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American Journal of Physics

Gauge invariant formulation of the interaction of electromagnetic radiation and matter

Donald H. Kobe, Arthur L. Smirl

Published Jun 1, 1978• 118 citations
Publisher

Abstract

The conventional perturbation theory in quantum mechanics for the interaction of electromagnetic radiation with matter, which is based on the time-dependent vector and scalar potentials, is shown to be dependent on the gauge. The problem is reformulated, using the approach of Yang, in a gauge-invariant way, in which the transitions between states are induced by the quantum-mechanical power operator. In order to use an unperturbed Hamiltonian which does not involve the electromagnetic field, the gauge is chosen to give the electric dipole interaction. This choice can be made if the magnetic field is negligible and the electric field is slowly varying over atomic dimensions. For a comparison of the gauge-invariant and conventional formulation, a two-level atom in a radiation field is considered. For the probability that an atom originally in the lower state will make a transition to the upper state when the field is not in resonance, the gauge-invariant formulation gives the correct result, whereas the gauge-dependent formulation gives an incorrect result.

DOI
10.1119/1.11264

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Gauge invariance in quantum mechanics: charged harmonic oscillator in the magnetic dipole approximation

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A manifestly gauge-invariant formulation of quantum mechanics is applied to a charged isotropic harmonic oscillator in a time-varying magnetic field in the magnetic dipole approximation. The energy operator for the problem is the sum of the kinetic and potential energies. The kinetic energy operator is the square of the gauge-invariant kinetic momentum operator divided by twice the mass. The energy eigenvalues and state probabilities are calculated and are shown to be the same in all gauges. In this problem there is no gauge in which the energy operator reduces to the unperturbed Hamiltonian, as there is in the electric dipole approximation. Consequently, eigenvalues of the unperturbed Hamiltonian and corresponding (gauge-dependent) state 'probabilities' are different from the gauge-invariant quantities in all gauges.

Journal of Physics A Mathematical and General•Feb 21, 1983•7 citations
The conventional perturbation theory in quantum mechanics for the interaction of electromagnetic radiation with matter, which is based on the time-dependent vector and scalar potentials, is shown to be dependent on the gauge. The problem is reformulated, using the approach of Yang, in a gauge-invariant way, in which the transitions between states are induced by the quantum-mechanical power operator. In order to use an unperturbed Hamiltonian which does not involve the electromagnetic field, the gauge is chosen to give the electric dipole interaction. This choice can be made if the magnetic field is negligible and the electric field is slowly varying over atomic dimensions. For a comparison of the gauge-invariant and conventional formulation, a two-level atom in a radiation field is considered. For the probability that an atom originally in the lower state will make a transition to the upper state when the field is not in resonance, the gauge-invariant formulation gives the correct result, whereas the gauge-dependent formulation gives an incorrect result.
The gauge-invariant formulation of quantum mechanics is applied to the charged harmonic oscillator in an electromagnetic field in the electric dipole approximation to obtain the probability that the oscillator is in a particular state at time t. This probability is compared with the corresponding 'probability' calculated from the conventional approach to the interaction of radiation with matter using the interaction A.p. The probabilities do not agree with each other. From the principle of gauge invariance it is concluded that the probability calculated from the gauge-invariant formulation is correct in this case, and that the conventional approach in general is incorrect.
The case of a single charged particle with potential energy is considered when the classical electromagnetic field is zero. The vector and scalar potentials describing this situation are not necessarily zero. When the conventional approach to radiation problems using the interaction A⋅p plus p⋅A plus A2 plus A0 (constants omitted) is used, time-dependent probabilities are predicted if the vector potential A=−∇Λ≠0 even though the electromagnetic field is zero. The reason for this unphysical behavior is that eigenfunctions of the unperturbed Hamiltonian, which is not gauge invariant, are used to calculate the probability amplitudes. When a manifestly gauge-invariant procedure is applied to this case the probabilities are constant in all gauges. The reason that physical results are obtained is that eigenstates of the energy operator are used to calculate the probability amplitudes.
For pt.I see ibid., vol.15, p.1201 (1982). The author formulates a manifestly gauge-invariant time-dependent perturbation theory for a nonrelativistic spinless charged particle interacting with a classical external electromagnetic radiation field. The treatment of the degenerate bound states and the states in the continuum is considered. It is found that the gauge-invariant and the conventional perturbative solutions agree on the net transition rates but disagree on the transition amplitudes and transition probabilities. The treatment of a realistic physical system can be obtained by combining the treatment here with that for a nondegenerate system.
A novel Hamiltonian scheme for non–relativistic quantum electrodynamics in which the gauge arbitrariness of the field potential is kept explicit is used to study the gauge–dependence properties of various versions of perturbation theory when resonance and line–broadening effects are admitted. Time–dependent perturbation theory is shown to have severe gauge–dependence problems unless ad hoc modifications are made. A time–independent formulation of S–matrix theory is then studied. Far from resonance, the S–matrix is gauge invariant in all orders of perturbation theory due to a very precise cancellation of gauge–dependent terms which requires, among other things, complete sets of intermediate states; energy conservation also has a crucial role. However, an obvious separation of the S–matrix into a resonant (pole) and non–resonant background leads to incomplete cancellation of the gauge–dependent terms. The introduction of the Heitler damping matrix into an integral equation for the T–matrix leads to a gauge–invariant result. This provides the basis for a gauge invariant S–matrix theory of atoms and molecules interacting with electromagnetic radiation that encompasses resonance and damping effects.
The conventional formulation for interaction of radiation with matter uses a zero potential Hamiltonian H 0 as an unperturbed Hamiltonian and this procedure leads to a conflict between the gauge invariance of probability amplitudes and the Born rule. It is pointed out that if one uses a dark Hamiltonian H d as the unperturbed Hamiltonian and considers its gauge dependence, then this conflict no longer exists. From this point of view the author proves that the Lamb gauge and the Coulomb gauge in the electric dipole approximation give the same gauge-independent probability amplitudes, and thus the A.p against r.E controversy becomes unimportant.
A manifestly gauge-invariant formulation of quantum mechanics is applied to a charged isotropic harmonic oscillator in a time-varying magnetic field in the magnetic dipole approximation. The energy operator for the problem is the sum of the kinetic and potential energies. The kinetic energy operator is the square of the gauge-invariant kinetic momentum operator divided by twice the mass. The energy eigenvalues and state probabilities are calculated and are shown to be the same in all gauges. In this problem there is no gauge in which the energy operator reduces to the unperturbed Hamiltonian, as there is in the electric dipole approximation. Consequently, eigenvalues of the unperturbed Hamiltonian and corresponding (gauge-dependent) state 'probabilities' are different from the gauge-invariant quantities in all gauges.