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Physical Review A

van der Waals limit of an interacting Bose gas in a weak external field

Philip de Smedt, Valentin Anatol'evich Zagrebnov

Published Jun 1, 1987• 17 citations
Publisher

Abstract

We study how the introduction of a two-body interaction changes the thermodynamic properties of the free Bose gas in a weak (scaled) external field. We show that, in the van der Waals limit, the thermodynamic pressure always is a ${C}^{\ensuremath{\infty}}$ function of the density in one and two dimensions, while this is not so in higher dimensions. The phase transition to the superfluid phase in the latter case is discussed in more detail by looking at the local densities. We also show that the van der Waals limit for this system does not correspond to the usual mean-field approximation.

DOI
10.1103/physreva.35.4763

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We show that universal properties of a many-atom quantum system exist at a much higher density, or a much shorter length scale, than those implied by traditional theories for a dilute Bose gas. In particular, a universal equation of state at length scale β 6 = ( mC 6 /ℏ 2 ) 1/4 (corresponding to the van der Waals interaction) is defined and investigated by combining the concept of effective potential, the constrained variational method and the analytic solution for the van der Waals potential. In one application, we show that a many-atom Bose system with negative scattering length may form a metastable liquid Bose–Einstein condensate (BEC) state with an equilibrium density that is controlled by a scaled scattering length.
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We consider a three-dimensional weakly interacting Bose gas in the fluctuation region (and its vicinity) of the normal-superfluid phase transition point. We establish relations between basic thermodynamic functions: density, n(T,μ)n(T,μ)n(T,μ), superfluid density ns(T,μ)n_s(T,μ)ns​(T,μ), and condensate density, ncnd(T,μ)n_{\rm cnd} (T,μ)ncnd​(T,μ). Being universal for all weakly interacting ∣ψ∣4|ψ|^4∣ψ∣4 systems, these relations are obtained from Monte Carlo simulations of the classical ∣ψ∣4|ψ|^4∣ψ∣4 model on a lattice. Comparing with the mean-field results yields a quantitative estimate of the fluctuation region size. Away from the fluctuation region, on the superfluid side, all the data perfectly agree with the predictions of the quasicondensate mean field theory.--This demonstrates that the only effect of the leading above-the-mean-field corrections in the condensate based treatments is to replace the condensate density with the quasicondensate one in all local thermodynamic relations. Surprisingly, we find that a significant fraction of the density profile of a loosely trapped atomic gas might correspond to the fluctuation region.
We show that universal properties of a many-atom quantum system exist at a much higher density, or a much shorter length scale, than those implied by traditional theories for a dilute Bose gas. In particular, a universal equation of state at length scale β6 = (mC6/2)1/4 (corresponding to the van der Waals interaction) is defined and investigated by combining the concept of effective potential, the constrained variational method and the analytic solution for the van der Waals potential. In one application, we show that a many-atom Bose system with negative scattering length may form a metastable liquid Bose–Einstein condensate (BEC) state with an equilibrium density that is controlled by a scaled scattering length.
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We consider an impurity in a one-dimensional weakly interacting Bose gas and analytically calculate the density profile of the Bose gas. Within the mean-field approximation, by increasing the distance from the impurity, the Bose gas density saturates exponentially fast to its mean thermodynamic-limit value at distances beyond the healing length. The effect of quantum fluctuations drastically changes this behavior, leading to a power-law decay of the density deviation from the mean density. At distances longer than the healing length and shorter than a new length scale proportional to the impurity coupling strength, the power-law exponent is 2, while at the longest distances the corresponding exponent becomes 3. The latter crossover does not exist in two special cases. The first one is realized for infinitely strongly coupled impurity; then the density deviation always decays with the exponent 2. The second special case occurs when the new length scale is smaller than the healing length, i.e., at weak impurity coupling; then the density deviation always decays with the exponent 3. The obtained results are exact in the impurity coupling strength and account for the leading order in the interaction between the particles of the Bose gas.