Quantum corrections to the noninertial Brownian motion of a particle in a one-dimensional tilted cosine periodic potential are treated in the high-temperature and weak bath-particle coupling limit by solving a quantum Smoluchowski equation for the time evolution of the distribution function in configuration space. The theoretical predictions from two different forms of the quantum Smoluchowski equation already proposed-viz., J. Ankerhold [Phys. Rev. Lett. 87, 086802 (2001)] and W. T. Coffey [J. Phys. A 40, F91 (2007)]-are compared in detail in a particular application to the dynamics of a point Josephson junction. Various characteristics (stationary distribution, current-voltage characteristics, mean first passage time, linear ac response) are evaluated via continued fractions and finite integral representations in the manner customarily used for the classical Smoluchowski equation. The deviations from the classical behavior, discernible in the dc current-voltage characteristics as enhanced current for a given voltage and in the resonant peak in the impedance curve as an enhancement of the Q factor, are, respectively, a manifestation of relatively high-temperature nondissipative tunneling (reducing the barrier height) and dissipative tunneling (reducing the damping of the Josephson oscillations) near the top of a barrier.
Quantum corrections to the noninertial Brownian motion of a particle in a one-dimensional tilted cosine periodic potential are treated in the high-temperature and weak bath-particle coupling limit by solving a quantum Smoluchowski equation for the time evolution of the distribution function in configuration space. The theoretical predictions from two different forms of the quantum Smoluchowski equation already proposed-viz., J. Ankerhold [Phys. Rev. Lett. 87, 086802 (2001)] and W. T. Coffey [J. Phys. A 40, F91 (2007)]-are compared in detail in a particular application to the dynamics of a point Josephson junction. Various characteristics (stationary distribution, current-voltage characteristics, mean first passage time, linear ac response) are evaluated via continued fractions and finite integral representations in the manner customarily used for the classical Smoluchowski equation. The deviations from the classical behavior, discernible in the dc current-voltage characteristics as enhanced current for a given voltage and in the resonant peak in the impedance curve as an enhancement of the Q factor, are, respectively, a manifestation of relatively high-temperature nondissipative tunneling (reducing the barrier height) and dissipative tunneling (reducing the damping of the Josephson oscillations) near the top of a barrier.
Recent progress in our understanding of quantum effects on the Brownian motion in an external potential is reviewed. This problem is ubiquitous in physics and chemistry, particularly in the context of decay of metastable states, for example, the reversal of the magnetization of a single domain ferromagnetic particle, kinetics of a superconducting tunnelling junction, etc. Emphasis is laid on the establishment of master equations describing the diffusion process in phase space analogous to the classical Fokker-Planck equation. In particular, it is shown how Wigner's [E. P. Wigner, Phys. Rev., 1932, 40, 749] method of obtaining quantum corrections to the classical equilibrium Maxwell-Boltzmann distribution may be extended to the dissipative non-equilibrium dynamics governing the quantum Brownian motion in an external potential V(x), yielding a master equation for the Wigner distribution function W(x,p,t) in phase space (x,p). The explicit form of the master equation so obtained contains quantum correction terms up to o(h(4)) and in the classical limit, h --> 0, reduces to the classical Klein-Kramers equation. For a quantum oscillator, the method yields an evolution equation coinciding in all respects with that of Agarwal [G. S. Agarwal, Phys. Rev. A, 1971, 4, 739]. In the high dissipation limit, the master equation reduces to a semi-classical Smoluchowski equation describing non-inertial quantum diffusion in configuration space. The Wigner function formulation of quantum Brownian motion is further illustrated by finding quantum corrections to the Kramers escape rate, which, in appropriate limits, reduce to those yielded via quantum generalizations of reaction rate theory.
Based on the dynamical quantization method we derive a quantum phase-space non-Markovian Smoluchowski equation describing the non-inertial Brownian motion of a harmonic oscillator immersed in a generic environment. In the long-time regime we investigate the tunneling phenomenon by evaluating the quantum Kramers escape rate of a Brownian particle over a potential barrier. As far as a quantum thermal reservoir is concerned, it is found that our steady quantum Kramers rate may depend upon no friction constant in the strong friction domain. This preposterous feature may suggest the existence of non-dissipative quantum tunneling at the low-temperature range, including the zero temperature case. Lastly, we predict that our quantum escape rate non-exponentially decays on the edge of the breakdown of the dissipation-fluctuation relation.
Quantum Brownian motion in a periodic cosine potential is studied and a simple estimate of the tunneling effect is obtained in the frames of a semiclassical quasi-equilibrium approach. It is shown that the latter is applicable for heavy particles but electrons cannot be described properly since the quantum effects dominate over the thermal ones. The electron purely quantum diffusion is investigated at zero temperature and demonstrates that electrons do not obey the classical Einstein law of Brownian motion in the fi eld of periodic potentials, since the dispersion of the Gaussian wave packet increases logarithmically in time. Diffusion in the fi eld of periodic potentials is important for particle transport via ordered structures, typical in condensed matter. The underlying mechanism is Brownian motion. If the diffusing particles are quantum ones, e.g. electrons, protons, light atoms, etc., their migration is described via the theory of quantum Brownian motion [1, 2], which is signifi cantly affected by the tunneling effect [3]. Hereafter an alternative approach to the problem of quantum Brownian motion in periodic potentials is developed based on the Bohm quantum potential [4]. In contrast to the WKB theory valid in vacuum the present paper describes tunneling in a dissipative environment. The starting point is a nonlinear quantum Smoluchowski-like equation [5, 6] 0 [ ( ) ] / t x x b x V Q d b β ∂ ρ = ∂ ρ∂ + β + ∂ ρ β ∫ (1)
We have investigated the phase dynamics of a superconducting tunnel junction at ultralow temperatures in the presence of high damping, where the interaction with environmental degrees of freedom represents the leading energy scale. In this regime, theory predicts the dynamics to follow a generalization of the classical Smoluchowski description, the quantum Smoluchowski equation, thus, exhibiting overdamped quantum Brownian motion characteristics. For this purpose, we have performed current-biased measurements on the small-capacitance Josephson junction of a scanning tunneling microscope placed in a low impedance environment at milli-Kelvin temperatures. We can describe our experimental findings with high accuracy by using a quantum phase diffusion model based on the quantum Smoluchowski equation. In this way we experimentally demonstrate that overdamped quantum systems follow quasiclassical dynamics with significant quantum effects as the leading corrections.
The strong-friction regime at low temperatures is analyzed systematically starting from the formally exact path-integral expression for the reduced dynamics. This quantum Smoluchowski regime allows for a type of semiclassical treatment in the inverse friction strength so that higher-order quantum corrections to the original quantum Smoluchowski equation [J. Ankerhold, P. Pechukas, and H. Grabert, Phys. Rev. Lett. 87, 086802 (2001); J. Ankerhold and H. Grabert, Phys. Rev. Lett. 101, 119903 (2008)] can be derived. Drift and diffusion coefficients are determined by the equilibrium distribution in position and are directly related to the corresponding action of extremal paths and fluctuations around them. It is shown that the inclusion of higher-order corrections reproduces the quantum enhancement above crossover for the decay rate out of a metastable well exactly.
In this thesis, the recent semiclassical approach to quantum Brownian motion of Coffey et\nal. [Phys. Chem. Chem. Phys. 9, 3361 (2007)] is studied in detail. This approach is based\non a semiclassical extension of Wigner's method of obtaining corrections to the classical\nequilibrium Maxwell-Boltzmann distribution, yielding a master equation for the reduced\nWigner function in quasi-phase space valid in the weak coupling and high temperature\nlimits. In the non-inertial or high damping limit, this master equation reduces to a quantum\nSmoluchowksi equation (QSE), where the drift coefficient remains as in the classical case,\nwhile the diffusion coefficient is altered to include the quantum parameter and derivatives\nof the potential.