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Physical Review Letters

Symplectically Invariant WKB Wave Functions

Robert G. Littlejohn

Published Apr 22, 1985• 22 citations
Publisher

Abstract

Traditional WKB theory yields wave functions which have divergences and are not invariant under any reasonable class of transformations. This Letter presents alternative WKB wave functions which have no divergences and are symplectic invariants.
DOI
10.1103/physrevlett.54.1742

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A method is presented for the construction of WKB wave functions that avoids explicit consideration of any matching between results pertaining to classically allowed and classically forbidden regions. The formalism is based on the maximization of a suitably defined quantal pseudoentropy, subject to the constraints posed by the expectation values of a reduced number of operators, which are evaluated according to special WKB techniques that consider expansions up to orders \ensuremath{\Elzxh} and ${\mathrm{\ensuremath{\Elzxh}}}^{2}$. The algorithm is tested with reference to the harmonic and quartic anharmonic oscillators.