The mathematical structures of the theories of a two-level atom interacting with radiation and an electromagnetic wave interacting with a dielectric medium in which it is propagated as a plane wave are identical. The spin structure of the Jones operator in optics representing the polarizer, is obtained in its general form in terms of Stokes parameters and identified with the optical density operator with a spin structure identical with the density operator in the quantum mechanics of the atom. While the quantum dynamical equation of the atom can be reduced to the gyroscopic form, the correspondence law giving expression to the parallelism of the two processes leads to forms of the dynamical law in topics which are identical with those of the quantum theory of the atom.
The mathematical structures of the theories of a two-level atom interacting with radiation and an electromagnetic wave interacting with a dielectric medium in which it is propagated as a plane wave are identical. The spin structure of the Jones operator in optics representing the polarizer, is obtained in its general form in terms of Stokes parameters and identified with the optical density operator with a spin structure identical with the density operator in the quantum mechanics of the atom. While the quantum dynamical equation of the atom can be reduced to the gyroscopic form, the correspondence law giving expression to the parallelism of the two processes leads to forms of the dynamical law in topics which are identical with those of the quantum theory of the atom.
The theory of optical birefringence is discussed from the point of view of the scattering of polarized photons by molecules using the framework of formal scattering theory and quantum electrodynamics. In Part One, those features from noncovariant quantum electrodynamics relevant to the molecular scattering of photons are reviewed. Chapter One contains an outline of classical electrodynamics in the Coulomb gauge, including the Stokes parameter and density matrix formulations of polarization. Chapter Two deals with the quantization of the radiation field, and the occupation number representation is defined. The quantum mechanical description of polarized light is outlined in Chapter Three: operator equivalents of the density matrix and Stokes parameters are invoked, the parameters themselves being obtained from the expectation values of the Stokes operators with the state vector of the photon. The Stokes parameter and density matrix are then applied to the polarization of a general beam containing an arbitrary number of photons, and some new methods are developed. The interaction of the electromagnetic field with bound electrons is formulated in Chapter Four in terms of a canonically transformed interaction Hamiltonian in which the multipole terms are explicit. Since each term is then gauge-invariant, this Hamiltonian is particularly suited to the application of diagrammatic perturbation theory which follows from the iteration of the scattering matrix in the interaction representation (Chapter Five). Also the extension of the theory to multiphoton processes is facilitated "because the field strength is explicit in the transformed Hamiltonian. The S-matrix connects the initial and final asymptotic states of the scattering system, and in Chapter Six the state vector and density operator of the scattered photon beam are obtained from those of the incident beam. Part Two contains the application of the above methods to a variety of linear and nonlinear optical birefringence effects in the absence or presence of external fields. In Chapter Seven, general equations are obtained for the polarization changes imposed on a forward scattered photon in terms of matrix elements of the reaction operator between plane polarized photon base states; whereas Chapter Eight extends this treatment to an n-photon beam, thereby encompassing the hyperpolarizability contributions to the polarization changes of the forward scattered beam. It is then demonstrated that the fundamental process in optical birefringence can be interpreted as an infinitesimal unitary transformation of the polarization spinor. Also the S-matrix approach to birefringence is compared with the methods used in crystal optics, and with the classical treatments of the scattering of polarized light by molecules. The general equations obtained for the polarization changes of the forward scattered beam are subsequently interpreted in the light of the physical circumstances appropriate to the bire- fringence effect of interest. In Chapters Nine, Ten, and Eleven, diagrammatic perturbation theory is used to obtain explicit expressions, in terms of molecular polarizability and rotation tensors, for the linear and nonlinear contributions to the polarization changes involved in natural optical activity, and in birefringence phenomena induced by static and optical electric and magnetic fields. The nonforward scattering of polarized photons by molecules is discussed in Part Three. General equations are calculated in Chapter Twelve for the azimuth, ellipticity, and depolarization ratio of the Rayleigh beam at any scattering angle and for any polarization of the incident beam. Explicit expressions in terms of molecular quantities are then obtained for the polarization at scattering angles of 90° and almost zero from both optically inactive and optically active molecules. It is demonstrated that a determination of the precise polarization state of the scattered beam can provide useful molecular information additional to that obtained from depolarization ratios alone. This is because the depolarization ratio depends on only the diagonal elements of the polarization density matrix and so does not convey all the information about the system. Raman scattering processes are contained in the formulation and the polarization of the Raman light at any scattering angle can be obtained. This is shown to be particularly useful for predicting the polarization of stimulated Raman light for any Raman-active liquid placed within a laser cavity. By extending the nonforward scattering formulation to incorporate multiphoton processes, equations are obtained in Chapter Thirteen for the ellipticity, azimuth, and depolarization ratio of the second harmonic wave at any scattering angle as a function of the incident polarization. Several specific situations are subsequently investigated. Finally, it is shown in Chapter Fourteen that the near-forw- ard Rayleigh and Raman scattering formulations provide an explanation for the observed polarization, as a function of the initial polarization, of the self-trapped filaments that arise from the self-focusing of an intense laser beam.
Since in quantum optics light is represented in terms of photons, light propagation through a linear medium is discussed quantum mechanically in this paper by following the multiple-scattering process of one incident photon from the medium. To treat the photon and the medium on the same quantum footing, the medium is assumed to be an ensemble of uniformly distributed identical two-level atoms. It is found that inside the medium the incident photon follows the same propagation rules as a plane wave does in the classical domain, and has a possibility to become entangled with the atoms. It is also found that when interacting with a two-level test atom outside the medium, the output photon appears to be formally in a single mode identical to that of the incident photon.
Analysis of the interaction of the electromagnetic field and matter is a topical area of research in modern physics. The goal of this paper is to move from mathematical postulates and formalisms of quantum mechanics to equations that include macroscopic variables. In this case, the macroscopic observables are determined by the mean values of the operator corresponding to the observable value, and the mean value is deter-mined by the density matrix. Then the equations are written only through the mean values, by substituting equivalent expressions for the density matrix. As a result, we come to a system of equations expressed in terms of such macroscopic variables as polarization and electromagnetic field. In the semi-classical approach, when the electromagnetic field is not quantized, it is necessary to add the Maxwell's equations of the electromagnetic field to the equations for the mean values. This forms a self-consistent system of equations.
In this work the electromagnetic field in a dielectric medium is quantized in a simple and straightforward way based on the classical expression for the energy density for the case of weak absorption. The quantized field leads to expressions for spontaneous and stimulated emission rates, and gain and absorption coefficients, for the general case of a dispersive dielectric host medium. Local field corrections, when they apply, arise in the same manner as in classical electromagnetic theory. The theory also leads to a radiative level shift dependent on the dispersion of the dielectric, and this shift may be interpreted as a van der Waals interaction between the guest atom and the atoms of the host medium.>
The nine (9) elements of the density matrix of a general three-level atom interacting with a classically described linearly polarized light are parameterized by eight (8) variables related to the populations of the atomic levels, and the coherences (interference effects) between the levels. The dynamical equations of these eight parameters (that is, the optical Bloch equations for a general three-level atom) are derived under the electric dipole as well as the rotating wave approximations, and under the assumption that the matrix elements of the atomic electric dipole are all real. The general optical Bloch equations so derived are shown to contain the well-known optical Bloch equations for three-level atoms in the , and cascade configurations as well as those for two-level atoms as special cases. Expressing the interaction of light with a three-level atom in all possible configurations as well as with a two-level atom by a single set of generalized optical Bloch equations is the main result of this work.
This book provides exact analytical solutions to some of the most challenging and exciting problems in quantum optics, ranging from the theory of multi-level atom-radiation field interaction to multi-photon parametric processes in non-linear quantum optics. The problems are generally reduced to two-state dynamics for which detailed reader-friendly solution procedures displaying every important mathematical step are presented. The exact discrete and equivalent continuous variable time evolution operators generate explicitly specified time evolving spin / helicity coherent state vectors and Schroedinger wave functions describing the general quantum states of light, including dissipative dynamics. Photon polarization state dynamics under semi-classical and fully quantized parametric interactions is clearly presented. All the results in fully quantized parametric processes in non-linear quantum optics are new and are appearing for the first time in the literature. The book is particularly useful for graduate level teaching and as a resource text for research in linear and non-linear quantum optics.