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Journal of Physics A Mathematical Nuclear and General

The free energy of the classical Heisenberg model with anisotropic interactions

J Rae

Published Jul 21, 1974• 7 citations
Publisher

Abstract

Exact expressions are given for the free energy of the classical Heisenberg model in one lattice dimension and two or three spin dimensions with general anisotropy; the two-dimensional result, already known, is in terms of Mathieu functions and the three-dimensional result in terms of Lame wavefunctions. The method presented solves the eigenvalue problem for an appropriate transfer matrix by relating it to solutions of the Helmholtz equation in suitable curvilinear coordinate systems. High and low temperature limits are discussed for the three-dimensional spin case and the connection given with already known results for partial anisotropy.

DOI
10.1088/0305-4470/7/11/014

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Exact expressions are given for the free energy of the classical Heisenberg model in one lattice dimension and two or three spin dimensions with general anisotropy; the two-dimensional result, already known, is in terms of Mathieu functions and the three-dimensional result in terms of Lame wavefunctions. The method presented solves the eigenvalue problem for an appropriate transfer matrix by relating it to solutions of the Helmholtz equation in suitable curvilinear coordinate systems. High and low temperature limits are discussed for the three-dimensional spin case and the connection given with already known results for partial anisotropy.
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The eigen-functions and eigen-values of finite three-dimensional Heisenberg models with anisotropy constant as a parameter (spin=1/2) were obtained exactly with the aid of group theoretical technique and by using a high speed computer. The calculated eigenvalues are identical with those obtained by Serber and Dresselhaus for the isotropic simple cubic 2×2×2 lattice. However, it was found that some terms in their full expressions were to be corrected. The zeros of the partition function of the above 2×2×2 lattice have been investigated as functions of the anisotropy parameter both in the complex temperature plane and in the complex magnetic field plane. Thermodynamic functions such as energy, specific heat, magnetization, and susceptibility have been numerically computed for these finite system.
A variational approach based on Bogoliubov inequality for the free energy is employed in order to treat the quantum spin-1 anisotropic ferromagnetic Heisenberg model in the presence of a crystal field. Within the Bogoliubov scheme an improved pair approximation has been used. The temperature-dependent thermodynamic functions have been obtained and provide much better results than the previous simple mean-field scheme. In one dimension, which is still nonintegrable for quantum spin-1, we get the exact results in the classical limit, or near-exact results in the quantum case, for the free energy, magnetization, and quadrupole moment, as well for the transition temperature. In two and three dimensions the corresponding global phase diagrams have been obtained as a function of the parameters of the Hamiltonian. First-order transition lines, second-order transition lines, tricritical and tetracritical points, and critical endpoints have been located through the analysis of the minimum of the Helmholtz free energy and a Landau-like expansion in the approximated free energy. Only first-order quantum transitions have been found at zero temperature. Limiting cases, such as isotropic Heisenberg, Blume-Capel, and Ising models, have been analyzed and compared to previous results obtained from other analytical approaches as well as from Monte Carlo simulations.
We discuss the ground state of the Heisenberg spin-1/2 chain in one dimension, considering nearest neighbor interactions. In the thermodynamic limit the energy is calculated analytically in several ways. We start by applying the Bethe ansatz to calculate the exact ground state energy of the XXX Heisenberg model. Next we study small perturbations of the spin anisotropy, the parameter for the interaction in the z-direction for the XXZ model, by applying time-independent perturbation theory. In addition we expand an exact integral expression of the energy of the XXZ model around the spin anisotropy in the thermodynamic limit. The results are compared to numerical solutions, which are obtained by means of exact diagonalization up to twelve lattice sites. We find that for ten or more lattice sites the numerics agree well with the expectation from the analytical calculations. Finally the concept of integrability is discussed in the context of the Heisenberg model.