferromagnets in the paramagnetic region, and the inverse characteristic times near the transition points are found to behave asymptotically as κ(5-η)/2f(q/κ) and κ3/2f(q/κ), respectively, where κ is the inverse correlation range of spin fluctuations and η the parameter measuring the deviation of spin pair correlation from the Ornstein-Zernike form. Finally a close analogy is pointed out between the present treatment of critical fluctuations are the theory of hydrodynamic turbulence.